我国西北夏季风边界千年尺度变化的证据--来自盐池和猪野泽盐类矿物分析结果

我国夏季风西北缘是响应长尺度气候变化最为敏感的区域之一, 但夏季风边界变化与千年尺度气候变化之间的关系尚不明确, 相关研究仍缺乏足够证据。夏季风西北缘湖泊沉积物中盐类矿物种类与含量的时空变化, 有助于推测气候变化特征。盐池和猪野泽分别位于祁连山北麓的河西走廊中段和东段, 是研究长时间尺度亚洲夏季风影响区西北边界变化的关键区域。研究全新世千年尺度下, 夏季风西北边界的变化对夏季风西北缘气候变化过程的影响, 对明确季风边缘区千年尺度季风变化机制, 预测未来长尺度气候变化有重要意义。因此, 本文选择盐池古湖泊盐池剖面(YC), 猪野泽青土湖01、02剖面(QTH01、QTH02)等三个剖面, 开展全新世千年尺度下, 亚洲季风西北边界地区湖泊沉积物盐类矿物时空变化对比研究。结果显示:QTH01、QTH02剖面盐类矿物以碳酸盐为主, 硫酸盐类矿物仅零星出现, 而YC剖面硫酸盐类矿物含量相对较高, 同时出现了氯化物型矿物, 全新世气候特征整体较猪野泽更为干旱。末次冰期和早全新世, 三个剖面受季风输送水汽影响明显, 碳酸盐类矿物能较好沉积, 季风边界在这一时期向北扩张, 推进到祁连山中段地区;中全新世QTH01、QTH02剖面受夏季风影响减弱, 湖泊退缩, 碳酸盐类矿物含量达到峰值, YC剖面则表现出极端干旱的气候特征, 硫酸盐类矿物因“盐效应”含量下降, 此时夏季风西北部水汽输送边界位于石羊河流域和盐池流域之间;晚全新世盐池和猪野泽均以风成沉积为主, 气候干旱, 碳酸盐类矿物难以保存, 硫酸盐和氯化物矿物含量出现高值, 说明夏季风西北边界进一步向南迁移。综上所述, 盐类矿物含量变化能良好反应夏季风西北缘全新世气候变化特征, 同时证明, 在全新世千年尺度上, 夏季风西北边界在盐池流域和石羊河流域之间存在变化。     

地质流体对砂岩储层黏土矿物的影响——以渤海海域古近系为例

根据偏光显微镜、扫描电镜和X-衍射等分析手段获取的数据和资料,分析对比了早期沉积水介质、幔源CO2流体、大气水、超压流体和充注烃类等对储层黏土矿物的控制作用。研究表明,早期沉积水介质是储层黏土矿物的决定性因素,微咸水-半咸水湖盆储层黏土矿物以伊利石为主,淡水湖盆储层黏土矿物以高岭石为主;幔源CO2流体侵位后带来明显的储层改造和热波动效应,储层中I/S中S%含量低于同深度泥岩,储层中高岭石含量明显偏高。欠压实超压储层中黏土演化明显滞后,表现在I/S中S%含量低于同深度泥岩和常压储层。油气层高岭石含量往往远高于相近深度的水层,可能与充注烃类携带的有机酸的溶蚀作用有关,另外,烃类充注后形成的惰性成岩环境也有利于高岭石的保存,高岭石的高含量带常与油层及高渗层相对应;受大气水淋滤的储层,以长石大量溶蚀,富含高岭石为特征,储层孔隙度一般较高。     

黑龙江省砂宝斯金矿床矿石矿物与金矿物特征研究

为给砂宝斯金矿床的勘探和利用提供依据,本文总结了多年的野外观察资料,并通过镜下鉴定、人工重砂、电子探针等方法对该矿床的矿石矿物、金矿物特征进行了系统研究。结果表明,该矿床的矿石类型为贫硫化物微细粒浸染型金矿石,矿石矿物主要为黄铁矿,次为毒砂,含有较多的微量元素;脉石矿物主要为石英。矿石结构主要为半自形-自形、他形、交代、固溶体分离结构,浸染状或细脉浸染状构造。金矿物主要为自然金,其赋存状态以硫化物中包裹金和脉石粒间金为主,主要为微粒金及次显微金,呈微细分散状态。除Au元素外,矿床中其他元素均不具有综合利用价值,有害元素含量低。     

Evidence of multi-stage faulting by clay mineral analysis: Example in a normal fault zone affecting arkosic sandstones (Annot sandstones)

Fault affecting silicoclastic sediments are commonly enriched in clay minerals. Clays are sensitive to fluid–rock interactions and deformation mechanisms; in this paper, they are used as proxy for fault activity and behavior. The present study focuses on clay mineral assemblages from the Point Vert normal fault zone located in the Annot sandstones, a Priabonian-Rupelian turbidite succession of the Alpine foredeep in SE France. In this area, the Annot sandstones were buried around 6–8 km below the front of Alpine nappes soon after their deposition and exhumed during the middle-late Miocene. The fault affects arkosic sandstone beds alternating with pelitic layers, and displays throw of about thirty meters. The fault core zone comprises intensely foliated sandstones bounding a corridor of gouge about 20 cm thick. The foliated sandstones display clay concentration along S–C structures characterized by dissolution of K-feldspar and their replacement by mica, associated with quartz pressure solution, intense microfracturation and quartz vein precipitation. The gouge is formed by a clayey matrix containing fragments of foliated sandstones and pelites. However, a detailed petrographical investigation suggests complex polyphase deformation processes. Optical and SEM observations show that the clay minerals fraction of all studied rocks (pelites and sandstones from the damage and core zones of the fault) is dominated by white micas and chlorite. These minerals have two different origins: detrital and newly-formed. Detrital micas are identified by their larger shape and their chemical composition with a lower Fe–Mg content than the newly-formed white micas. In the foliated sandstones, newly-formed white micas are concentrated along S–C structures or replace K-feldspar. Both types of newly formed micas display the same chemical composition confirmed microstructural observations suggesting that they formed in the same conditions. They have the following structural formulas: Na_0.05 K_0.86 (Al _1.77 Fe_0.08 Mg_0.15) (Si_3.22 Al_0.78) O₁₀ (OH)_2. They are enriched in Fe and Mg compared to the detrital micas. Newly-formed chlorites are associated with micas along the shear planes. According to microprobe analyses, they present the following structural formula: (Al_1,48 Fe_2,50 Mg_1,84) (Si_2,82 Al_1,18) O₁₀ (OH)₈. All these data suggest that these clay minerals are synkinematic and registered the fault activity. In the gouge samples, illite and chlorite are the major clay minerals; smectite is locally present in some samples.In the foliated sandstones, Kubler Index (KI) ((001) XRD peak width at half height) data and thermodynamic calculations from synkinematic chlorite chemistry suggest that the main fault deformation occurred under temperatures around 220 °C (diagenesis to anchizone boundary). KI measured on pelites and sandstones from the hanging and footwall, display similar values coherent with the maximal burial temperature of the Annot sandstones in this area. The gouge samples have a higher KI index, which could be explained by a reactivation of the fault at lower temperatures during the exhumation of the Annot sandstones formation.     

REQUIREMENTS OF SHRIMP, PENAEUS CHINENSIS O''''SBECK FOR POTASSIUM, SODIUM, MAGNESIUM AND IODINE

Potassium, sodium, magnesium and iodine requirements of shrimp, Penaeus chinensis were studied.Orthogonal design was employed in this experiment. The composition of the basal diet consisted of fishmeal, peanut cake, corn meal, soybean cake, wheat bran, vitamin mix and mineral mix, and supple-mentations of potassium, sodium, magnesium and iodine in the basal diet were made according to theL_9(3~4) orthogonal table. The results indicatal that iodine supplementation improved growth of the shrimpsignificantly and raised survival very significanly, iodine requirement of the shrimp was 0.003%, sodiumrequirement was 0.87% or less; and that 1.1-1.3% potassium and 0.18-0.38% magnesium in the dietwere proper nutrition supplements for the shrimp.     

Stability relations of Mn–Fe–Al piemontite

Abstract Comparison of the stability relations of Fe-piemontite, Pm₁₇Ps₁₇Cz₆₆ (Ca₂Al₂Mn_0.5 Fe_0.5Si₃O₁₂(OH)), with similar experimentally determined results on Pm₃₃Cz₆₇ suggests that, at moderate f_o2, addition of Fe to piemontite raises its thermal stability and slightly decreases its sensitivity to oxygen fugacity. Reversal study of the reaction: Fe-piemontite + quartz = garnet (Gr₃₃Sp₂₇And₄₀) + anorthite + fluid at P_fluid= 2 kbar in cold-seal apparatus using solid oxygen buffers was completed. The data indicated breakdown of Pm₁₇Ps₁₇Cz₆₆ at 645°± 10° C along the Cu₂O–CuO buffer, 477°± 10° C along the Cu–Cu₂O buffer, and 365°± 10° C for the hematite-magnetite buffer. Mn-free clinozoisite and epidote have been shown to be stable to much higher temperatures than piemontite at moderate f_o2 (< Cu–Cu₂O). At very high f_o2, however, the presence of Mn⁺³ in a distorted octahedral site may permit persistence of piemontite to higher temperatures than Mn-poor epidote minerals. The compositional range of natural Fe–Mn–Al piemontites supports these results. Cation partitioning from piemontite-bearing parageneses also indicates crystallization at high f_o2, but application of the cited results should be made with caution. Synthetic phases were too fine-grained for optical or microprobe analysis, and reaction was often incomplete. The assumption that all Fe + Mn was contained in piemontite and garnet, respectively, in the low- and high-temperature assemblages is supported by the cell dimensions for these synthetic minerals, which are close to predicted values. The reaction is pseudo-univariant, as solid solution in garnet and piemontite would be f_o2-dependent in a more complex chemical system. Although bulk rock and fluid compositions may also have a marked effect on the stability of natural epidote–piemontite, f_o2 is the major control on Fe : Mn : Al in epidote minerals.     

Clay mineral records of East Asian monsoon evolution during late Quaternary in the southern South China Sea

High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 190 ka during late Quaternary from core MD01-2393 off the Mekong River in the southern South China Sea are reported to reconstruct a history of East Asian monsoon evolution. The dominating clay mineral components indicate a strong glacial-interglacial cyclicity, with high glacial illite, chlorite, and kaolinite contents and high interglacial smectites content. The provenance analysis indicates the direct input of clay minerals via the Mekong River drainage basin. Illite and chlorite derived mainly from the upper reach of the Mekong River, where physical erosion of meta-sedimentary rocks is dominant. Kaolinite derived mainly from active erosion of inhered clays from reworked sediments in the middle reaches. Smectites originated mainly through bisiallitic soils in the middle to lower reaches of the Mekong River. The smectites/(illite+chlorite) and smectites/kaolinite ratios are determined as mineralogical indicato     

Refined relationship between the position of the fundamental OH stretching and the first overtones for clays

The aim of this paper is to determine a relationship between the wavenumbers of the first OH-stretching overtones (W_2OH) and the wavenumbers of the OH-stretching fundamentals (W_OH) to help to interpret the near-infrared (NIR) spectra. The first overtone (2OH) bands appear at wavenumbers less than twice those of the fundamental bands (OH), due to the anharmonic character of vibrations, X = W_2OH/2 - W_OH, with X being the anharmonicity constant. Talc samples with various crystal chemistries are used to solve the equation and the experimental data are well fitted with X = –85.6 cm^–1. As far as the authors are aware, it is the first time that the anharmonicity constant for the OH-stretching vibrations is determined for phyllosilicates. The anharmonicity constant remains almost unchanged for several types of clay samples. Therefore the relation, established from talc samples because their absorption bands are narrow and their wavenumber range of OH vibrations is wide, can be used for any other clay minerals.     

Features of clay minerals in the YSDP102 core on the continental shelf of the southeast Yellow Sea

Ninety-eight clay mineral samples from the YSDP102 core were analyzed by x-ray diffractometer to study the four clay minerals: illite, chlorite, kaolinite and smectite. Twenty-eight samples had been analyzed on the laser particle-siz eanalyzer to reveal the particle features of the sediments. Distribution of the clay minerals and the particle characteristics in the YSDP102 core show that the core experienced three different depositional periods and formed three different sedimentary intervals due to different sediment sources and different depositional environments. Features of the clay minerals and the heavy minerals in the YSDP102 core indicate that coarse-grained sediments and fine-grained sediments result from different sources. The Yellow Sea Warm Current has greatly influenced the sedimentary framework of this region since the current‘s formation.     

海洋粘土沉积物的组成及其增白试验

为了海洋粘土的开发应用,利用FTIR和XRD衍射对其进行了矿物成分分析。结果表明,海洋粘土样品中粘土矿物含量较高,其主要矿物组成为伊/蒙混层和伊利石并含有少量其它矿物,同时证实样品中有磁铁矿和赤铁矿存在。粘土沉积物的化学成分分析显示,粘土中Fe2O3质量分数较高,约为7%。采用酸溶氢气还原法对东太平洋的粘土样品进行了化学增白试验,并探讨了酸种类及其浓度、药剂用量、反应时间、煅烧温度等因素对除铁增白效果的影响,优选出最佳除铁增白方案,使海洋粘土的白度由原来的23.8%提高到73.1%。另外,对增白前后样品的粒度、比表面积和分散性的测试表明,在增白的同时样品的活性也得到了提高。