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111.
G. Urbano A.M. Meléndez V.E. Reyes M.A. Veloz I. González 《International Journal of Mineral Processing》2007
The galvanic effect between the main associated mineralogical phases in a mineral sphalerite concentrate was evaluated using an alternative methodology. Comparative voltammetric studies were performed between high purity galena mineral (94.65%) and sphalerite concentrate (content of 78.11% sphalerite, ZnS; 13.64% galena, PbS; 0.57% chalcopyrite, CuFeS2; 0.41% cadmium sulfide, CdS; and 0.11% arsenopyrite, FeAsS) using carbon paste electrodes (CPE) in order to identify galvanic interactions that affect their reactivity. The electrolyte was an aqueous solution of 0.1 M NaNO3 (pH 6.5). The results showed that, in sphalerite concentrate, the electrochemical reactivity of the galena was diminished and displaced to more positive potentials with respect to the high purity galena mineral response. This behavior can be attributed to the galvanic protection offered by the sphalerite on the galena, thereby avoiding its free oxidation. On the other hand, sphalerite oxidation was diminished by the formation of a passive products film that is dissolved to more positive potentials which provokes oxidation of other minerals like CuFeS2, (Zn,Cd)S and FeAsS present in a minor proportion in the sphalerite concentrate. 相似文献
112.
In western Victoria, a widespread stratiform style of gold enrichment in Palaeozoic black mudstone and chert—clearly different from the classic mesothermal quartz vein deposits of the Victorian goldfields—has been confirmed by whole-rock geochemistry and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICPMS). This enrichment pre-dates compaction, deformation and low-grade metamorphism of the sedimentary host-rocks, and therefore possibly developed diagenetically during slow deposition of the thin carbonaceous black mudstone beds and the thinner layers of chert. These paired strata have been documented at many locations in three regional outcrop areas of chevron-folded Cambrian and Lower Ordovician metasediments in the Stawell and Bendigo Zones, where they are interbedded with quartz-rich turbidites. The layers were named ‘indicators’ by the early miners, who found locally rich nuggety gold deposits at intersections between these layers and mesothermal quartz veins. Gold is present in euhedral pyrite crystals in both black shale and chert. LA-ICPMS analysis of individual pyrite crystals in the indicator beds shows that pyrite is enriched in Au, As, Sb, Se, Te and Bi. The Au content of pyrite varies from 0.03 to 2.69 ppm with a mean of 0.58 ppm and shows a positive correlation with As, which varies from 1000 to 6000 ppm. Many pyrite crystals show enrichment of gold in their cores and depletion in their rims, confirming the likely syngenetic or syndiagenetic accumulation of gold during pyrite formation in the sediments. Prior to regional metamorphism, folding and faulting, the many indicator strata in the outcrop areas were parts of an extensive marine sequence of Late Cambrian and Early Ordovician age. The former primary source of this mineralisation is considered to have been one or more contemporaneously exhalative submarine hydrothermal systems. Thus, the older Palaeozoic sediments of the western Lachlan Fold Belt were significantly enriched in syngenetic gold in the Early Palaeozoic, at least 40 million years before emplacement of the quartz – gold vein deposits of the goldfields. 相似文献
113.
Atomistic calculations of structural and elastic properties of serpentine minerals: the case of lizardite 总被引:1,自引:0,他引:1
A.-L. Auzende R. J.-M. Pellenq B. Devouard A. Baronnet O. Grauby 《Physics and Chemistry of Minerals》2006,33(4):266-275
The physical properties of the hydrous phyllosilicate lizardite have been investigated by atomistic simulation using the GULP code based on transferable semi-empirical interatomic potentials. Lizardite behavior was first investigated during structure relaxation at room temperature. The Helmholtz free energy is minimum for an equilibrium structure that is in agreement with experiment. The bulk, shear, and Young modulii for lizardite were calculated along with the Poisson ratio. From the shear and bulk modulii, we also calculated translational and longitudinal acoustic wave velocities that are important quantities for tectonophysics models. As expected, lizardite is stiffer in the a direction parallel to the layers than in the c perpendicular direction; the variation of the unit cell parameters with pressure is in good agreement with experiment. The cohesive energy between two successive layers along c direction was calculated at 0.33 eV (i.e., 0.11 eV per OH bond) in good agreement with recent ab initio calculations. Upon pressure and temperature variations, we evidenced that structural changes are mainly pressure induced; pressure being accommodated by a decrease of the c parameter up to 10 GPa. We also found that the change of slope in the derivative of the c cell parameter with respect to pressure occurring around 2 GPa originates from the bending of the interlayer hydroxyl groups with respect to the layer normal direction. 相似文献
114.
115.
发现天然产高压相矿物的微矿物学途径 总被引:2,自引:0,他引:2
迄今人们已经在陨石中发现了11种高压相矿物,它们是地幔过渡带和下地幔的主要矿物相,其中有8种是最近5年来随着研究工作的深入和微矿物学 技术的不断发展而连续发现的。1995年在寺巷口陨石中发现了属于地幔过渡带的林伍德石、 瓦茨利石、镁铁榴石、镁方铁矿和磷酸盐A相,随后又参与了陨石中其它新高压同质多像矿 物的发现和研究。在工作中使用了多种近代微矿物学技术,特别是激光拉曼探针和原位X射线显微分析技术在鉴定中起了关键作用。 相似文献
116.
117.
滇西北中甸地区的铜金找矿远景 总被引:5,自引:0,他引:5
滇西北中甸地区的铜,金矿产,分别以印支期和喜马拉雅期作为主要成矿期。铜矿分西矿带和东矿带。西矿带重点应加强欧赛拉-阿热-带的铜(多金属)矿勘查;东矿带的独哥-地苏嘎-欠虽一带是寻找斑岩型铜多金属矿最有远景的地区。寻找喜马拉雅期金矿床,重点应放在甭哥以东的富碱斑岩出露区。 相似文献
118.
An improvement on the new method of Intervalhalving-Scanning (INS) proposed by the senior author for derivation of thermodynamic properties of minerals from reversed experiment (REP) data has been made in the present work. The treatment of the REP data of 6 reactions in the system MgO-SiO_2-H_2O and the derivation of △_(?)H(?) (298. 15K) for minerals Talc,Forsterite and Anthophyllite are chosen as an example for demonstration of the application of the method.INS is quite different from all the methods for the derivation in the literature and throughout based on thermodynamic principles and equations so that its thermodynamical validity is thoroughgoing. 相似文献
119.
N. G. Vashchenkova M. T. Gorovaya A. V. Mozherovskii 《Russian Journal of Pacific Geology》2009,3(3):249-259
The Argillite Sequence located at the base of the sedimentary cover on the continental slope of the Sea of Japan was studied by petrographic, palynological, and X-ray diffraction methods. Two spores-pollen complexes were distinguished in it: the Late Oligocene reflecting cooling and the Early Miocene corresponding to initiated warming. The data obtained indicate that the sequence is composed of terrigenous silty-clayey sediments that accumulated in shallow coastal-marine settings. The global sea-level rise at the Early-Middle Miocene transition, combined with the regional tectonic processes, determined the basin deepening, owing to which the argillite sequence was overlain by thick Middle Miocene diatomaceous-clayey sediments. Due to tectonic movement along existing faults in the terminal Late Miocene, the argillite sequence occurring initially at depths of at least 400–500 m was locally exhumed to the basin bottom. 相似文献
120.