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61.
本文研究了在pH 6.5-7.8的(CH_2)_6N_4-HCl缓冲介质中,CDMAA和TritonX-100对Ga与o-Cl-PF和F~-显色反应的增敏作用。结果表明,Ga-o-Cl-PF-F-CDMAA-TritonX-100多元配合物λ_(max)为565nm,表观摩尔吸光系数ε=1.74×10~5L·mol~(-1)·Cm~(-1),Ga含量在0~6.0μg/25ml范围内符合比尔定律,用合成样和标样进行本方法考验,结果满意。 相似文献
62.
Nitrogen and sulfur species in Antarctic aerosols at Mawson,Palmer Station,and Marsh (King George Island) 总被引:4,自引:0,他引:4
D. L. Savoie J. M. Prospero R. J. Larsen F. Huang M. A. Izaguirre T. Huang T. H. Snowdon L. Custals C. G. Sanderson 《Journal of Atmospheric Chemistry》1993,17(2):95-122
High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na+, SO
4
2–
, NO
3
–
, methanesulfonate (MSA), NH
4
+
,210Pb, and7Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na+, 68–151 ng m–3; NO
3
–
, 25–30 ng m–3; nss SO
4
2–
, 81–97 ng m–3; MSA, 19–28 ng m–3; NH
4
+
, 16–21 ng m–3;210Pb, 0.75–0.86 fCi m–3. Results from multiple variable regression of non-sea-salt (nss) SO
4
2–
with MSA and NO
3
–
as the independent variables indicates that, at Mawson, the nss SO
4
2–
/MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO
4
2–
during transport over Antarctica from the oceanic source region. The mean210Pb concentrations at Palmer and Marsh and the mean NO
3
–
concentration at Palmer are about a factor of two lower than those at Mawson. The210Pb distributions are consistent with a210Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO
3
–
and210Pb at Mawson support the conclusion that the primary source regions for NO
3
–
are continental. In contrast, the mean concentrations of MSA, nss SO
4
2–
, and NH
4
+
at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO
4
2–
by 10%; and NH
4
+
by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH
4
+
/(nss SO
4
2–
+MSA) equivalent ratios indicate that NH3 neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March. 相似文献
63.
64.
65.
复杂构造应力扰动场与发震构造识别问题的研究 总被引:7,自引:2,他引:7
在地震短临阶段异常是由局部断层扩展或弱化引起。实验与数值模拟结果曾得到与之相伴的是平均应力扰动场的四象限分布和最大剪应力扰动场的八瓣式分布。为检验此结果的普适性作了进一步的研究。结果表明不论区域构造及其基本应力场如何复杂,这种四象限分布与八瓣式分布型式不变,这为最终判定失稳区提供了依据。与此同时,在复杂构造情况下这种应力扰动场的畸变也不容忽视 相似文献
66.
67.
The paper focuses on the seismic response of walls in dual (frame + wall) structures, with particular emphasis on shear behaviour.
Although dual structures are widely used in earthquake-resistant medium-rise and high-rise buildings, the provisions of modern
seismic codes regarding design of walls for shear are not fully satisfactory, particularly in the (common) case that walls
of substantially different length form part of the same structure. Relevant provisions of the leading seismic codes are first
summarised and their limitations discussed. Then an extensive parametric study is presented, involving two multistorey dual
systems, one with identical walls, and one with walls with unequal length, designed to the provisions of Eurocode 8 for two
different ductility classes (H and M). The walls of the same structures are also designed to other methods such as those used
in New Zealand and Greece. The resulting different designs are then assessed by subjecting the structures to a suite of strong
ground motions, carrying out inelastic time history analysis, and comparing the results against design action effects. It
is found that although modern code procedures generally lead to satisfactory performance (differences among them do exist),
the design of walls seems to be less appropriate in the case of unequal length walls. For this case a modified procedure is
proposed, consisting of an additional factor to account for the relative contribution of walls of the same length to the total
base and an improved envelope of wall shears along the height; this improved method seems to work better than the other procedures
evaluated herein, but further calibration is clearly required. 相似文献
68.
介绍了新水溶性显色剂 2 - ( 2 ,3,5 -三氮唑偶氮 ) - 1 ,8-二羟基 - 3,6-萘二磺酸与钴的显色反应及应用 ,建立了测定钴的新方法。在 pH 9.9的Na2 B4O7 NaOH缓冲液中该试剂与钴形成 1∶1蓝色稳定络合物 ,λmax为 5 88.8nm ,Co的质量浓度在 0~ 1 .0mg/L内符合比尔定律 ,表观摩尔吸光系数为 3.46× 1 0 4 L·mol- 1 ·cm- 1 。所拟方法用于环境水样及维生素B1 2 注射液中的微量钴测定 ,结果与原子吸收法相符 ,5次测定的RSD <1 %。 相似文献
69.
有机试剂4-(6-甲氧基-8-喹啉偶氮)-间苯二酚的合成和结构分析 总被引:1,自引:0,他引:1
徐建强 《南京气象学院学报》2001,(4)
以 6-甲氧基 - 8-氨基喹啉为原料 ,经重氮化后与间苯二酚偶联 ,合成了有机试剂 4- (6-甲氧基 - 8-喹啉偶氮 ) -间苯二酚 (简称 MQAR) ,用 DMF重结晶精制。通过TL C、EA、UV- VIS、IR、1 HNMR等分析手段 ,对合成产物进行分析和结构鉴定 ,确证得到了 MQAR纯品 ,产品熔点为 1 94℃。 相似文献
70.
对中国大陆1970年以来12组7级以上地震进行了前后10年左右地震时间间隔序列的R/S分析,滑动计算其Hurst指数H值。H值的时间进程显示,9组大震前2年左右H值在较为稳定的背景上开始出现异常变化,其异常特征为“下降-低值-回升”,地震大多发生在H值回升的过程中,具有中、短期前兆意义。H值的异常过程揭示了在大震孕震系统内地震活动从无序向有序的时间演化过程。 相似文献