White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

山西能源重化工基地建设研究

山西能源重化工基地建设关系到全国四个现代化的实现,被列为国家重点建设工程,制定了《山西能源重化工基地综合规划》。本文分析了80年代山西省经济建设的成就与问题。提出了“整体创新,综合开发”,把山西能源重化工基地建设成内陆经济开放区的战略大思路,为此,90年代应完成11项大型经济战略工程,同时展望了经济发展改革前景。     

Towards a method for postcolonial development geography? Possibilities and challenges

In this paper we explore the contours of a 'method' for postcolonial development geography, which makes it possible to imagine another 'world-picturing'. We suggest three steps towards such a method. First, we propose that a postcolonial method involves thinking about why we are doing research in the south in the first place; how we come to and produce our questions; and how we analyze and represent our findings based on our subject positionings. Second, that we need to recognize theorization as an inherent part of method, rethink how we currently theorize and reconfigure our methods of theorization to address wider political aims. Problematizing theorization helps challenge the universalism of Eurocentric theories, thus enabling development geography to move towards more decolonized versions and visions. Finally, that this must be accompanied by firmer recognition of our multiple investments – personal, institutional and geopolitical – and how they frame the possibilities for change. These are some possible steps that we think can reconfigure the 'scholarly track' that postcolonial development geographers traverse.     

Reconstruction of the diagenesis of the fluvial-lacustrine- deltaic sandstones and its influence on the reservoir quality evolution-- Evidence from Jurassic and Triassic sandstones, Yanchang Oil Field, Ordos Basin

The reservoir quality of Jurassic and Triassic fluvial and lacustrine-deltaic sandstones of the Yanchang Oil Field in the Ordos Basin is strongly influenced by the burial history and facies-related diagenetic events. The fluvial sandstones have a higher average porosity (14.8%) and a higher permeability (12.7×10?3 ?m2) than those of the deltaic sandstones (9.8% and 5.8 ×10?3 ?m2, respectively). The burial compaction, which resulted in 15% and 20% porosity loss for Jurassic and Triassic sandstones, respectively, is the main factor causing the loss of porosity both for the Jurassic and Triassic sandstones. Among the cements, carbonate is the main one that reduced the reservoir quality of the sandstones. The organic acidic fluid derived from organic matter in the source rocks, the inorganic fluid from rock-water reaction during the late diagenesis, and meteoric waters during the epidiagenesis resulted in the formation of dissolution porosity, which is the main reason for the enhancement of reservoir-quality.     

资源环境与社会经济协调发展探析

文章首先回顾了资源环境与社会经济发展的理论，提出资源环境与社会经济协调发展内涵：一方面，要在资源环境承载力范围内发展社会经济，追求社会经济发展的最大化，另一方面，环境承载力是动态的，要依靠社会经济发展不断提高，这两个方面是相互作用、相互制约的。在此基础上，详细论述了资源环境与社会经济协调发展的内容,并从社会经济发展、资源环境管理等角度探讨了资源环境与社会经济协调发展的政策调控，通过建立节约型国民经济体系、深化资源环境管理，实现区域一体化，以保证资源环境与社会经济协调发展的实现。     

Some Aspects of Resource Uncertainty and Their Economic Consequences in Assessment of the 1002 Area of the Arctic National Wildlife Refuge

Natural Resources Research - Exploration ventures in frontier areas have high risks. Before committing to them, firms prepare regional resource assessments to evaluate the potential payoffs. With...