新显色剂四-(3-磺基-4-氯苯基)卟啉分光光度法测定微量铜

研究了新显色剂四-(3-磺基-4-氯苯基)卟啉在微酸性介质中,表面活性剂OP与CPC存在下测定微量铜的显色反应。络合物在波长420 nm处有最大吸收峰,摩尔吸光度系数为3.44×105L·mol-1cm-1,用双峰双波长光度法测定摩尔吸光系数为6.72×105L·mol-1·cm-1,铜含量在0.5~4.5μg/25 m L范围内符合比耳定律。方法应用于矿样中微量铜的测定,结果令人满意。     

现代测绘与数字地球──迎接21世纪的挑战

本文简要介绍了现代测绘性质、作用、地位及本学科的发展方向;较为详细叙述了现代测绘的主要技术的发展状况及 ３Ｓ集成的广阔应用前景;简述了数字地球的概念及其主要支撑技术、与现代测绘关系,及现代测绘的主要任务;在迎接２１世纪的挑战中,提出一些建议,供研究参考。     

铜藻(Sargassum horneri)在营养限制胁迫后对NH4-N的超补偿吸收研究

以经济马尾藻铜藻(Sargassum horneri)为研究材料,研究了其在营养限制胁迫后对NH_4-N的超补偿吸收情况。实验分营养限制和恢复营养两个阶段进行,每个阶段均设置饥饿处理组、饱和处理组和正常对照组。铜藻在低营养限制胁迫(饥饿)下培养10天后,恢复营养盐培养3天,分别采用次溴酸盐氧化法和锌镉还原法测定培养液中的NH_4-N和NO_3-N的浓度。本文研究发现,饥饿处理组中铜藻吸收氨氮的速率远高于正常对照组和饱和处理组,在恢复培养第一天时,饥饿处理组对NH_4-N的吸收速率最高为14.94μmol/(g·h),与正常对照组及饱和处理组间差异显著。在恢复培养的后两天,三个处理组中铜藻对NH_4-N的吸收速率差异慢慢变小,直至最后几乎相同。三组对NO_3-N没有表现出较高的吸收,最高仅为6.15μmol/(g·h),结果表明:氮源包括NH_4-N和NO_3-N时,铜藻优先选择吸收NH_4-N。实验后称重测定生长速率:对照组、饥饿处理组和饱和组生长率(SGR)分别为8.48%、8.86%、8.01%,ANOVA方差分析表明,三者存在显著差异(P=0.0320.05),从而证实了铜藻也存在超补偿生长的现象。     

CaTiO3－钙钛矿的晶体结构相变、高温流变及其下地幔地球动力学意义

利用高精度的ＭＴＳ材料实验系统,在１４７３－１６７３Ｋ的温度区间和可控热力学环境条件下,对［１００］ｐｃ和［１１０］ｐｃ两个方位的ＣａＴｉＯ3－钙钛矿单晶体进行了高温蠕变试验,着重观测了晶体结构相变和高温流变的相关性．研究表明,钙钛矿的晶体结构相变对其高温流变性质有明显影响,斜方晶系钙钛矿蠕变强度大大高于四方和立方晶系钙钛矿,后两者具有很强的高温塑性各向异性．在分析相变过程晶体结构变化特征和观测到的高温流变数据基础上,认为钙钛矿晶体结构相变中发生的位错结构的变化是导致其高温流变性变化的主要物理机制．     

三维F－K域DMO方法及应用效果

在常速情况下,从三维时距方程出发,通过倾角代换,将三维倾角时差分裂为两个正交方向上的二维倾角时差,然后在这两个正交方向上分别做一次二维倾角时差校正,便可达到三维倾角时差校正的目的．应用实例表明这种三维ＤＭＯ分裂方法是切实有效的．     

Numerical study of the 3D failure envelope of a single pile in sand

The paper presents a comprehensive study of the failure envelope (or capacity diagram) of a single elastic pile in sand. The behavior of a pile subjected to different load combinations is simulated using a large number of finite element numerical calculations. The sand is modeled using a constitutive law based on hypoplasticity. In order to find the failure envelope in the three-dimensional space (i.e. horizontal force H, bending moment M and vertical force V), the radial displacement method and swipe tests are numerically performed. It is found that with increasing vertical load the horizontal bearing capacity of the pile decreases. Furthermore, the presence of bending moment on the pile head significantly influences the horizontal bearing capacity and the capacity diagram in the H–M plane manifests an inclined elliptical shape. An analytical equation providing good agreement with the 3D numerical results is finally proposed. The formula is useful for design purposes and the development of simplified modeling numerical strategies such as macro-element.     

双巷三维并行电法数值及物理模型试验研究

电法勘探是一种以研究地下探测目标体与周围介质之间的电性差异的地球物理探测方法,通常采用的二维电法勘探只能得到一条垂直于测线的视电阻率剖面,如果不能确定测线位置正好在异常体的正上方,这时就难给出较准确的结论。三维电阻率法采集数据量大,可获得三维电性数据体,而且可方便地根据需要实现水平及垂直切片,有着二维电法探测不能比拟的优点,实现对目标体的准确定位及全面透视。通过对构建的三维地质模型体进行数值模拟和物理模拟,表明双巷并行三维电法对地质异常体可以进行有效的探查并获得良好的探测效果。     

Predicting the displacement of triple pendulum™ bearings in a full‐scale shaking experiment using a three‐dimensional element

The accuracy of a series spring model to predict the peak displacement and displacement history of Triple Pendulum? (TP) bearings in a strongly shaken, full‐scale building is evaluated in this paper. The series spring model was implemented as a self‐contained three‐dimensional TP bearing element in OpenSees and is now available for general use. The TP bearing element contains the option for constant friction or a generalized friction model that accounts for the effect of instantaneous velocity and compression load on the friction coefficient. Comparison between numerical simulation and experimental data of a five‐story steel moment frame building shows that the peak displacement of isolation system can generally be predicted with confidence using a constant friction coefficient model. The friction coefficient model accounting for the effect of axial load and velocity leads to minor improvement over the constant friction coefficient models in some cases. Copyright © 2013 John Wiley & Sons, Ltd.     

核废物地质处置中热-水-应力耦合对迁移影响的三维有限元模拟

将所建立的热-水-应力-迁移耦合模型及开发的有限元程序,由二维分析拓展到三维分析,并从方法论研究的角度,以一个简单的核废物地质处置模型为算例,进行热-水-应力-迁移耦合过程的三维数值模拟,考察了近场的温度、饱和度、核素浓度、孔隙水压力、位移、正应力、流速等的分布与变化,认为计算结果符合规律,得出了若干结论：为了精确地模拟放射性核素迁移,就必须将温度场、渗流场、应力场和核素浓度场进行耦合分析;核废物埋存若干年后将在处置孔壁附近产生较高的压应力;缓冲层内各点的核素浓度达到相对稳定的时间要比温度和饱和度达到相对稳定的时间长得多。     

Polar constituents of organic matter rich marls from evaporitic series of the Mulhouse basin

A suite of marl samples from the evaporitic series of the Mulhouse basin (France; Lower Oligocene) was studied for its biomarker content, in particular its polar constituents. Novel series of 3-carboxyalkyl steranes and 15-oxo triaromatic ketones were identified by synthesis. The 3-carboxyalkyl steranes probably originate from highly polar precursors yet unreported in living organisms. Our data suggest that micro-algae could be the major source of these compounds which seem to be indicators of high algal input rather than characteristic of evaporitic environments. The 15-oxo triaromatic ketones could be oxidation products of triaromatic steroid hydrocarbons formed during diagenesis, although their formation during work-up procedure could not be excluded.