中国西北地区剪切波三维速度结构

本文研究区包括中国西北地区几个不同的构造单元,即准噶尔、阿尔泰、天山、内蒙古褶皱、塔里木盆地、柴达木和祁连山地区.从群速度和剪切波速度模型上可以看出,除塔里木具有十分明显的稳定构造体特征外,其它地区均具构造活动地区的特征,但其速度表现各具特点,并与它们的构造演化史有关.莫霍界面的起伏基本上控制了布格重力异常的分布;另外,天山地区与北山的速度结构在土地幔盖层中差别很大,天山的上地幔高速盖层可能与应力场有关.     

二维横向各向同性介质中人为边界反射的吸收——差分法弹性波场模拟

本文对有限差分法弹性波场三分量正演模拟中遇到的人为边界反射问题进行了研究,分别获得2-D横向各向同性介质中U_x,U_z,与U_y位移分量模拟时的边界吸收条件.从吸收边界上反射系数与入射角之间的关系可以说明,本文提出的边界吸收条件的吸收能力比较强.     

拟合法15°波动方程有限差分串联偏移

本文把最佳拟合算法（三点和五点差分格式）及串联偏移方法应用在15°波动方程偏移中。由于拟合法的差分因子随着采样间隔、步长、速度等参数的变化而变化,因此与原有的波动方程差分偏移法相比,串联偏移方法能有效的使大倾角归位,克服频散,速度及步长可以灵活变化,运算效率高等优点。     

Li3N·LiI·LiCl锂快离子导体研究

采用固态反应的方法制备Li_3N·LiI·LiCl快离子导体样品。使用X—射线衍射分析和差热分析的方法进行物相鉴定。电化学性能测试结果表明,样品具有较高的离子电导率,在100℃,其电导率可达10~(-4)_s/cm量级。样品的电导率与温度的关系很好地遵循Arrhenius方程。测得样品的电导活化能E_a为0.45eV。     

地球弓激波前的低频磁流体波

一、引言 在地球弓激波前存在着低频磁流体波。这种低频磁流体波是太阳风在地球弓激波上的反射粒子和太阳风粒子之间相互作用产生的。根据人造卫星的观测资料可以得到,在地球弓激波前,Pc3-4脉动频率范围内的低频磁流体波的主频率和行星际磁场强度     

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。     

3D chemical model for geological macromolecules

This study defines a chemical representation of the kerogen macromolecule based on data from physicochemical analyses. The model should permit: creation of various schematic drawings representing an average macromolecule; future integration of new analytical results (for instance on structures of biomarkers or biopolymers); and determination of the distribution of chemical bonds.The models developed in this study can be represented in a 3D space, using classical chemical symbols, in the form of cyclic groups linked to each other by aliphatic chains. One cyclic group is a connected set of aromatic, naphthenoaromatic or naphthenic rings. These cyclic groups are constructed using basic elements such as atoms and bonds defined by their length and direction.Modeling of kerogen is done in three successive steps. A library is first created to define atoms, bonds and cyclic groups. Secondly, starting from a set of equations describing the analytical results, cyclic and aliphatic groups are chosen in the appropriate stoechiometric amount to match the analytical data. Finally the construction is done: cyclic groups are placed randomly in a 3D space, connections are made by aliphatic chains, and functional groups are added.The molecular modeling software Xmol^TM can be operated on APOLLO stations. It allows the creation of libraries, the calculation of chemical bonds corresponding to the analyses and the construction of macromolecules. An example is given for a type III kerogen at the beginning of diagenesis.     

Identification and occurrence of novel C36–C54 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.     

康定片麻岩岩石化学特征的初步研究

川西地区康定片麻岩(原称澄江—晋宁期岩浆岩第Ⅳ期的酸性岩)的主体是富钠质的英云闪长质-奥长花岗质片麻岩(灰色片麻岩);尚有少量花岗质片麻岩,系灰色片麻岩遭受钾质交代而成。其岩石化学特征与太古代花岗地体一致.灰色片麻岩属低铝型,以相对富铁和不具Eu异常为特征。它与川滇交界区晚太古代垭口片麻岩等一起构成川西滇中地区的片麻岩基底.     

中国西部三维速度结构及其各向异性

本文用覆盖中国的358条勒夫面波路径资料,研究了10.45-113.80s范围内中国西部的三维SH波速度结构.结果表明,各构造单元的SH波速度结构均有明显的差别.作为稳定块体的塔里木盆地,壳内重力分异程度较高,上、中、下地壳厚度差别小,壳内无明显的低速层,地壳平均速度比较小;上地幔低速层埋深大且层中速度大;区内横向变化小.构造活动区如天山、青藏高原,其突出的特征是下地壳厚度大且速度大,上地幔盖层速度值相当高.这与西伯利亚、印支板块的挤压有密切的关系.青藏高原东部及其北、东边缘地区壳内存在低速层,上地幔低速层埋深浅,一些地区存在壳幔过渡层.面波各向异性研究表明,青藏高原、天山及印支板块北缘下存在明显的各向异性,以构造边缘地区及上地幔低速层附近最为突出.印度板块、西伯利亚板块与中国大陆间的碰撞引起强大的水平压力和一定的下插作用,是造成青藏高原隆起、地壳增厚、天山隆起的最根本的因素,同时也促成壳幔中辉石、橄榄石的定向排列和物质运移,因而出现明显的各向异性现象.