Precambrian metaplutonic rocks of the São Gabriel block in southernmost Brazil comprise juvenile Neoproterozoic calc-alkaline gneisses (Cambaí Complex). The connection with associated (ultra-)mafic metavolcanic and metasedimentary rocks (Palma Group) is not well established. The whole complex was deformed during the Brasiliano orogenic cycle. Both metasedimentary and metavolcanic rocks as well as metaplutonic rocks of the Cambaí Complex have been sampled for geochemical analyses in order to get constraints on the tectonic setting of these rocks and to establish a tectonic model for the São Gabriel block and its role during the assembly of West-Gondwana. The major element compositions of the igneous rocks (Palma Group and Cambaí Complex) indicate a subalkaline character; most orthogneisses have a calc-alkaline chemistry; many metavolcanic rocks of the Palma Group show signatures of low-K tholeiitic volcanic arc basalts. Trace element data, especially Ti, Zr, Y, Nb, of most igneous samples from both the lower Palma Group and the Cambaí Complex indicate origin at plate margins, i.e., in a subduction zone environment. This is corroborated by relative enrichment in LREE, low contents of Nb and other high field strength elements and enrichment in LILE like Rb, Ba, and Th. The data indicate the possible existence of two suites, an oceanic island arc and a continental arc or active continental margin. However, some ultramafic samples of the lower Palma Group in the western São Gabriel block indicate the existence of another volcanic suite with intra-plate character which possibly represents relics of oceanic island basalts (OIB). Trace element data indicate contributions from andesitic to mixed felsic and basic arc sources for the metasedimentary rocks. The patterns of chondrite- and N-MORB-normalized spider diagrams resemble the patterns of the igneous rocks, i.e., LILE and LREE enrichment and HFS depletion. The geochemical signatures of most igneous and metasedimentary samples and their low (87Sr/86Sr)t ratios suggest only minor contribution of old continental crust.A geotectonic model for the São Gabriel block comprises east-ward subduction and following accretion of an intra-oceanic island arc to the eastern border of the Rio de la Plata Craton at ca. 880 Ma, and westward subduction beneath the newly formed active continental margin between ca. 750 and 700 Ma. The São Gabriel block represents relics of an early Brasiliano oceanic basin between the Rio de la Plata and Kalahari Cratons. This ocean to the east of the Rio de la Plata Craton might be traced to the north and could possibly be linked with Neoproterozoic juvenile oceanic crust in the western Brasília belt (Goiás magmatic arc). 相似文献
During the period between 18 August and 22 September 2006, an ultraviolet
photometric O3 analyzer, a NO-NO2-NOx chemiluminescence
analyzer, and a quartz micro-oscillating-scale particle concentration
analyzer were simultaneously used for monitoring at three different heights
each at Beijing (325-m tower) and Tianjin (255-m tower). These towers belong
to the Institute of Atmospheric Physics (IAP) of the Chinese Academy of
Sciences (CAS) and to the Tianjin Municipal Meteorological Bureau,
respectively. These measurements were used to continuously measure the
atmospheric O3 and NOx volume-by-volume concentrations and the
PM2.5 mass concentration within a vertical gradient. When combined with
meteorological data and information on the variation of vertical
characteristics of the various atmospheric pollutants in the two cities,
analysis shows that these two cities were seriously polluted by both
PM2.5 and O3 during summer and autumn. The highest daily-average
concentrations of PM2.5 near the ground in Beijing and Tianjin reached
183 μg m-3 and 165 μg m-3, respectively, while the O3 concentrations reached 52 ppb and 77 ppb, and NOx concentrations
reached 48 ppb and 62 ppb for these two cities, respectively. The variations
in the daily-average concentrations of PM2.5 between Beijing and
Tianjin were demonstrated to be consistent over time. The concentrations of
PM2.5 measured in Beijing were found to be higher than those in
Tianjin. However, the overall O3 concentrations near the ground in
Tianjin were higher than in Beijing. NOx concentrations in Tianjin were
consistently lower than in Beijing. It was also found that PM2.5
pollution in Beijings atmosphere may also be affected by the pollutants
originating in and delivered from Tianjin, and that Ti 相似文献
Magma mixing structures from the lava flow of Lesbos (Greece) are analyzed in three dimensions using a technique that, starting from the serial sections of rock cubes, allows the reconstruction of the spatial distribution of magmas inside rocks. Two main kinds of coexisting structures are observed: (i) “active regions” (AR) in which magmas mix intimately generating wide contact surfaces and (ii) “coherent regions” (CR) of more mafic magma that have a globular shape and do not show large deformations. The intensity of mingling is quantified by calculating both the interfacial area (IA) between interacting magmas and the fractal dimension of the reconstructed structures. Results show that the fractal dimension is linearly correlated with the logarithm of interfacial area allowing discrimination among different intensities of mingling.
The process of mingling of magmas is simulated using a three-dimensional chaotic dynamical system consisting of stretching and folding processes. The intensity of mingling is measured by calculating the interfacial area between interacting magmas and the fractal dimension, as for natural magma mixing structures. Results suggest that, as in the natural case, the fractal dimension is linearly correlated with the logarithm of the interfacial area allowing to conclude that magma mixing can be regarded as a chaotic process.
Since chemical exchange and physical dispersion of one magma inside another by stretching and folding are closely related, we performed coupled numerical simulations of chaotic advection and chemical diffusion in three dimensions. Our analysis reveals the occurrence in the same system of “active mixing regions” and “coherent regions” analogous to those observed in nature. We will show that the dynamic processes are able to generate magmas with wide spatial heterogeneity related to the occurrence of magmatic enclaves inside host rocks in both plutonic and volcanic environments. 相似文献