The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

EPR investigation of the methyl radical,the hydrogen atom and carbon oxide radicals in Maxixe-type beryl

The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1 signal typical for the CH₃ radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g _// = 2.00263, g _⊥ = 2.00249 and A_// = 2.288 mT, A_⊥ = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A ₀ = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g _// = 2.00265, g _⊥ = 2.00625 and A_// = 0.895 mT, A_⊥ = 0.885 mT, could come from a HCO₃ radical. One narrow and easily saturated signal with g _// = 2.00227 and g _⊥ = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g _// = 2.0017 and g _⊥ = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise from a carbon dioxide radical, which rotates around its symmetry axis.     

溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。     

Numerical Simulation of Residual Circulation due to Bottom Rouglmess Variability Under Tidal Flows in A Semi-Enclosed Bay

Nowadays there are some chronic serious environmental problems, such as eutrophication, blue tide and so on, in a complicated coastal zone or a semi-enclosed bay, because the water exchanges between an inner bay and an outer sea is weak compared with the supply of contaminant. Under this situation, a method to improve the water quality by 3-dimensional small unsymmetrical structures has been proposed by Komatsu et al. In this paper, several numerical simulations of the tidal current and concentration for various arrangements of bottom roughness in a semi-enclosed model bay are carfled out with a depth-averaged 2-D numerical model. The model is solved by the hybrid finite analytic method with nonstaggered grid. And the SIMPLES algorithm with Rhie and Chow＇ s momentum interpolation technique is used for the simulation. The effect of Komatsu＇ s method for water purification is examined by numerical simulation. The result of numerical experiment indicates that it is possible to generate a new tidal residual current and to activate a tidal exchange by bottom roughness arrangement only.     

正压浅海湍流运动的雷诺应力封闭模型

根据湍流封闭理论,建立一种适用于正压浅海湍流运动的雷诺应力封闭模型(RSM),以代替目前三维浅海动力学模型中普遍采用的湍粘性系数的传统假设。通过直接建立并模化f—平面上正压海洋的雷诺应力传输方程,分别得到的微分形式和代数形式的RSM方程组。并讨论了进行数值计算所需要的边界条件。利用该模型可以进一步研究浅海潮流、风暴潮流及风海流等浅海流动的三维结构和湍流特性。     

东营城区高精度三维地震采集方法研究

根据东营城区内建筑物较多，环境干扰较大，地下构造复杂，断裂非常发育，目的层埋藏深，资料信噪比较低的特点，以地震老资料和钻井资料为基础，建立地震地质模型，利用射线追踪技术选取合适的观测系统参数。充分利用卫星数字地图，没计了灵活多变的观测系统，采用可控震源与炸药震源配合使用方法，及时对城区内地下面元的覆盖次数、方位角和炮检距的分布进行质量监控，利用现场处理系统对资料进行及时分析，提高了地震资料品质。所获得的东营城区高精度三维地震采集资料显示，其浅中层分辨率和中深层信噪比都有了明显改善，取得了良好的地质效果。     

Hammerstein型非线性积分方程解的存在性

该文采用化为积分方程组的方法 ,利用锥上不动点指数计算 ,在不要求非线性项 f (x,u)非负的情况下 ,证明 Hammerstein型非线性积分方程 φ(x) =∫Gκ(x,y) f (y,φ(y) ) dy非平凡解和多解存在性的一些新的结果。此结果可用来证明非线性常微分方程两点边值问题解的存在性。     

诊断台风异常路径的三层权重控制点方案

本方案采用850、700、500hPa三个层次的环境平均流场作控制点法。综合考虑这些层次上的引导气流在不同时、空域中的相对重要性。试验结果表明,其效果比单一取某层作引导为佳。且对用来预测台风的未来24小时路径是否异常具有一定的参考价值。     

3D gravity modelling for Anyongbok Seamount in the East Sea

A seamount chain with an approximately WNW trend is observed in the northeastern Ulleung Basin. It has been argued that these seamounts, including two islands called Ulleung and Dok islands, were formed by a hotspot process or by ridge related volcanism. Many geological and geophysical studies have been done for all the seamounts and islands in the chain except Anyongbok Seamount, which is close to the proposed spreading ridge. We first report morphological characteristics, sediment distribution patterns, and the crustal thickness of Anyongbok Seamount using multibeam bathymetry data, seismic reflection profiles, and 3D gravity modeling. The morphology of Anyongbok Seamount shows a cone shaped feature and is characterized by the development of many flank cones and flank rift zones. The estimated surface volume is about 60 km³, and implies that the seamount is smaller than the other seamounts in the chain. No sediments have been observed on the seamount except the lower slope, which is covered by more than 1,000 m of strata. The crustal structure obtained from a 3D gravity modeling (GFR = 3.11, SD 3.82 = mGal) suggests that the seamount was formed around the boundary of the Ulleung Plateau and the Ulleung Basin, and the estimated crustal thickness is about 20 km, which is a little thicker than other nearby seamounts distributed along the northeastern boundary of the Ulleung Basin. This significant crustal thickness also implies that Anyongbok Seamount might not be related to ridge volcanism.