Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

Using numerical modelling to evaluate tsunami hazard near the Kuril Island

A sequence of computer experiments is used to study questions concerning the tsunami problem as a quantitative estimate of tsunami danger, detailed geographical tsunami classification, determination of the parameters of critical tsunami waves, and the conditions of their development. We call a wave critical, if its impact on the coast is most hazardous.Using the Middle Kuril Island as an example, we present the results of a computer experiment which includes determining the wavefields on the shelf and estimating the effects connected with the deep-water Bussol and Diana Straits.Numerical simulation of tsunami waves of different sources permits the assessment of the extent of tsunami danger in different areas of the coastal zone of Simushir Island, depending on the location of the focus zone and their geometry.The major singularities of the wavefield arise in the zones of the deep-water straits. The distribution of the amplification factors is determined by both the global parameters of the wavefields and the local properties of individual harbours. The results obtained for a particular harbour in the northern part of Simushir Island, formed the basis for the quantitative estimate of tsunami danger for this area.     

Enhancement of radon signals in geophysical studies with the track technique

The existence of a suspected geological fault has been confirmed using Solid State Nuclear Track Detectors (SSNTDs) by measuring radon concentration variations in the upper soil above its inferred position. The results obtained prompted us to increase the natural radon signal in the soil, using an additional radon source; this enhancement technique, has been experimentally checked with SSNTD detectors.On leave from Faculté des Sciences, Laboratoire des D.S.T.N. Université de Dakar, Dakar-Fann, Sénégal     

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.     

Fracture analysis in the south-western Corinth rift (Greece) and implications on fault hydraulic behavior

This paper reviews the data concerning the fracture network and the hydraulic characteristics of faults in an active zone of the Gulf of Corinth. Pressure gap measured through fault planes shows that in this area the active normal faults (Aigion, Helike) act, at least temporarily and locally, as transversal seal. The analysis of the carbonate cements in the fractures on both the hangingwall and the footwall of the faults also suggests that they have acted as local seals during the whole fault zone evolution. However, the pressure and the characteristics of the water samples measured in the wells indicate that meteoric water circulates from the highest part of the relief to the coast, which means it goes through the fault zones. Field quantitative analysis and core studies from the AIG-10 well have been performed to define both regional and fault-related fracture networks. Then laboratory thin section observations have been done to recognize the different fault rocks characterizing the fault zone components. These two kinds of approach give information on the permeability characteristics of the fault zone. To synthesize the data, a schematic conceptual 3D fluid flow modeling has been performed taking into account fault zone permeability architecture, sedimentation, fluid flow, fault vertical offset and meteoric water influx, as well as compaction water flow. This modeling allows us to fit all the data with a model where the fault segments act as a seal whereas the relays between these segments allow for the regional flow from the Peloponnese topographic highs to the coast.     

Subsurface thermal and hydrothermal characterization based on geothermal resources map, drill hole thermal gradients, Curie point depths and hypocenter distribution — Examples of Tohoku district, Japan

Subsurface thermal structure in Tohoku district are characterized by existing data such as geothermal resources maps, drill hole thermal gradients, Curie point depths and hypocenters distribution maps. The collected data are registered in a database system, then, compared in plan view, cross-section and bird's-eye pictures. The comparison indicates that subsurface temperatures extrapolated from drill hole thermal gradients are generally concordant to the Curie point depth, assumed to be 650 °C. Tohoku district is generally divided into 5 type areas; fore arc lowland, fore arc mountain country, Quaternary volcanic terrain, back arc lowland and back arc mountain country. The surface thermal manifestations in Quaternary volcanic terrain are mainly controlled by the magma chambers as heat sources, while, surface thermal features such as hot springs in non-volcanic areas are controlled by degrees of heat flows, and hydrothermal flows in permeable Cenozoic formations and along permeable fault zones.     

Early Jurassic rift structures associated with the Soapaga and Boyacá faults of the Eastern Cordillera, Colombia: Sedimentological inferences and regional implications

The NW-trending Bucaramanga fault links, at its southern termination, with the Soapaga and Boyacá faults, which by their NW trend define an ample horsetail structure. As a result of their Neogene reactivation as reverse faults, they bound fault-related anticlines that expose the sedimentary fill of two Early Jurassic rift basins. These sediments exhibit the wedge-like geometry of rift fills related to west-facing normal faults. Their structural setting was controlled further by segmentation of the bounding faults at approximately 10 km intervals, in which each segment is separated by a transverse basement high. Isopach contours and different facies associations suggest these transverse anticlines may have separated depocenters of their adjacent subbasins, which were shaped by a slightly different subsidence history and thereby decoupled. The basin fill of the relatively narrow basin associated with the Soapaga fault is dominated by fanglomeratic successions organized in two coarsening-upward cycles. In the larger basin linked to the Boyacá fault, the sedimentary fill consists of two coarsening-upward sequences that, when fully developed, vary from floodplain to alluvial fan deposits. These Early Jurassic rift fills temporally constrain the evolution of the Bucaramanga fault, which accommodated right-lateral displacement during the early Mesozoic rift event.     

HP–LT Variscan metamorphism in the Cubito-Moura schists (Ossa-Morena Zone, southern Iberia)

Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S₁) in these rocks. The main foliation in the schists is a crenulation cleavage (S₂), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe³⁺ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S₁ chlorites down to 0.1 in syn-S₂ chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006).     

3-D seismic structure of the source area of the 1993 Latur, India, earthquake and its implications for rupture nucleations

The Latur earthquake (M_w 6.1) of 29 September 1993 is a rare stable continental region (SCR) earthquake that occurred on a previously unknown blind fault. In this study, we determined detailed three-dimensional (3-D) P- and S-wave velocity (V_p, V_s) and Poisson's ratio (σ) structures by inverting the first P- and S-wave high-quality arrival time data from 142 aftershocks that were recorded by a network of temporary seismic stations. The source zone of the Latur earthquake shows strong lateral heterogeneities in V_p, V_s and σ structures, extending in a volume of about 90 × 90 × 15 km³. The mainshock occurred within, but near the boundary, of a low-V_p, high-V_s and low-σ zone. This suggests that the structural asperities at the mainshock hypocenter are associated with a partially fluid-saturated fractured rock in a previously unknown source zone with intersecting fault surfaces. This might have triggered the 1993 Latur mainshock and its aftershock sequence. Our results are in good agreement with other geophysical studies that suggest high conductivity and high concentration of radiogenic helium gas beneath the source zone of the Latur earthquake. Our study provides an additional evidence for the presence of fluid related anomaly at the hidden source zone of the Latur earthquake in the SCR and helps us understand the genesis of damaging earthquakes in the SCR of the world.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.