4-溴苯甲酸-2,3,4,5,6-五溴苯酯的合成(英文)

以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。     

低凝固温度琼脂糖的制备方法研究

以石花菜分级得到的琼脂糖为原料，采用甲基化方法制备低凝固温度琼脂糖。所得到的低凝固温度琼脂糖产品的凝固温度为30．1℃(1.5％浓度)，融化温度为64．8℃(1．5％浓度)，凝胶强度为264g／cm^2(1.0％浓度)，主要质量标准与Sigma公司的低凝固温度琼脂糖产品接近，符合低凝固温度琼脂糖产品的质量要求。     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

往复流中双向导向叶冲动透平模型性能试验研究

研制了 30 0双向自调导叶透平试验机组 ,安装在 10 0 0活塞式往复流透平试验台上 ,对两种叶轮方案和 6种不同喷咀、扩压器进行了不同活塞行程、不同周期和不同恒定输出电压下性能试验。试验结果表明在喷咀出口角α1=2 1 5°、扩压器入口角α2 =6 5 5°和α1=2 4°、α2 =6 3°组合最佳 ,最高效率达 5 3 3% ,而且在宽广流量系数范围内 ,特别是大流量系数范围内都有较高效率。大大优于常用对称翼透平。将上下游导叶固定 ,变成双向固定导叶透平。用No 1叶轮和 6种导叶出口角组合进行试验。表明最佳导叶出口角为 2 4°～ 30°,最高效率仍达 38 5 % ,比对称翼透平仍高许多     

Responses of CO2 in surface water in subtropical West Pacific to El Niño event

In order to investigate the relationships between the change of TCO2, △PCO2 and SST, current, upwelling and biological activities during El Nin(～)o event in the subtropical Pacific, the responses of TCO2 and △PCO2 in surface water in the subtropical Pacific during El Nin(～)o and La Nina have been simulated using a three-dimension carbon cycle model with biota pump. The results of numerical simulations show that TCO2 in sea water increases with reducing of SST during mature phase of El Nin(～)o in the subtropical West Pacific . At the same period , the Kuroshio in this region was weakened , the zonal currents were divergence , the upwelling carried the water with high concentrations of CO2 to the sea surface , so both of TCO2 and △PCO2 in surface water were increased . But TCO2 and △pCO2 were decreased during La Nina period. These simulated results confirmed the observations in 1982/1983 , 1986/1987 ,1991/1995 and 1997/1998 El Nin(～)o events .     

城市景观三维重建中的三角剖分算法

在构建城市景观时,为了快速精确地重建建筑物、绿地、河流等三维模型,提高自动化程度,缩短建设周期,需对用户采集的矢量地物数据进行三角剖分,再以OpenGL重绘三维模型。本文提出了一种对多边形进行三角剖分的递归分割算法,并以VisualC++实现,以实际的4万多个建筑物进行三角剖分实验,充分证明其是有效的。     

多频载波相位组合进行单点定位

不同于双频数据的应用,多频数据的采用对单点定位有着特殊意义,可以更好地获得其模糊度的解。基于卫星导航定位系统多频载波相位线性组合理论,研究了具有特殊意义的组合观测值及其特性。在此基础上,通过多频观测值数据的数值仿真,采用新方法进行整周模糊度快速求解。编制了基于多频载波相位组合单点定位软件,通过结果的比较分析,得出有一定实际应用意义的结论。此方法算法简单,速度快,能够满足实时导航定位的需要,具有工程应用价值。     

利用p~3软件进行GPS单点定位解算的若干问题

利用p3软件对大量实测数据进行了高精度单点定位有关问题的验证和分析;在IGS提供的精密星历和卫星钟差产品中,较为深入地比较分析了快速产品和几种最终产品的定位精度、收敛速度及p3软件的正反算结果精度。得出以下结论:快速产品与最终产品的定位精度和收敛速度相似;COD的收敛速度和定位精度最高;p3软件的反算精度明显优于正算,且精度也比较均匀。这些研究成果对PPP技术的实际应用具有较好的借鉴意义。     

弹道计算中的扰动引力影响研究

随着弹道导弹系统技术的不断改进,影响导弹精度的工具类误差已逐渐降低,地球重力场扰动引力已经成为影响导弹命中精度的主要因素。这里从3个方面分析了扰动引力对弹道的影响,模拟结果表明,对于射程为10000 km以上的远程导弹,扰动引力的影响会造成超过1 km的落点偏差;5×10-5m s-2的扰动引力系统性偏差对导弹落点有明显影响。因此,扰动引力对导弹落点的影响不容忽视。