When are relative variograms useful in geostatistics?

The relative variogram has been employed as a tool for correcting a simple kind of nonstationarity, namely that in which local variance is proportional to local mean squared. In the past, this has been linked in a vague way to the lognormal distribution, although if {Z_t; t D}is strongly stationary and normal over a domain D,then clearly {exp (Z_t); t D}will stillbe stationary, but lognormal. The appropriate link is made in this article through a universal transformation principle. More general situations are considered, leading to the use of a scaled variogram.     

Modification Of The Standard ∈-Equation For The Stable Abl Through Enforced Consistency With Monin–Obukhov Similarity Theory

A condition is derived for consistency of the standard-equation with Monin–Obukhov (MO) similarity theory of thestably-stratified surface layer. The condition is derivedby extending the procedure used to derive the analogous condition forneutral theory to stable stratification. It is shown that consistencywith MO theory requires a function of flux Richardson number, Ri_f, to be absorbed into either of two closure parameters, c ₁ or c ₂.Inconsistency, on the other hand, results if constant values of these are maintained for all Ri_f, as is done in standardapplication of the equation, and the large overpredictions ofturbulence found in such application to the one-dimensionalstable atmospheric boundary layer (1D-SBL) are traced to thisinconsistency. Guided by this, we formulate a MO-consistent-equation by absorbing the aforementioned function intoc ₁, and combine this with a Level-2.5 second-orderclosure model for vertical eddy viscosity and diffusivities.Numerical predictions of the 1D-SBL by the modified model converge to a quasi-steady state, rectifying the predictive failure of the standard -equation for the case.Quasi-steady predictions of non-dimensional variables agree stronglywith Nieuwstadt's theory. Qualitative accuracy of predictionsis inferred from comparisons to field data, large-eddy simulationresults and Rossby-number similarity relationships.     

Gas and Particulate Products Distribution from the Photooxidation of α-Humulene in the Presence of NOx, Natural Atmospheric Air and Sunlight

The photooxidation of -humulene in the presence of NO_x, natural sunlight, and rural background air was investigated using a combination of gas chromatography-mass spectrometry (GC-MS) and high performance liquid chromatography (HPLC). Identification and quantification of gas and particulate reaction products were reported over the course of the reaction. The daytime photooxidation was carried out in a large outdoor smog chamber (190 m³). A wide range of ring retaining and ring opening products in the gas and particle phase are reported. On average, measured gas and particle phase products accounted for 44% of the reacted -humulene carbon. Measurements show that a number of reaction products with low vapor pressures (e.g. 3-seco--humulone aldehyde, 7-seco--humulone aldehyde, -humulal aldehyde, -humulene 3-oxide or -humulene 7-oxide, -humulaic/alic acid isomers, and 3-seco--14-hydroxyhumulone aldehyde) were found in the early stage of the reaction and may play an important role in the early formation of secondary organic aerosol. A detailed mechanism is proposed to account for most products observed in this investigation.     

Giant Vibrations in Dip

This work reports the discovery of solar-type oscillations in thegiant star Hydrae.     

华北平原冬麦田土壤CH4的吸收特征研究

利用静态箱/气相色谱(GC)法,对华北平原冬小麦拔节-成熟期间麦田土壤CH₄气体通量进行了测定,得出华北平原典型冬麦田土壤是大气CH₄的弱吸收汇。试验期间土壤CH₄通量存在明显的季节变化和日变化,麦田拔节-成熟期间土壤CH₄通量日平均值为-18.3μg·m^-2·h^-1,波动范围为-4.3-24.4μg·m^-2·h^-1;在土壤CH₄通量的日变化中,观测到麦田土壤在午间和夜间都有一个吸收峰,峰值出现的时间因生育期不同而有所不同。试验期间CH₄通量日平均值与土壤温度关系不明显,而与土壤水分呈负相关(α=0.01);日变化中土壤CH₄通量与地表温度的相关性较差,而与5cm地温相关密切。麦田拔节-成熟期间土壤CH₄通量日平均值随NH4+-N施用量的增加呈递减规律,农田秸秆还田后不利于土壤对CH₄的吸收。     

Accelerator mass spectrometry radiocarbon dating of 1994 Lake Winnipeg cores

Conventional radiocarbon dating of Lake Winnipeg core samples has produced erroneously old ages due to the incorporation of pre-Quaternary carbon derived from carbonaceous rocks, soils and sediments in the watershed, as well as a hard-water effect resulting from leaching of calcareous rocks and soils. To circumvent these problems and develop a reliable chronology for the Lake Winnipeg core series, a total of 64 samples from the Lake Winnipeg core series were processed to isolate well preserved macrofossils suitable for Accelerator Mass Spectrometry (AMS) radiocarbon dating. Here we report six radiocarbon ages derived from plant macrofossils and ostracodes, and reconstruct aspects of the depositional environment of each sample based on the associated macrofossil assemblage.     

Lagrangian Solution of Dynamo Equations and Path Integrals

We discuss an explicit solution of the Cauchy problem for induction equation and suggest its generalization for equations of ²-dynamo. These solutions are based on concepts of multiplicative, Wiener path, and stochastic integrals. Obtained explicit solution can be useful as a tool in investigations of a dynamo with fluctuating helicity.     

A method of searching for radial velocity anomalies in the lower mantle using interfering signals

Radial velocity anomalies in the lower mantle that give rise to triplications in the travel-time curve for short-periodP waves will produce arrivals havingdT/d values that differe by roughly 0.2–0.5 s/deg. The first two arrivals associated with such triplications will be separated by less than one second over a distance range of 4°–10° they may not, therefore, be separable visually on single seismograms, so that their presence can only be inferred from some measurable property that depends on their mutual interference. If there are lateral variations in the regions of anomalous velocity gradients, the interfering signals will also have different azimuths of arrival. Using two synthetic wavelets we have investigated the effect of interference on bothdT/d and azimuth measurements at the Yellowknife Array. We found that if the interfering pulses have a dominant frequencyv, there is a range of time separations (0.30/v0.55/v) over which the measureddT/d and azimuth values may fluctuate by much more than the differences indT/d and azimuth between the interfering signals. We have evaluated the following empirically defined functions for three different primary signals, and for three different relative amplitudes of the interfering signals:f (t), the drift function, which expresses how the measured slownesses,p, and azimuths, , differ from the slownesses and azimuths of the primary wavelets; f(), the range function, which describes the behaviour of the upper and lower bounds ofp and as a function of the difference in arrival times of the signals, andf , studied the properties of these functions, and have outlined how these properties provide criteria based on the numerical and statistical characteristics of the arrival vectors, and on the waveform of the signal that will enable small radial velocity anomalies to be more clearly delineated.Contribution No. 863 from the Earth Physics Branch.     

A study on the long term periodicities among the X‐ray binaries: Two new superorbital periods

Long term behaviours of a few selected X‐ray binaries are studied on the basis of RXTE/ASM archive covering a period of ∼13 years of continuous X‐ray data. Two new superorbital periods seem to be revealed for the GX354‐0 and X Persei systems as 8.7 years and 345 days, respectively. Although the X Persei system has two strongest peaks in its power density spectrum at 15.7 years and at 345 days, the latter is much more plausible. The GX354‐0 system also has few additional periodicities appeared in different time intervals (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Biodegradation and environmental behavior of biodiesel mixtures in the sea: An initial study

Biodiesel, a mixture of fatty acid methyl esters (FAMEs) derived from animal fats or vegetable oils, is rapidly moving towards the mainstream as an alternative source of energy. However, the behavior of biodiesel, or blends of biodiesel with fossil diesel, in the marine environment have yet to be fully understood. Hence, we performed a series of initial laboratory experiments and simple calculations to evaluate the microbial and environmental fate of FAMEs. Aerobic seawater microcosms spiked with biodiesel or mixtures of biodiesel and fossil diesel revealed that the FAMEs were degraded at roughly the same rate as n-alkanes, and more rapidly than other hydrocarbon components. The residues extracted from these different microcosms became indistinguishable within weeks. Preliminary results from physical-chemical calculations suggest that FAMEs in biodiesel mixtures will not affect the evaporation rates of spilled petroleum hydrocarbons but may stabilize oil droplets in the water column and thereby facilitate transport.