四川稻城竹鸡顶铜矿地质特征及成矿特点

竹鸡顶斑岩型铜矿位于西南三江成矿带内,热液蚀变以青磐岩化、泥化为特征。区内现已圈出1个矿带和2个矿化带,并有幅频激电异常、土壤铜异常与之套合。该区具有较好的找矿前景。     

内蒙古阿鲁科尔沁旗好力宝铜钼矿床地质特征及找矿方向

好力宝铜钼矿床属与燕山期隐伏的隐爆角砾状斜长花岗斑岩和碎裂次石英斑岩有关的热液脉状和斑岩型矿床.铜钼矿体受隐爆角砾岩筒和岩体控制,矿化产在蚀变隐爆角砾岩和硅化带中.今后的找矿方向应侧重于对斜长花岗斑岩与围岩接触带和碎裂次石英斑岩中化探异常和低阻高极化异常地段的探索.     

演化中的裂谷带——五大连池火山岩带

小古里河—科洛—五大连池—二克山新生代火山岩带是一条富钾火山岩带。文中重点论述了以下4点内容:(1)火山岩及其包体中存在典型的地幔交代作用;(2)根据火山岩K2O/Na2O比值勾画出富钾火山岩带范围;(3)地幔气体的绝热膨胀导致"冷泉和冻土现象";(4)地震活动的现状。论证了NNW走向的五大连池火山岩带是新生代初始的大陆裂谷,它们切穿了大兴安岭北北东向构造带。进一步从岩浆演化的趋势认为五大连池裂谷带将持续演化而不会夭折。     

钾霞石制备体系碱性滤液的利用技术

为处理钾长石水热制备钾霞石所产生的碱性滤液,本文采用水热法,考察了氢氧化铝溶解时间、晶化时间、晶化温度、水碱比对钾霞石产率和白度的影响,并对合成钾霞石物相进行了表征。结果表明,合成钾霞石的最佳条件为,氢氧化铝溶解时间为1.5 h,晶化时间为4 h,晶化温度280℃,水碱比为1.8。XRD结果表明,产物为钾霞石粉体。傅里叶变换红外光谱表明,Al(OH)₃中的Al在水热条件下进入到Si—O骨架中形成了Si—O—Al官能团,从而印证了钾霞石的合成。差热分析结果表明,合成钾霞石具有良好的热稳定性。氮气吸附结果表明,合成钾霞石比表面积为5.18 m²/g,平均孔径为32.98 nm。实现了钾长石水热制备钾霞石所剩碱性滤液的资源化利用,并为钾长石水热制备钾霞石提供了一种母液循环的思路,使水热制备钾霞石工业化成为一种可能。     

论南岭成矿带大宝山斑岩型铜矿的特殊性及其勘查意义

广东省大宝山矿床是南岭成矿带唯一的大型铜多金属矿床，此次研究在矿区中南部发现了细脉浸染状铜矿的新类型。为确定其是否为斑岩型铜矿的成因类型，本文在梳理南岭成矿带铜成矿条件和成矿规律的基础上，查明了矿区中南部英安斑岩的蚀变和铜矿化特征。综合研究认为南岭成矿带早侏罗世中酸性斑岩的小岩体较多，叠加多期断裂构造和碳酸盐岩建造，非常有利于铜多金属成矿物质的运移、富集。大宝山英安斑岩发育黑云母化、钾长石化、青磐岩化、绢英岩化、泥化等蚀变类型，铜矿化与绢英岩化、绿泥石化关系密切。大宝山铜矿中的英安斑岩沿逆冲推覆构造侵位并呈岩墙状产出，冷却过程中受区域构造应力产生了一组平行裂隙，岩浆房去气作用排出的热液沿裂隙蚀变围岩并充填成矿。大宝山斑岩型铜矿取得的找矿勘查成果表明，“全位成矿，缺位找矿”理念可以有效指导靶区圈定和老矿山外围（深部）找矿勘查，早侏罗世的南岭具有形成较大规模斑岩型铜矿的条件。     

胶东海阳所超镁铁岩中强亲铁元素的地球化学特征及其构造环境探讨

强亲铁元素与亲石元素具有不同的地球化学行为，因此能够从不同的角度为造山带中超镁铁岩的成因及演化提供重要信息。位于苏鲁造山带东北端的胶东海阳所超镁铁岩主要由橄榄岩和辉石岩组成，它们常以团块状赋存于花岗质片麻岩中。虽然前人对这些超镁铁岩已经开展大量岩石学研究，但关于其成因及构造属性仍存在较大争议。本文开展了海阳所超镁铁岩的全岩主微量元素、强亲铁元素及Re-Os同位素的分析工作，结果显示蛇纹石化橄榄岩具有较高的MgO和Fe₂O₃^T含量，较低的Al₂O₃、TiO₂和CaO含量，明显富集流体迁移元素（U、Pb），亏损高场强元素（Zr、Hf），强亲铁元素没有发生明显分异，但Ru显示正异常，表明海阳所蛇纹石化橄榄岩是经历了低-中等程度部分熔融及熔/流体交代作用影响的残余地幔橄榄岩。海阳所辉石岩的主量元素表现出明显的结晶分异特征，稀土元素较原始地幔富集，铂族元素（PGEs）含量较低且发生了明显的分异，表明辉石岩的地幔源区经历过高程度的部分熔融和硫化物的分离。海阳所蛇纹石化橄榄岩的Os同位素地球化学特征表现出大洋亲和性，与辉石岩不具有熔体-残留体的关系。由于该地区发育较深层次的韧性剪切带，蛇纹石化橄榄岩中的橄榄石与辉石表现出韧性变形的特征，同时有辉石岩侵入到橄榄岩的现象，表明该地区的蛇纹石化地幔橄榄岩与辉石岩既不同时，也不同源，因此，暗示了该套岩石组合可能形成于大洋核杂岩（OCC）与洋脊型蛇绿岩（MOR）堆晶岩交互发育环境。     

同位素地球化学、岩石地球化学——密坑山锡矿同位素年代学研究的启示

密坑山锡矿田位于江西省会昌县西南约40km处。该区为一晚中生代破火山，火山岩为上侏罗统鸡笼嶂组流纹质凝灰熔岩及火山碎屑岩，火山口周围环状及放射状断裂发育，火山口中心为浅成相的密坑山似斑状钾长花岗岩中央岩株侵入体所充填。上世纪80年代以来，在该岩体与流纹质凝灰熔岩的内外接触带相继发现了岩背、淘锡坝、苦竹岽、矿背、上湾等一批大、中型锡多金属矿床或矿点，表明这一岩体对成矿具有重要的制约作用。     

Catalytic ozonation of phenol in water with natural brucite and magnesia

Catalytic ozonation has attracted much attention in treatment of wastewater for its mild conditions. Phenol and its ramifications are common components in a wide variety of wastewaters including those from coal conversion processes, coking plants, petroleum refineries and several chemical industries. In this paper, natural brucite and magnesia have been successfully used in catalytic ozonation of phenol. And the mechanisms of catalysis were also investigated. From Figs. 1 and 2, it can be found that both brucite and magnesia have remarkable catalysis on degradation of phenol and removal of Chemical Oxygen Demand （COD）. The pH of solutions on the process of ozonation alone, catalytic ozonation with brucites and with magnesia were 6.35-2.76, 10.18-8.52 and 10.58-10.83, respectively. It can be concluded that alkali environment plays a critical role for catalytic ozonation of phenol. We also found that the alkaline minerals reacted on the surface with oxalic acid and other low molecular-weight acids which are intermediate products in ozonation, but those intermediate products could be mineralized into carbon dioxide completely with enough ozonation time.     

Hydrogeochemical controls on surface and groundwater chemistry in naturally acidic, porphyry-related mineralized areas, southern Rocky Mountains

In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors： mineralogy and hydrology. Parameters that potentially affect water chemistry include： host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations （for example： Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L）. With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides.     

熊耳山地区太古宙超镁铁质岩的地球化学特征及成因探讨

熊耳山地区太古宙超镁铁质岩在空间分布上具有不均一性、成带性和多方向性特征 ,岩石以橄榄岩、辉石岩、角闪石岩为主 ,蚀变强烈。岩石贫钙、镁 ,低铝、K2 O Na2 O,稀土总量较高 ,轻重稀土分馏显著。地球化学特征表明大部分超镁铁质岩体为岩浆侵入成因