Electronic Structures of Square Planar Coordinated Transition Metal Ions in Compounds with Gillespite Structure

Electronic structures of square planar coordinated transition metal ions in BaCuSi₄O₁₀ and CaCrSi₄O₁₀ are investigated using the ligand-field theory (LFT), angular overlap model (AOM) and iterative extended Hückel molecular orbital theory (IET). The electronic energy levels of the natural mineral dioptase are also investigated, in which the Cu²⁺ ions occupy the sites of pseudo D_4h symmetry. Both LFT and AOM predict that the crystal-field levels of transition metal ions in these compounds follow such an order that E (²B_1g <E(²B_2g <E(²A_1g )<E(²E_g ), and the frequencies of the crystal-field transitions obtained from point charge calculations are in good agreement with those observed. However, the energy-level order cannot be determined unambiguously from the IET calculation because it depends on the values of parameters chosen for the calculation.     

黑硼锡镁矿孪晶的电子衍射分析

黑硼锡镁矿是1985年在我国发现的一种新矿物,微孪晶特别发育,其电子衍射斑点往往具规律的分裂现像。用选区电子衍射获得[010]、[141]和[121]定向带轴电子衍射斑点分裂图,经矩阵分析,确定两套斑点分裂是由其呈挛晶结构关系所致,孪晶面为(101),属于面律孪晶,这种孪晶的微形貌由明场像(BF)得到证实。根据不同取向的电子衍射图,确定该矿物属单斜晶系,a_0=10.7,b_0=3.01,c_0=5.39,β=94.5°。上述挛晶结构特征及其晶体学数据与X射线单晶研究结果有很好的可比性。     

HP—3808A测距仪测距精度分析

本文采用数理统计方法,详细分析了HP—3808A激光测距仪近几年来积累的测量数据,求得仪器平均测距相对精度为1:70万。并且讨论了进一步提高测距精度的技术措施。