水化学性质对蒙脱石悬浮液膨胀性的影响

实验研究了NaOH、HCl、NaCl和CaCl2等电解质加入量对蒙脱石悬浮液膨胀性的影响,并通过离子色谱、体视显微镜和激光粒度分析技术,研究了蒙脱石粒度变化与体积膨胀之间的关系。实验结果表明,NaOH、HCl对蒙脱石悬浮液膨胀性影响不明显,而NaCl和CaCl2对蒙脱石悬浮液的膨胀有明显的抑制作用;而且CaCl2对蒙脱石膨胀的抑制作用明显强于NaCl,CaCl2浓度比NaCl少了1个数量级时即可达到相同的膨胀抑制效果。离子色谱分析显示,CaCl2溶液与蒙脱石混合后,悬浮液上清液中的Ca2+浓度减少,而Na+浓度增加,分析存在离子交换过程。经激光粒度分析仪和体视显微镜观察,电解质的加入使颗粒之间产生了团聚作用,改变了颗粒的粒径,从而在宏观上表现为蒙脱石悬浮液体积的减少。     

CO2浓度升高对极端干旱区多枝柽柳叶片水分利用效率的影响

采用美国Li-COR公司生产的LI-6400便携式光合作用测量系统,在2008和2009年生长季节对极端干旱区额济纳绿洲多枝柽柳(Tamarix ramosissima Ledeb.)叶片的净光合速率(Pn)与蒸腾速率(Tr)、胞间CO2浓度(Ci)随光照强度的变化.结果表明:胞间CO2浓度(Ci)随光照强度增强而减小...     

CO2浓度升高对三江平原湿地活性有机碳及土壤微生物的影响

利用开顶箱薰气室,设置正常大气CO2浓度(Ambient CO2,350 umol·mol-1)和高CO2浓度(Elevated CO2,700μmol·mol-1)2个水平和不施氮(NN,0 gN·m-2)、常氮(MN,5 gN·m-2)、高氮(HN,15 gN·m-2)3个氮素水平,研究CO2浓度升高和氮肥施用对三江平原草甸小叶章湿地(Calamagrostis angustifolia)土壤活性有机碳及微生物的影响。结果表明,CO2浓度升高条件下,土壤微生物量碳(MBC)和溶解性有机碳(DOC)呈增加趋势,易氧化有机碳(LOC)和水溶性碳水化合物碳(CHC)的变化因生长期和氮素水平而异。CO2浓度升高,小叶章湿地土壤微生物数量在不同的生长时期呈现不同的响应趋势。细菌数量在腊熟期增幅最大,为31.4%;真菌数量在腊熟期增加16.6%,成熟期增加24.3%;放线菌数量没有发生明显变化。相关分析表明,细菌、真菌和放线菌数量都与土壤微生物量碳呈显著相关。湿地土壤中的活性有机碳可以为土壤微生物提供更多的有效能量,从而加快湿地生态系统养分循环过程。     

CONVERSION RATES OF SURFACE HOX RADICALS IN BEIJING CITY

1INTRODUCTIONThe hydroxyl radicals play a central role in atmospher-ic photochemistry, reacting with a lot of compounds, often initiating their oxidation and subsequent loss and resulting in the formation of ozone and other deleteri-ous oxidants, acids, and fine particles in polluted ar-eas. A thorough understanding of this role is necessary for efficient, cost-effective pollution control. There-fore, the measurement of OH is very significant (E-HHAT etal., 1991). Nevertheless, most me…     

Study of Dissolved Chlorofluorocarbons in Lake Washington

Measurements of three chlorofluorocarbons(CFCs) :trichlorofluoromethane (CFC-11),dichlorodifluoromethane (CFC-12) and trichlorotrifluoroethane (CFC-113), along with methyl chloroform (CH3CCl3) and carbon tetrachloride (CCl4) were made in water samples from Lake Washington,using Electron Capture-Gas Chromatography (EC-GC).The samples were collected in mid-autumn, a period when the lake‘‘‘‘‘‘‘‘s upper layer undergoes rapid cooling,At the time of sam-pling,a strong vertical temperature gradient was present in the lake,with surface temperatures of -14℃,and near bottom(50 meters) temperatures of -8℃ ,The concentrations of dissolved CFC-12 and CFC-11 increased with depht ,as expected from the higher solubilities of these gases at lower temperatures ,Atmospheric measurements made at the sampling site at the time of the cruise ,showed that CFC-11 and CFC-12 saturations in the near surface samples were 100% and 106%,respectively,For the deepest sample (52 meters)CFC-11 and CFC-12 saturations were 102% and 126%,Because the surface layer of the lake respondes to changes in atmospheric CFCs on a time scale of several weeks ,the highere than equilibrium concentrations of CFC-12 observed at the time of sampling may reflect earlier episodes of elevated levels of atmospheric CFC-12 in this urban area.High concentrations of dissolved CFCs in runoff or industrial effluent might also lead to elevated CFC levels in the lake. The cold ,deep water of Lake Wahington is realtively isolated from the effects of surface gas exchange except during winter ,and the supersaturations observed in the deep layer may reflect pe-riods of elevated atmospheric CFC-12 levels from the previous winter season.These results were compared to summertime profiles of CFC-11 and CFC-12 made in 1994.     

Problems of ecological and technical safety by exploration and production of natural gas hydrates

Gas hydrates-the firm crystal connections formed water （water, ice, water vapor） and low-molecu- lar waterproof natural gases （mainly methane） whose crystal structure effectively compresses gas： each cubic meter of hydrate can yield over 160 m^3 of methane. In present time exploitation of the Messoyahsk （Russia） and Mallik （Canada） deposits of gas hydrates in is conducted actively. The further perfection of prospecting methods in the field of studying gas hydrates containing sediments in round extent depends on improvement of geophysical and well test research, among which native-state core drilling is one of the major. Sampling nativestate core from gas hydrates sediments keeping not only original composition, but structural-textural features of their construction. Despite of appeal of use gas hydrates as the perspective and ecologically pure fuel possessing huge resources, investigation and development of their deposits can lead to a number of the negative consequences connected with arising hazards for maintenance of their technical and ecological safety of carrying out. Scales of arising problems can change from local up to regional and even global.     

阳极焙烧炉的燃烧计算与分析

采用计算燃烧学的原理和模型以及CFD软件对以重油作为燃料的阳极焙烧炉炉内的流动、燃烧过程进行了模拟计算,讨论了炉内温度场、流场和各组分浓度场的分布规律,分析了这些因素对碳阳极焙烧质量的影响.研究表明,在设计阳极焙烧炉结构时应考虑火道中挡板对气流分布的影响.     

泥石流体的沉积稳定浓度与颗粒级配之关系

沉积稳定浓度主要反映了泥石流固体物质的级配特点,它涉及到泥石流体的固体颗粒的大小和排列状况。利用这种浓度可确定泥石流体的粘滞系数、宾汉剪切力以及与泥石流颗粒级配有关的其他参数。分析了泥石流体的沉积稳定浓度与颗粒级配的理论关系,并用实验方法建立了它们的关系式。