承德市工业结构、布局与环境质量关系研究

以承德市为例,论述工业结构、布局与环境质量关系,提出了调整工业布局的综合评判模型,促进城市生态系统具有和谐的结构,齐全的功能和高效的生态效率。     

利用长周期面波研究华北地区地壳与上地幔结构的横向非均匀性

本文以太行山为界将华北地区分为东西两部分,东部为河淮块体,西部为鄂尔多斯块体.利用最小二乘法,从混合路径基阶瑞利面波群速度频散提取两块体的纯路径频散,并反演其地壳、上地幔的层状结构.所得结表果明,两块体的面波频散和地壳、上地幔结构存在明显差异.东部的河淮块体地壳较薄,地壳内平均速度比西部的鄂尔多斯块体壳内平均速度约低0.13km/s,壳内20km深度左右出现低速层;而西部的块体壳内速度成层递增,未见低速层出现.两块体上地幔顶部速度均偏低,地幔低速层的埋藏深度基本相同.但西部块体地幔低速层厚,且比东部块体地幔低速层的速度约低0.3km/s.     

测量控制网设计的机助模拟法

一、概述 测量控制网是工程施工测量和城市测量的基础。控制网的优劣首先反映在网的精度指标，它决定于网形结构、多余观测量的选择和旋测仪器实际所能达到的精度等因素。但控制网的精度不是越高越好，在满足必要精度后增加的“额外的”精度，并不会带来明显的效益，反而会使测设控制网的成本大大提高。因此，避免控制网对绝对精度的过高要求，达到布设控制网的较好的经济效益，也是反映控制网的优劣的重要指标。     

Electronic Structures of Square Planar Coordinated Transition Metal Ions in Compounds with Gillespite Structure

Electronic structures of square planar coordinated transition metal ions in BaCuSi₄O₁₀ and CaCrSi₄O₁₀ are investigated using the ligand-field theory (LFT), angular overlap model (AOM) and iterative extended Hückel molecular orbital theory (IET). The electronic energy levels of the natural mineral dioptase are also investigated, in which the Cu²⁺ ions occupy the sites of pseudo D_4h symmetry. Both LFT and AOM predict that the crystal-field levels of transition metal ions in these compounds follow such an order that E (²B_1g <E(²B_2g <E(²A_1g )<E(²E_g ), and the frequencies of the crystal-field transitions obtained from point charge calculations are in good agreement with those observed. However, the energy-level order cannot be determined unambiguously from the IET calculation because it depends on the values of parameters chosen for the calculation.