南极乔治王岛菲尔德斯半岛土壤矿物化学风化特征分析

本文在考察菲尔德斯半岛成土环境、土壤理化性状的基础上，分析了本区代表性土壤的粘土矿物组成，粘粒、粉粒和全土中土壤大量元素的含量。认为亚南极海洋性气候区（无冰区）土壤次生粘土矿物主要是蒙脱石、伊利石和绿泥石；土壤矿物风化过程包括脱盐基、周期性滞水氧化－还原脱铁锰和微弱的脱硅过程     

砂岩储层中粘土矿物二次参数定量评价方法及其地质意义

随着油气田的二次、三次开采，人们愈来愈认识到砂岩储层中粘土矿物的重要作用如，高石的速流性，蒙脱石的水敏性，伊利石的丝缕化障积性，绿泥石的酸敏性等，具有这些特性的粘土矿物以不同的方式堵塞和填积在储层孔隙喉道中，影响油开采的效益和开采所选的工艺。     

辉碲铋矿单矿物的化学分析

辉碲铋矿物经ＨＮＯ３－ＫＣｌＯ３溶解，用火焰原子吸收法或乙二胺四乙酸二钠事滴定法测定Ｂｉ，火焰原子吸收法测定Ｔｅ、Ｆｅ、Ｃｕ，３，３＇－二氨基联苯胺光度法测定Ｓｅ，硫酸重量法测定Ｓ。其结果与矿物化学成分理论值十分接近，主、次量元素平行测定６次，其ＲＳＤ小于０．８％，痕量元素ＲＳＤ（ｎ＝６）小于１０％。     

邯邢侵入体中幔源超镁铁质岩包体的发现及其矿物地球化学特征

邯邢中基性侵入杂岩体中产有众多的岩石包体。作者在暗色闪长岩相中首次发现了超镁铁质岩包体,以方辉榄橄岩为主,由镁榄橄石(Fo=92±),顽火辉石(En=90±),铬透辉石和铬尖晶石组成,碎斑-平结构,发育扭折带。全岩SiO_2=41.02,MgO=42.24,∑EREE(3.95)甚低,稀土元素配分曲线显示特殊的向下凸的形状。δ~(18)O=6.5～7.0。辉石平衡温度约为1000℃,压力为20×10~8～22×10~8Pa。矿物-地球化学研究表明具上地幔岩特征,属A型包体,这在国内外文献中还未曾见过类似的报导。这个发现对探讨华北板块的地壳上地幔组成与演化,中生代构造岩浆活动的大地构造背景以及物质来源和邯邢式铁矿的成因将产生深远的影响。     

Electronic Structures of Square Planar Coordinated Transition Metal Ions in Compounds with Gillespite Structure

Electronic structures of square planar coordinated transition metal ions in BaCuSi₄O₁₀ and CaCrSi₄O₁₀ are investigated using the ligand-field theory (LFT), angular overlap model (AOM) and iterative extended Hückel molecular orbital theory (IET). The electronic energy levels of the natural mineral dioptase are also investigated, in which the Cu²⁺ ions occupy the sites of pseudo D_4h symmetry. Both LFT and AOM predict that the crystal-field levels of transition metal ions in these compounds follow such an order that E (²B_1g <E(²B_2g <E(²A_1g )<E(²E_g ), and the frequencies of the crystal-field transitions obtained from point charge calculations are in good agreement with those observed. However, the energy-level order cannot be determined unambiguously from the IET calculation because it depends on the values of parameters chosen for the calculation.