砷酸根的液—固界面交换吸附研究——pH和Ca(Ⅱ)的影响

研究ｐＨ和Ｃａ（Ⅱ）对砷酸根在海水与ＮａＣｌ介质中对水合氧化物和粘土矿物上交换吸附的影响：（１）在酸性条件下和海水及ＮａＣｌ介质中，砷酸根在针铁矿上的交换率Ｅ（％）—ｐＨ曲线呈平顶峰型、在δ－ＭｎＯ呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子／配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。（２）在碱性条件下的海水介质中，砷酸根与水合氧化物和粘土矿物的Ｅ（％）—ｐＨ曲线都呈Ｖ型，这是因为生成了具有一定结构的液—固界面三元络合物之故。（３）在ＮａＣｌ介质中，Ｃａ加入起促进作用，再次证明液—固界面三元络合物生成机理与Ｖ型曲线的内在关系     

A comparison of three marine ecosystems surrounding the Korean peninsula: Responses to climate change

This study uses a comparative approach to examine responses of marine ecosystems to climatic regime shifts. The three seas surrounding the Korean peninsula, the Japan/East Sea, the East China Sea and the Yellow Sea represent three contiguous but distinct ecosystems. Sampling has been carried out by the National Fisheries Research and Development Institute of South Korea since 1965, using the same methods in all three seas. Sampling was generally synoptic. Amplitude time series of 1st EOF modes for temperature, salinity, zooplankton biomass and concentrations of four major zooplankton taxa were used to determine whether the three marine ecosystems respond in a similar manner to climate variations. Temporal patterns of the variables were strongly similar among the three seas at decadal time scales, but very weakly similar at interannual scales. All three seas responded to a climatic regime shift that occurred in 1989. Temperature, zooplankton biomass and copepod concentrations increased in the late 1980s or early 1990s in all three seas. Concentrations of amphipods, chaetognaths and euphausiids also increased in the Japan/East Sea and the East China Sea, but not the Yellow Sea. The Yellow Sea ecosystem differs strongly from the other two seas, and water exchange between the Yellow Sea and the East China Sea is much weaker than that between the East China Sea and Japan/East Sea. Spatial patterns of zooplankton determined by the EOF analysis were closely related to currents and fronts in each of the three seas.     

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c     

邢台矿区山字型构造的发现及其地质意义

邢台山字型构造位于河北省邯邢煤田内，其前弧向ES突出，脊柱呈ES-WN走向。分别分析了山字型构造脊柱及其东、西翼反射弧构造形迹特征，对研究区找矿具有重要意义。     

灾害预报与鸡西煤矿瓦斯爆炸事件

2002年上半年,伴随着厄尔尼诺现象的日益加剧,全球性重大自然灾害频繁发生.6月20日发生在中国黑龙江省鸡西煤矿的瓦斯爆炸事件和6月22日发生在伊朗的强烈地震,时间恰逢月亮近地潮的6月19日和太阳潮半日形变最大值的夏至的6月21日附近,是地球形变和排气较强烈的时段.据国内外有关资料,月球与地球发震有关系的重要条件是“近地点兼朔、望”以及各大行星特定位置的配合,张元东称之为“特殊天象组合期”[1];郭增建等提出,月亮赤纬角或太阳黄赤交角最大时地球形变和排气最强烈[2～5].在此期间,中国各种大的突发性灾难,如空难、海难、火车事故、矿…     

电子政务建设应注意军事应用的几个问题

电子政务的运行模式必将促使国防动员、军队决策指挥 ,以及战场信息应用等环节发生相应的变化。建设电子政务将促进国防动员工作规范化、制度化 ,将创造条件实现政府对军队的信息支援 ,将有利于未来战争数字战场环境建设。建设电子政务系统和“数字城市”、“数字省区”时 ,应结合国防动员和信息支援的问题从顶层构架 ,统盘考虑军事应用 ,同时制定法规和标准     

金矿脉分形特征及找矿意义研究

各种类型的金矿脉常呈不规则的几何形状产出,对它们用欧几里德方法进行描述和分析,不仅难以精确地说明其几何形态特征,有时甚至无法作出实际测量,因此也就很难掌握其产状变化的准确趋势,给金矿床的定量定位预测造成了困难.分形理论为获得有关隐伏矿床(脉)分布的更为准确的信息提供了有利工具.通过对招远灵山和河东两个典型金矿床矿脉分维数、几何丰度和有效紧密度等研究,讨论了分形理论在紧密结合地质特征条件下,客观准确揭示不规则矿脉变化规律及在找矿预测等方面的应用前景.     

中国东部四明山古夷平面遗迹特征与演化

古夷平面研究在地貌演化和新构造运动研究中占有极其重要的地位,但由于遭受构造运动和剥蚀作用的影响,很多古夷平面遗迹已无从清晰辨识。浙江四明山顶古近纪夷平古风化壳面的发现,为研究浙江东部甚至华东地区的新生代地貌演化提供了重要地质信息,同时为始新世和中新世时的古气候、古环境研究提供了重要物质证据。通过详细的野外地质调查,系统采集了该区5个点位的20个古风化壳样品和7个点位的15个现代风化壳样品,开展黏土矿物分析和玄武岩K-Ar年龄测试。研究确认四明山地区发育有2期古夷平面遗迹,即古近纪(E)和新近纪(N)古夷平面遗迹:第一期夷平面发育时间为65. 0～32. 2 Ma,解体和古夷平面遗迹保存时间为32. 2～21. 7 Ma;第二期夷平面发育时间为21. 7～10. 5 Ma,解体和古夷平面遗迹保存时间为10. 5～3. 0 Ma。研究区2期火山活动喷发所形成的玄武岩盖层有效保护了该区的古风化壳,从而使四明山古夷平面遗迹具有空间展布完整、剖面信息清晰等特征,呈现出由古夷平面(古风化壳)与玄武岩堆积面(现代风化壳)组成的"双风化壳"现象,为观察古夷平面遗迹特征提供了最佳场所。