Stable carbon isotopic ratios of CH4-CO2-bearing fluid inclusions in fracture-fill mineralization from the Lower Saxony Basin (Germany) - A tool for tracing gas sources and maturity

The stable carbon isotopic ratios (δ¹³C) of methane (CH₄) and carbon dioxide (CO₂) of gas-rich fluid inclusions hosted in fracture-fill mineralization from the southern part of the Lower Saxony Basin, Germany have been measured online using a crushing device interfaced to an isotopic ratio mass spectrometer (IRMS). The data reveal that CH₄ trapped in inclusions seems to be derived from different source rocks with different organic matter types. The δ¹³C values of CH₄ in inclusions in quartz hosted by Carboniferous rocks range between −25 and −19‰, suggesting high-maturity coals as the source of methane. Methane in fluid inclusions in minerals hosted by Mesozoic strata has more negative carbon isotope ratios (−45 to −31‰) and appears to represent primary cracking products from type II kerogens, i.e., marine shales. There is a positive correlation between increasing homogenization temperatures of aqueous fluid inclusions and less negative δ¹³C(CH₄) values of in co-genetic gas inclusions probably indicating different mtaturity of the potential source rocks at the time the fluids were released. The CO₂ isotopic composition of CH₄-CO₂-bearing inclusions shows slight negative or even positive δ¹³C values indicating an inorganic source (e.g., water-rock interaction and dissolution of detrital, marine calcite) for CO₂ in inclusions. We conclude that the δ¹³C isotopic ratios of CH₄-CO₂-bearing fluid inclusions can be used to trace migration pathways, sources of gases, and alteration processes. Furthermore, the δ¹³C values of methane can be used to estimate the maturity of the rocks from which it was sourced. Results presented here are further supported by organic geochemical analysis of surface bitumens which coexist with the gas inclusion-rich fracture-fill mineralization and confirm the isotopic interpretations with respect to fluid source, type and maturity.     

Mediterranean warming is especially due to summer season

We created a new homogenized daily minimum and maximum temperature data set (1955–2007) for the central Mediterranean area of Tuscany (Italy). Yearly and seasonal long-term trends of some climatic and extreme climatic indices were investigated. The results highlighted a positive trend for mean temperature of about 0.9°C per 50 years with a slightly more pronounced increase in maximum temperature. Seasonal analysis revealed a by far much greater increase in summer (June, July, August) and spring (March, April, May) temperature in respect of autumn and winter, this finding consistent with most recent Mediterranean evidences. Warm extremes showed an overall tendency to increase, while a slight not significant decrease trend was found in regard to frost days and cold extremes. Comparisons with different patterns of Mediterranean warming confirmed the magnitude of recent very fast rise in temperature, especially during summer. This change could be due to last decades modifications of general circulation patterns and land–temperature, land–precipitation positive feedback processes dependent from soil moisture. All these results confirm that the Mediterranean is a region especially responsive and thus very vulnerable to climate change.     

The Tunisian Jurassic aquifer in the North African Sahara aquifer system: information derived from two-dimensional seismic reflection and well logs

Southern Tunisia is an arid area where socio-economic activities are dependent on groundwater resources. The presented study aims to better characterize the Jurassic aquifer based on geological and geophysical data, with a view to develop a rational exploitation program. Well logs are used to precisely determine the position and composition of the known Jurassic aquifer layers and to identify others able to produce good quality water. The logs show that limestones, sandstones and dolomites of the Krachoua, Techout and Foum Tataouine formations are the main Jurassic aquifers. Sixty-eight seismic-reflection sections are integrated within this study. The interpolation between the interpreted sections leads to the construction of isochronous isopach maps and geoseismic sections, and their analysis finds that compressive and extensive tectonic deformations have influenced the Jurassic aquifer geometry. The Hercynian orogeny phase manifestation is remarkable in that there are several stratigraphic gaps in the Jurassic sequence. The E–W, NW–SE, and NNW–SSE accidents, reactivated in normal faults since the Permian to Lower Cretaceous epochs, have generated the structures found in the Jurassic series, such as subsided and raised blocks. Their syn-sedimentary activity has controlled the thickness and facies of these series. The Cretaceous, Tortonian and Post-Villafranchian compressions are responsible for the Jurassic-deposits folding in some localities. The highlighted tectonic and sedimentary events have an important impact on the Jurassic aquifer function by favoring the Jurassic aquifer interconnections and their connections with the Triassic and Cretaceous permeable series.     

DEM assessment of impact forces of dry granular masses on rigid barriers

In the design of sheltering structures/embankments for the mitigation of the risk due to rapid and long spreading landslides, a crucial role is generally played by the assessment of the impact force exerted by the flowing mass on the artificial obstacle. This paper is focused on this issue and in particular on the evaluation of the maximum impact force on the basis of the results obtained by performing an extensive numerical campaign by means of a 3D discrete element code, in which a dry granular mass is schematised as a random distribution of rigid spherical particles. The granular mass is generated just in front of the obstacle: its initial volume, velocity distribution, height, length and porosity are arbitrarily assigned, and the impact process is exclusively analysed. The initial conditions are varied to take a large variety of geometrical/mechanical factors, such as the initial front inclination, its height, the initial void ratio, the length of the impacting mass and the inter-particle friction angle, into consideration. A design formula is also proposed on the base of the obtained results and critically compared with the literature data.     

Some observations on the prediction of the dynamic parameters of debris flows in pyroclastic deposits in the Campania region of Italy

Over the last 20 years, many tools have been developed for the prediction of the post-failure behaviour of rapid landslides. However, as pointed out by several researchers, knowledge may be improved by the performance of back-analyses using different models and the evaluation of their reliability. This paper reports the back-analysis, conducted using numerical models, of 57 rapid landslides that have occurred in the Campania region. The back-analysis has been performed using the 2-D DAN_W code (version 2003) with two different rheological models: the Voellmy and the frictional models. The latter has been immediately discarded because it did not match the observed data. Instead, using the Voellmy model, the best-fit values of the parameters (friction μ and turbulence ξ) for different types of flow (channelled, un-channelled and mixed flows) have been researched. With these values a parametric study has been carried out on four representative slope profiles of the Campania region, enabling the prediction of runout, velocity and depth of flow (dynamic parameters) of potential debris flows.

Incorporating multiple observations for distributed hydrologic model calibration: An approach using a multi-objective evolutionary algorithm and clustering

The use of distributed data for model calibration is becoming more popular in the advent of the availability of spatially distributed observations. Hydrological model calibration has traditionally been carried out using single objective optimisation and only recently has been extended to a multi-objective optimisation domain. By formulating the calibration problem with several objectives, each objective relating to a set of observations, the parameter sets can be constrained more effectively. However, many previous multi-objective calibration studies do not consider individual observations or catchment responses separately, but instead utilises some form of aggregation of objectives. This paper proposes a multi-objective calibration approach that can efficiently handle many objectives using both clustering and preference ordered ranking. The algorithm is applied to calibrate the MIKE SHE distributed hydrologic model and tested on the Karup catchment in Denmark. The results indicate that the preferred solutions selected using the proposed algorithm are good compromise solutions and the parameter values are well defined. Clustering with Kohonen mapping was able to reduce the number of objective functions from 18 to 5. Calibration using the standard deviation of groundwater level residuals enabled us to identify a group of wells that may not be simulated properly, thus highlighting potential problems with the model parameterisation.     

Photoelectric photometry of 14 asteroids

Results of observations of 14 asteroids are reported; all of them, except 181 Eucharis, have been previously observed at least once. V photoelectric lightcurves were obtained from September 1982 to June 1983 at the Astronomical Observatory of Torino and at the Astrophysical Observatory of Catania. Part of this program aims to obtain complete lightcurves and, when possible, phasecurve information and to determine amplitudes and V magnitudes at different longitudes for a selected group of asteriods, in order to enlarge the set of known rotational axis directions.     

UV and optical emission lines from the z∼ 2.6 radio galaxy 0828+193: spatially resolved measurements

We present an investigation into the spatial variation of the rest-frame ultraviolet (UV) and optical line and continuum emission along the radio axis of the z ∼ 2.6 radio galaxy 0828+193, using long-slit spectra from the Keck II and Subaru telescopes. Line brightnesses, line ratios and electron temperatures are examined, and their relationship with the arm-length asymmetry of the radio source is also investigated. We find that on the side of the nucleus with the shortest radio lobe, the gas covering factor is higher, and the ionization parameter is lower. The contrasts in environmental density required to explain the asymmetries in the line brightness and the radio arm-length asymmetries are in fair agreement with each other. These results add further weight to the conclusion of McCarthy, van Breugel & Kapahi – lobe distance asymmetries in powerful radio sources are the result of an asymmetry in the environmental density.
We also note that the brightness of both the UV and optical continuum emission shows a similar spatial asymmetry to that shown by the line emission. While the UV continuum asymmetry can be wholly explained by the expected asymmetry in the nebular continuum, the optical continuum asymmetry cannot. We argue that, at least at optical wavelengths, the starlight and/or the scattered light must also be strongly spatially asymmetric.     

METHODS OF VARIMAX ROTATION IN FACTOR ANALYSIS WITH APPLICATIONS IN CLINICAL AND FOOD CHEMISTRY

Orthogonal rotations,e.g,the varimax rotation,are common practice in factor analysis.However,theterm varimax rotation does not refer to a unique procedure,since several different types of rotation arepossible.In this paper six different types of rotation are examined(raw varimax of loadings,normalvarimax of loadings,raw and normal varimax of scores,eigenvalue-weighted varimax of loadings andArthur varimax)from both a theoretical and practical point of view.It can be concluded that an adequateapplication of these methods can often simplify the interpretation of the calculated factors.