Implications for behavior of volatile elements during impacts—Zinc and copper systematics in sediments from the Ries impact structure and central European tektites

Moldavites are tektites genetically related to the Ries impact structure, located in Central Europe, but the source materials and the processes related to the chemical fractionation of moldavites are not fully constrained. To further understand moldavite genesis, the Cu and Zn abundances and isotope compositions were measured in a suite of tektites from four different substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia) and chemically diverse sediments from the surroundings of the Ries impact structure. Moldavites are slightly depleted in Zn (~10–20%) and distinctly depleted in Cu (>90%) relative to supposed sedimentary precursors. Moreover, the moldavites show a wide range in δ⁶⁶Zn values between 1.7 and 3.7‰ (relative to JMC 3‐0749 Lyon) and δ⁶⁵Cu values between 1.6 and 12.5‰ (relative to NIST SRM 976) and are thus enriched in heavy isotopes relative to their possible parent sedimentary sources (δ⁶⁶Zn = ?0.07 to +0.64‰; δ⁶⁵Cu = ?0.4 to +0.7‰). In particular, the Cheb Basin moldavites show some of the highest δ⁶⁵Cu values (up to 12.5‰) ever observed in natural samples. The relative magnitude of isotope fractionation for Cu and Zn seen here is opposite to oxygen‐poor environments such as the Moon where Zn is significantly more isotopically fractionated than Cu. One possibility is that monovalent Cu diffuses faster than divalent Zn in the reduced melt and diffusion will not affect the extent of Zn isotope fractionation. These observations imply that the capability of forming a redox environment may aid in volatilizing some elements, accompanied by isotope fractionation, during the impact process. The greater extent of elemental depletion, coupled with isotope fractionation of more refractory Cu relative to Zn, may also hinge on the presence of carbonyl species of transition metals and electromagnetic charge, which could exist in the impact‐induced high‐velocity jet of vapor and melts.     

Changes in biodiversity of the extremely polluted Golden Horn Estuary following the improvements in water quality

Long-term biological data supported by physicochemical parameters were evaluated to investigate the biodiversity of the Golden Horn Estuary from the past to the present. Limited observations dating back to 60 years ago indicated the existence of a diverse community in this small estuary. Unfortunately, in parallel with the increase in unplanned settlements and industry around the Golden Horn, pollution stress increased since the 1960s. Preliminary studies in the 1990s indicated survival of only a couple of pollution-resistant species, in the relatively cleaner lower estuary. Following the intensification of rehabilitation studies in 1998 and particularly after the opening of the floating bridge at the mid estuary; a remarkable day-by-day recovery in marine life has begun with the improving water quality. Nutrient concentrations decreased markedly; while water clarity significantly increased. Fecal coliform values decreased 10(3) fold. Phytoplankton composition changed and dense blooms of eukaryotic phytoplankters frequently occurred. Hydrogen sulfide almost completely disappeared even during the warmest periods of the year and dissolved oxygen concentrations increased. All results clearly depicted that the Golden Horn ecosystem shifted to eutrophic conditions from an anoxic environment. SCUBA dives in 2002, documented the level of diversification of life in the Golden Horn. All appropriate substratums were intensely covered by macrobenthic forms until the Halic Bridge and filter feeders dominated the plankton-rich ecosystem. Achieving the diversity of 1940s is not possible since the Black and Marmara seas, influencing water quality of the Golden Horn, are also suffering from anthropogenic impacts and are far less diverse than their rich diversity in 1940s. However, the Golden Horn is a good example that even the most polluted ecosystems can recover when appropriate measures are taken.     

基于大数据的上海中心城区建成环境与城市活力关系分析

运用大众点评数据、出租车到达数据与文化设施POI数据测度城市活力的经济、社会和文化维度,在街区和街道层面分析城市活力的空间结构特征,建立计量模型分析城市建成环境对城市活力的影响关系。结果表明:①上海中心城区城市活力表现出明显的空间差异,主要表现为由中心向四周递减、浦西优于浦东的总体特征;②街区和街道尺度影响城市活力的建成环境因素存在差异;③街区尺度建成环境对城市社会、经济和文化活力的影响存在差异:提升人口密度对经济活力具有正面影响,过高的人口密度可能不利于社会和文化活力发展;增加POI密度、路网密度和POI混合度有利于城市活力的提升;建筑层数和建筑密度的增加会降低街区的社会活力和文化活力,但会提升街区的经济活力;交通可达性有利于经济活力的提升。     

Adaptive neuro-fuzzy modeling for the swelling potential of compacted soils

This paper aims to present the usability of an adaptive neuro fuzzy inference system (ANFIS) for the prediction swelling potential of the compacted soils that are important materials for geotechnical purposes such as engineered barriers for municipal solid waste, earth dams, embankment and roads. In this study the swelling potential that is also one of significant parameters for compacted soils was modeled by ANFIS. For the training and testing of ANFIS model, data sets were collected from the tests performed on compacted soils for different geotechnical application in Nigde. Four parameters such as coarse-grained fraction ratio (CG), fine-grained fraction ratio (FG), plasticity index (PI) and maximum dry density (MDD) were presented to ANFIS model as inputs. The results obtained from the ANFIS models were validated with the data sets which are not used for the training stage. The analyses revealed that the predictions from ANFIS model are in sufficient agreement with test results.     

Convective and stratiform precipitation characteristics in an ensemble of regional climate model simulations

We apply a recently proposed algorithm for disaggregating observed precipitation data into predominantly convective and stratiform, and evaluate biases in characteristics of parameterized convective (subgrid) and stratiform (large-scale) precipitation in an ensemble of 11 RCM simulations for recent climate in Central Europe. All RCMs have a resolution of 25 km and are driven by the ERA-40 reanalysis. We focus on mean annual cycle, proportion of convective precipitation, dependence on altitude, and extremes. The results show that characteristics of total precipitation are often better simulated than are those of convective and stratiform precipitation evaluated separately. While annual cycles of convective and stratiform precipitation are reproduced reasonably well in most RCMs, some of them consistently and substantially overestimate or underestimate the proportion of convective precipitation throughout the year. Intensity of convective precipitation is underestimated in all RCMs. Dependence on altitude is also simulated better for stratiform and total precipitation than for convective precipitation, for which several RCMs produce unrealistic slopes. Extremes are underestimated for convective precipitation while they tend to be slightly overestimated for stratiform precipitation, thus resulting in a relatively good reproduction of extremes in total precipitation amounts. The results suggest that the examined ensemble of RCMs suffers from substantial deficiencies in reproducing precipitation processes and support previous findings that climate models’ errors in precipitation characteristics are mainly related to deficiencies in the representation of convection.     

上海城市发展的环境问题及其对策研究

上海市的发展战略;空间布局模式和环境管理是文章讨论的三个主要问题。作者认为:(1)战略设想要立足于上海的发展,“开发浦东、振兴上海、服务全国、面向世界;”(2)新的空间布局模式应为“逐步形成新的CBD,强化和完善金融和服务功能”;(3)城市发展和环境建设要协调。文章着重讨论了上海城市发展中出现的环境问题及其治理的对策和措施。     

Petrophysical and geochemical constraints on alteration processes in granites

The hydrothermal alteration of granites has large influence on their petrophysical properties. To reveal the impact of alteration on magnetic and porosity properties of granites we have conducted a complex study of effects of two largely independent alteration processes, related to chemically different fluids, in granites of the Vysoký Kámen stock (the Krudum granite body, Czech Republic). It includes the whole-rock geochemical, magnetic and pore-space characterization. The alkali feldspathization resulted in decomposition of Li-mica, quartz removal, depletion in mafic cations and growth of new alkali feldspars (albite, K-feldspar), decreasing the overall magnetic susceptibility and disrupting the pore space by its discontinuation. The preservation of the orientation of the principal susceptibility axes is likely related to insignificant influence of the feldspathization process on the paramagnetic and diamagnetic phases orientation acquired during the magma emplacement. The greisenization, on the other hand had considerably more significant effects on microstructure and physical properties of the granite. The microstructure was modified by the growth of large amounts of new phases (Li-mica, quartz and topaz). This changed the mineral density of the rock, the porosity, size and character of pores to larger, flatter and probably more connected. This led also to the complete reworking of the original anisotropy of magnetic susceptibility during the greisenization.     

Soil gas radon concentrations along the Ganos Fault (GF)

In this study, soil radon levels have been measured for the first time across the Ganos fault (GF), which is known as the western part of the North Anatolian Fault Zone. LR 115 Type 2 Solid State Nuclear Track Detectors (time integrated) have been applied to determine soil gas radon levels, and the survey was performed in 16 stations along the fault line. The results showed that soil gas radon concentrations and variation of concentration levels are comparable high along the fault line. It is also observed that in the middle of the Ganos Fault, fairly elevated radon levels were detected. These can be related to the activity of the fault lines. It is confirmed that the study area has a very active tectonic structure and is great location for analyzing radon variations.     

一次极端寒潮天气过程等熵位涡分析

利用2016年1月1日至31日的FNL资料,对一次极端寒潮天气过程进行了等熵位涡分析。结果表明:高位涡主体由极涡分裂而来,前面低位涡区的阻挡与后侧低位涡大气的北上加强了位涡的经向交换,高位涡空气不断由极地向南输送,使得高位涡主体不断加强维持。高位涡在由北向南移动的同时,也由对流层顶向下输送。此次寒潮过程主要有3股冷空气由上而下发展,位置均在高空急流轴的北侧,最南端的一股下沉气流最旺盛,这是其与高空急流相互作用的结果。强盛的冷空气下沉使得寒潮影响范围触及我国华南地区。随着高位涡的向南向下传输,一方面引起对流层中高层低涡系统迅速发展,当它移到中国东部地区时,东亚大槽迅速加深,使槽后强冷空气迅速向南爆发;另一方面,在高位涡输送的过程中,其后侧有强烈的下沉运动,使得地面冷高压快速发展,导致强寒潮天气的爆发。