Chemical composition of precipitation at Mt. Vesuvius and Vulcano Island,Italy: volcanological and environmental implications

Natural precipitation and water samples from passive devices were collected at Mt. Vesuvius and Vulcano Island, Italy, during the period 2004–2006, in order to investigate its possible interactions with fumarolic gases. Evidence of chemical reactions between fumarolic fluids and rain samples before and after its deposition into the sampling devices was found at Vulcano Island. Very low pH values (down to 2.5) and significant amounts of chlorine and sulfate (up to 22 mEq/l) were measured at sampling points located close to the fumarolic field. In contrast, anthropogenic contributions and/or dissolution of aerosols (both maritime and continental) influence the chemistry of rainwaters at Mt. Vesuvius, which show inter-annual variations that are highly consistent with those recorded at the coastal site at Vulcano Island. Chemistry of waters directly exposed to fumarolic fluids may then give useful information about its temporal evolution, holding the signal of the “maximum” chemical event occurred in the meanwhile. In addition, the observation of the health status of vegetation colonizing the immediate surroundings of the fumarolic fields, due to its strong dependence on the interactions with these fluids, may work as a possible biomarker of volcanic activity.     

Distribution patterns of chlorophyll <Emphasis Type="Italic">a</Emphasis> in spring and autumn in association with hydrological features in the southern Yellow Sea and northern East China Sea

Two field studies were conducted to measure pigments in the Southern Yellow Sea (SYS) and the northern East China Sea (NECS) in April (spring) and September (autumn) to evaluate the distribution pattern of phytoplankton stock (Chl a concentration) and the impact of hydrological features such as water mass, mixing and tidal front on these patterns. The results indicated that the Chl a concentration was 2.43±2.64 (Mean ± SD) mg m^?3 in April (range, 0.35 to 17.02 mg m^?3) and 1.75±3.10 mg m^?3 in September (from 0.07 to 36.54 mg m^?3) in 2003. Additionally, four areas with higher Chl a concentrations were observed in the surface water in April, while two were observed in September, and these areas were located within or near the point at which different water masses converged (temperature front area). The distribution pattern of Chl a was generally consistent between onshore and offshore stations at different depths in April and September. Specifically, higher Chl a concentrations were observed along the coastal line in September, which consisted of a mixing area and a tidal front area, although the distributional pattern of Chl a concentrations varied along transects in April. The maximum Chl a concentration at each station was observed in the surface and subsurface layer (0–10 m) for onshore stations and the thermocline layer (10–30 m) for offshore stations in September, while the greatest concentrations were generally observed in surface and subsurface water (0–10 m) in April. The formation of the Chl a distributional pattern in the SYS and NECS and its relationship with possible influencing factors is also discussed. Although physical forces had a close relationship with Chl a distribution, more data are required to clearly and comprehensively elucidate the spatial pattern dynamics of Chl a in the SYS and NECS.     

Antiangiogenic activity of low-temperature lysozyme from a marine bacterium <Emphasis Type="Italic">in vivo</Emphasis> and <Emphasis Type="Italic">in vitro</Emphasis>

We extracted marine low-temperature lysozyme (MLTL), a novel lysozyme, from a marine microorganism through fermentation. Our previous study suggested that a low molecular weight (16 kDa) may exert anti-tumor activity through antiangiogenesis. In this study, we extracted a high weight (39 kDa) and investigated its antiangiogenic activity in vivo and in vitro. Using zebrafish embryos as an in vivo study model, we found that treatment with MLTL significantly inhibited the growth of subintestinal vessels (SIVs) in a dose-dependent manner and that 400 μg/ml MLTL was sufficient to block the growth of SIVs. An in vitro study conducted using human umbilical vein endothelial cells (HUVECs) revealed that MLTL suppressed the proliferation, migration and tube formation of HUVECs in a dose-dependent manner. Interestingly, assays by flow cytometry and DNA electrophoresis indicated that MLTL was able to induce apoptosis of HUVECs. Moreover, further study demonstrated that the disruption of intracellular Ca²⁺ homeostasis may play an important role in MLTL induced apoptosis of HUVECs. Taken together, the results of this study demonstrate for the first time that MLTL inhibits angiogenesis through its pleiotropic effects on vascular endothelial cells and induces apoptosis through regulation of cellular Ca²⁺ levels. The results of this study also revealed a possible mechanism underlying the antiangiogenic effect of MLTL and suggested that MLTL may be a promising new antiangiogenic agent for use in cancer therapy.     

Peat humification- and δ<Superscript>13</Superscript>C<Subscript>cellulose</Subscript>-recorded warm-season moisture variations during the past 500 years in the southern Altai Mountains within northern Xinjiang of China

To predict future spatio-temporal patterns of climate change, we should fully understand the spatio-temporal patterns of climate change during the past millennium. But, we are not yet able to delineate the patterns because the qualities of the retrieved proxy records and the spatial coverage of those records are not adequate. Northern Xinjiang of China is one of such areas where the records are not adequate. Here, we present a 500-yr land-surface moisture sequence from Heiyangpo Peat (48.34°N, 87.18°E, 1353 m a.s.l) in the southern Altai Mountains within northern Xinjiang. Specifically, peat carbon isotope value of cellulose (δ¹³C_cellulose) was used to estimate the warm-season moisture variations and the degree of humification was used to constrain the δ¹³C_cellulose-based hydrological interpretation. The climatic attributions of the interpreted hydrological variations were based on the warm-season temperature reconstructed from Belukha ice core and the warm-season precipitation inferred from the reconstructed Atlantic Multidecadal Oscillations (AMO). The results show that humification decreased and the δ¹³C_cellulose-suggested moisture decreased from ~1510 to ~1775 AD, implying that a constant drying condition may have inhibited peat decay. Our comparison with reconstructed climatic parameters suggests that the moisture-level decline was most likely resulted from a constant decline of precipitation. The results also show that humification kept a stable level and the δ¹³C_cellulose-suggested moisture also decreased from ~1775 to ~2013 AD, implying that peat decay in the acrotelm primarily did not depend on the water availability or an aerobic environment. Again, our comparison with reconstructed climatic parameters suggests that the land-surface moisturelevel decline was most likely resulted from a steady warming of growing-season temperature.     

Discrete numerical modeling of granular materials considering crushability

The aim of this study is to numerically investigate the influence of particle breakage on the mechanical behavior of granular materials using a discrete element method (DEM). To enable particle crushing, non-crushable elementary particles are boned together to represents the granular aggregates which can be crushed when the external force exceeds its strength. The flaw of the aggregate was also modeled by randomly distributed void. Single particle crushing tests were carried out to determine the distribution of particle strength. The results of single particle crushing tests illustrate that the simulated single particle fracture strength and pattern agree well with the Weibull’s distribution equation. Conventional oedometer tests, drained monotonic and cyclic triaxial tests were also carried out to investigate the crushing of the aggregates and the associated mechanical behaviors. The effect of confining pressure on the crushing of aggregates and the mechanical behavior was also analyzed. It was found that the peak stress and dilation decrease significantly when particle crushing was considered. The deformation behavior of the specimen is essentially controlled by two factors: particle rearrangement - induced dilation and particle crushing - induced contraction. The increase of permanent strain and the reduction of dilation were observed during cyclic loading and they tend to reach a stable state after a certain number of cycles. The crushing of aggregate is most significant in the first two cycles. The results also indicated that for the same axial strain the volumetric strain and the bound breakage in the cyclic loading tests are significantly larger than that in the monotonic loading tests, especially at high cyclic stress ratio.     

Selecting suitable sites for mountain ginseng (<Emphasis Type="Italic">Panax ginseng</Emphasis>) cultivation by using geographically weighted logistic regression

With the well-being trends to pursue a healthy life, mountain ginseng (Panax ginseng) is rising as one of the most profitable forest products in South Korea. This study was aimed at evaluating a new methodology for identifying suitable sites for mountain ginseng cultivation in the country. Forest vegetation data were collected from 46 sites and the spatial distribution of all sites was analyzed using GIS data for topographic position, landform, solar radiation, and topographic wetness. The physical and chemical properties of the soil samples, including moisture content, pH, organic matter, total nitrogen, exchangeable cations, available phosphorous, and soil texture, were analyzed. The cultivation suitability at each site was assessed based on the environmental conditions using logistic regression (LR) and geographically weighted logistic regression (GWLR) and the results of both methods were compared. The results show that the areas with northern aspect and higher levels of solar radiation, moisture content, total nitrogen, and sand ratio are more likely to be identified as suitable sites for ginseng cultivation. In contrast to the LR, the spatial modeling with the GWLR results in an increase in the model fitness and indicates that a significant portion of spatial autocorrelation in the data decreases. A higher value of the area under the receiver operating characteristic (ROC) curve presents a better prediction accuracy of site suitability by the GWLR. The geographically weighted coefficient estimates of the model are non-stationary, and reveal that different site suitability is associated with the geographical location of the forest stands. The GWLR increases the accuracy of selecting suitable sites by considering the geographical variations in the characteristics of the cultivation sites.     

A satellite relative motion model including $$J_2$$ and $$J_3$$J3 via Vinti’s intermediary

Vinti’s potential is revisited for analytical propagation of the main satellite problem, this time in the context of relative motion. A particular version of Vinti’s spheroidal method is chosen that is valid for arbitrary elliptical orbits, encapsulating \(J_2\), \(J_3\), and generally a partial \(J_4\) in an orbit propagation theory without recourse to perturbation methods. As a child of Vinti’s solution, the proposed relative motion model inherits these properties. Furthermore, the problem is solved in oblate spheroidal elements, leading to large regions of validity for the linearization approximation. After offering several enhancements to Vinti’s solution, including boosts in accuracy and removal of some singularities, the proposed model is derived and subsequently reformulated so that Vinti’s solution is piecewise differentiable. While the model is valid for the critical inclination and nonsingular in the element space, singularities remain in the linear transformation from Earth-centered inertial coordinates to spheroidal elements when the eccentricity is zero or for nearly equatorial orbits. The new state transition matrix is evaluated against numerical solutions including the \(J_2\) through \(J_5\) terms for a wide range of chief orbits and separation distances. The solution is also compared with side-by-side simulations of the original Gim–Alfriend state transition matrix, which considers the \(J_2\) perturbation. Code for computing the resulting state transition matrix and associated reference frame and coordinate transformations is provided online as supplementary material.     

On the energy integral for first post-Newtonian approximation

The post-Newtonian approximation for general relativity is widely adopted by the geodesy and astronomy communities. It has been successfully exploited for the inclusion of relativistic effects in practically all geodetic applications and techniques such as satellite/lunar laser ranging and very long baseline interferometry. Presently, the levels of accuracy required in geodetic techniques require that reference frames, planetary and satellite orbits and signal propagation be treated within the post-Newtonian regime. For arbitrary scalar W and vector gravitational potentials \(W^j (j=1,2,3)\), we present a novel derivation of the energy associated with a test particle in the post-Newtonian regime. The integral so obtained appears not to have been given previously in the literature and is deduced through algebraic manipulation on seeking a Jacobi-like integral associated with the standard post-Newtonian equations of motion. The new integral is independently verified through a variational formulation using the post-Newtonian metric components and is subsequently verified by numerical integration of the post-Newtonian equations of motion.     

An Anisotropic Cosmic-Ray Enhancement Event on 07-June-2015: A Possible Origin

A usual event, called anisotropic cosmic-ray enhancement (ACRE), was observed as a small increase (\({\leq}\,5\%\)) in the count rates of polar neutron monitors during 12?–?19 UT on 07 June 2015. The enhancement was highly anisotropic, as detected only by neutron monitors with asymptotic directions in the southwest quadrant in geocentric solar ecliptic (GSE) coordinates. The estimated rigidity of the corresponding particles is \({\leq}\,1\) GV. No associated detectable increase was found in the space-borne data from the Geostationary Operational Environmental Satellite (GOES), the Energetic and Relativistic Nuclei and Electron (ERNE) on board the Solar and Heliospheric Observatory (SOHO), or the Payload for Antimatter Matter Exploration and Light-nuclei Astrophysics (PAMELA) instruments, whose sensitivity was not sufficient to detect the event. No solar energetic particles were present during that time interval. The heliospheric conditions were slightly disturbed, so that the interplanetary magnetic field strength gradually increased during the event, followed by an increase of the solar wind speed after the event. It is proposed that the event was related to a crossing of the boundary layer between two regions with different heliospheric parameters, with a strong gradient of low-rigidity (\({<}\,1\) GV) particles. It was apparently similar to another cosmic-ray enhancement (e.g., on 22 June 2015) that is thought to have been caused by the local anisotropy of Forbush decreases, with the difference that in our case, the interplanetary disturbance was not observed at Earth, but passed by southward for this event.