量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

辽宁省深部构造特征及其地质意义

本文应用了最新取得的“五统一”区域重力成果，并经过对浅表松散槽（如下辽河断陷，大岩体等）的密度亏损进行补偿改正后，求取了全省的区域重力场及其垂向二次导数，计算了莫氏面等深度图。在分析区域重力场及其垂向二次导数异常特征和莫氏面起伏特征的基础上，划分出辽宁深部构造的基本格局。从平面上探讨了深部构造与地形地势、地质构造及矿产分布的关系，从剖面上剖析了辽宁省地壳分层的宏观特征     

THE EFFECT OF DRAINAGE ON CHEMICALELEMENTS CONTENT OF MARSH

I INTRODUCTIONWetland has very important effect on retainingwater and against drought, regUlating climate, controlling soil erosion and so on ac. Today men often attachimportance to economic effect of wetland reclamation,but neglect and destroy other functions and effectswhich result in blind wetland development, a lot ofwetland degeneration. The area of freshwater wetland inthe 1950s was 134 x 10'ha, but in the 1970s 70% hadchanged into farmland (MITSCH, 1993). The area ofwetland in d…     

ELECTROCHEMICAL CORROSION BEHAVIOR OF STEEL IN THE JUNCTURE AREA OF SEA CLAY AND SAND

Corrosion behavior of steel in the juncture area of sea clay and sand was studied. The results show that galvanic corrosion occurred between steel samples buried in sea clay and sand, and that the polarity of the galvanic cell reversed after some testing later. The cause of reversing of polarity is discussed.     

金州地区震旦系基本层序与沉积环境

金州地区广泛发育震旦纪地层,具分布连续、出露完整、沉积相标志明显的特点。本文运用现代沉积学和地层学理论,对区内震旦系岩石地层进行了基本层序研究与沉积环境分析。     

NORTHERN AND SOUTHERN HEMISPHERIC POLAR LOWS——A COMPARATIVE STUDY

Northern Hemispheric“polar lows”,i.e.maritime,small,but fairly intense cyclonic systems have been studied formore than two decades.Recently researchers have turned their attention towards the occurrence of polar lows and othersmall-scale cyclonic disturbances on the Southern Hemisphere.In this paper a short account of our present knowledgeof Northern Hemispheric polar lows will be given,followed by some preliminary results of an investigation of the natureand occurrence of polar lows on the Southern Hemisphere.     

K-H Instability of Dust Plasma

Areview about K-H instability related to comet tail is presented.The effect of dust graing on KHI is theoretically analysed and relations of critical shear to excit KHI with the properties of dust grains both for sheared ion flow and for sheared dust flow re put out.Their possible application in comet tail is suggested.     

自动高精度测距系统

介绍了自动高精度测距系统。该系统能以５×１０－７的测距精度测定多个观测点的形变，可作为跨断层动态连续观测的新仪器。