松辽盆地姚家组—嫩江组沉积演化与成藏响应

松辽盆地姚家组—嫩江组是一套完整的基准面升降旋回沉积地层,嫩江组二段底部最大湖泛面形成了盆地范围内稳定分布的油页岩,不仅是层序及地层对比的标准界面,而且成为重要的烃源岩层和盖层。姚家组及嫩江组一段是湖进形成的大型湖泊与退积型三角洲沉积,嫩江组二段到五段是强制性水退形成的大型湖泊与进积三角洲沉积;在湖进期嫩江组一段长轴物源方向发育大型重力流水道及末端浊积扇沉积,在嫩江组二段强制性水退环境下进积型三角洲前方发育大型滑塌扇沉积;储集层是湖进-湖退过程中形成的大型三角洲复合体,以分流河道、河口坝及席状砂体为特征,这些砂体向湖盆中心延伸楔入湖相泥岩及成熟烃源岩中,形成良好的生储盖组合关系,特别是盆地长轴物源方向发育的大型三角洲复合体成为油藏集中发育的良好场所,是松辽盆地成为巨型陆相含油气盆地的重要地质条件,同时重力流水道及滑塌扇体也具有形成岩性油气藏的有利条件,是不可忽视的勘探领域。     

内蒙古孟恩陶勒盖银铅锌矿床白云母Ar-Ar年龄及其意义

文章采用Ar_Ar同位素测年法对孟恩陶勒盖银铅锌矿云英岩化阶段形成的白云母进行了测试 ,获得白云母坪年龄为 (179.0± 1.5 )Ma ,等时线年龄为 (182 .3± 3.8)Ma。这组数据近似地代表了该矿床的形成年龄 ,同时也显示该地区除已知的晚侏罗_早白垩世构造_岩浆_成矿作用外 ,还有一期重要的早侏罗_中侏罗世构造_岩浆_热液成矿事件 ,这也是到目前为止所获得的大兴安岭中南段热液矿床最老的成矿年龄     

青藏高原唐古拉山冬克玛底河流域水文过程特征分析

利用１９９３年５￣９月连续时间序列的资料，对青藏高原唐古拉山冬克玛底冰川区及其流域的水文过程特征进行初步分析。由于青藏高原季风环流的影响，在性质不同气团控制所产生的降水天然过程的降水量差别极大，该区域主要降水集中在６￣８月，Ｔｒｅｔｙａｋｏｖ雨量器对标准雨量器捕捉率的修正量小于天山地区的研究结果，该流域地面蒸发过程较为强盛，各种下垫面的蒸发量占流域水量平衡收入的３７％，土壤蒸发量与水面蒸发和土壤含     

鄂尔多斯盆地上古生界碎屑岩相对高渗储集层成因及分布*

鄂尔多斯盆地上古生界发育 “粒间孔型石英砂岩”、“溶孔型石英砂岩”、“粒间孔—溶孔复合型长石砂岩”3类相对高渗储集层。结合鄂尔多斯盆地地质背景,分析了该地区上古生界3类相对高渗储集层的岩石结构、组分与物性等基本特征,详细探讨了沉积环境、成岩作用、构造活动对鄂尔多斯盆地上古生界各类相对高渗储集层形成的控制机理,并在此基础上,依据与物源的距离、沉积相类型及砂体分布、孔隙类型、颗粒成分及粒度粗细、杂基成分及含量、储集层最大埋深、后期构造运动等因素,对主力勘探层系山西组二段和下石盒子组八段进行了储集层优劣分级综合评价,认为受高石英含量母岩控制的沉积体系、辫状河高能沉积相带和强溶蚀、弱压实的有利成岩相带分布区是鄂尔多斯盆地上古生界碎屑岩相对高渗储集层的主要发育区域。     

中国桐柏大别构造带变质演化的岩石学证迹

桐柏大别构造带是秦岭造山带的东延部分，经历过多期次不同体制的构造运动，现今的桐柏大别山区是由一系列变质地体拼合而成，地体与地体之间为断层或韧性剪切带所围限各地体有自身变质变形史和PTt轨迹，但却有着碰撞造山带所共有的后造山抬升过程。本文揭示了随县群、红安岩群及大别杂岩中柯石英榴辉石、蓝晶铝直闪石片岩及紫苏石榴黑云母片麻岩的退变质再平衡结构特点。报道了大别山麻粒岩相变质年龄为1699Ma。各类岩石减压退变质再平衡结构，标志着后造山的隆升过程及其对桐柏大别构造带变质演化的启示。     

Adsorption and Desorption of Phosphate on Calcite and Aragonite in Seawater

The adsorption and desorption of phosphate on calcite and aragonite were investigated as a function of temperature (5–45 °C)and salinity (0–40) in seawater pre-equilibrated with CaCO₃. An increase in temperature increased the equilibrium adsorption; whereas an increase in salinity decreased the adsorption. Adsorption measurements made in NaCl were lower than the results in seawater. The higher values in seawater were due to the presence of Mg²⁺ and Ca²⁺ ions. The increase was 5 times greater for Ca²⁺ than Mg²⁺. The effects ofCa²⁺ and Mg²⁺ are diminished with the addition of SO₄ ^2- apparently due to the formation of MgSO₄ and CaSO₄ complexes in solution and/or SO₄ ^2- adsorption on the surface of CaCO₃. The adsorbed Ca²⁺ and Mg²⁺ on CaCO₃ (at carbonate sites) may act as bridges to PO₄ ^3- ions. The bridging effect of Ca²⁺is greater than Mg²⁺ apparently due to the stronger interactions of Ca²⁺ with PO₄ ^3-.The apparent effect of salinity on the adsorption of PO₄ was largely due to changes in the concentration of HCO₃ ^- in the solutions. An increase in the concentration of HCO₃ ^- caused the adsorption of phosphate to decrease, especially at low salinities. The adsorption at the same level of HCO₃ ^- (2 mM) was nearly independent of salinity. All of the adsorption measurements were modeled empirically using a Langmuir-type adsorption isotherm[ [PO₄]_ad = K_mC_m[PO₄]_T/(1 +K_m [PO₄]_T) , ]where [PO₄]_ad and [PO₄]_T are the adsorbed and total dissolved phosphate concentrations, respectively. The values of C_m (the maximum monolayer adsorption capacity, (mol/g) and K_m (the adsorption equilibrium constant, g/(mol) over the entire temperature (t, °C) and salinity (S) range were fitted to[ C_m = 17.067 + 0.1707t - 0.4693S + 0.0082S² ( = 0.7) ][ ln K_m = - 2.412 + 0.0165t - 0.0004St - 0.0008S² ( = 0.1) ]These empirical equations reproduce all of our measurements of[PO₄]_ad up to 14 mol/g and within ±0.7 mol/g.The kinetic data showed that the phosphate uptake on carbonate minerals appears to be a multi-step process. Both the adsorption and desorption were quite fast in the first stage (less than 30 min) followed by a much slower process (lasting more than 1 week). Our results indicate that within 24 hours aragonite has a higher sorption capacity than calcite. The differences between calcite and aragonite become smaller with time. Consequently, the mineral composition of the sediments may affect the short-term phosphate adsorption and desorption on calcium carbonate. Up to 80 % of the adsorbed phosphate is released from calcium carbonate over one day. The amount of PO₄ left on the CaCO₃ is close to the equilibrium adsorption. The release of PO₄ from calcite is faster than from aragonite. Measurements with Florida Bay sediments produced results between those for calcite and aragonite. Our results indicate that the calcium carbonate can be both a sink and source of phosphate in natural waters.     

黔中开阳磷矿沉积区震旦纪陡山沱期定量岩相古地理重建*

磷矿的沉积和成矿与成磷期的古地理环境密切相关。本文首次将“单因素分析多因素综合作图法”运用于开阳地区震旦纪陡山沱期沉积型磷矿床的成矿分析和找矿预测上。通过选取陡山沱组及其各岩性段的地层厚度及磷矿层品位作为单因素,确定开阳地区古地理格局;结合地层岩性组合、沉积特征等多因素综合分析,恢复开阳地区成矿期沉积环境,编制陡山沱早期、中期和晚期岩相古地理图。根据定量岩相古地理重建结果,认为开阳地区陡山沱期整体处于南靠黔中古陆、地势南高北低、局部地形复杂的滨岸海滩沉积环境,其中临滨带为最有利成矿带,局部地形变化也会造成矿层厚度、品位的差异;矿层受到的水流冲蚀、暴露、淋滤及再沉积作用是导致矿石品位显著提升的关键因素。通过定量岩相古地理学精确还原成矿期古地理环境、解析多期次沉积成矿过程,对于确定磷矿控矿因素、构建找矿预测模型和预测矿体空间位置具有重要意义。     

Major element geochemistry of purple soils/rocks in the red Sichuan Basin, China: implications of their diagenesis and pedogenesis

Major element compositions and chemical weathering features of the purple soils and their corresponding rocks in the Red Sichuan Basin, China were studied in this paper to infer the diagenetic features of the purple rocks and the pedogenetic features of the purple soils. The results showed that all of the rock and soil samples, except those from Yibin, have strongly similar major element compositions and the distribution patterns of their major element compositions are similar to those of the upper continental crust. Chemical index of alteration, chemical index of weathering and Na₂O/K₂O indicate that the purple soils and rocks have similar chemical weathering intensities, whereas the Al₂O₃–CaO* + Na₂O–K₂O (A–CN–K) relationship, suggests that chemical weathering was strong during diagenesis of the purple rocks, but weak during pedogenesis of the purple soils. Variations in major element compositions of the purplish rock samples, except that from Yibin, do not primarily reflect differences in compositions of the sediment source, sediment recycling and potassium metasomatism, and therefore the effects of chemical weathering on the major element compositions were mainly dependent on climate condition and the residence time of material exposed to chemical weathering. Chemical weathering of the purple rocks reached only moderate degrees under the general influence of warm and humid climate during Jurassic and Cretaceous. Warmer and more humid climate conditions partly resulted in stronger chemical weathering of rocks in the southern region of the basin than in the central and western region, whereas shorter residence time of material in upslope position partly resulted in weaker chemical weathering of rocks in the eastern region than in the central and western region. The same climate and stable tectonic setting led to comparable chemical weathering intensities of rocks in the Ziliujing and Jiaguan Formations. Gradually colder and dryer climate from Early Jurassic to Middle Jurassic then to Late Jurassic and shorter residence time in tectonically active setting of Middle Jurassic and late Late Jurassic resulted in the following order of chemical weathering intensity of the purple Jurassic rocks: Ziliujing Formation ? Shaximiao Formation ≈ Suining Formation > Penglaizhen Formation.     

皖南花山锑金矿床硫化物电子探针分析及其指示意义

花山锑金矿床位于皖南东至县境内, 是皖南地区代表性金-多金属矿床之一。 本次工作对花山锑金矿床开展了野外地质、岩相学特征观察以及金属硫化物电子探针分析, 得到以下结论：1） 花山锑金矿床主要成矿阶段可分为毒砂-黄铁矿（PyⅠ）阶段、黄铜矿-黄铁矿 （PyⅡ）阶段和方解石-辉锑矿阶段。 2） 金在不同阶段硫化物中均有赋存, 其矿化伴随整个热液成矿过程, 且以毒砂-PyⅠ阶段和黄铜矿-PyⅡ阶段为主。 毒砂-PyⅠ阶段和黄铜矿-PyⅡ阶段发育金矿化, 无锑矿化, 方解石-辉锑矿阶段发育锑、金共生矿化。 3） 早阶段即毒砂 -PyⅠ阶段和黄铜矿-PyⅡ阶段载金矿物为黄铁矿、毒砂及黄铜矿, 成矿物质来源以地层为 主;晚阶段即方解石-辉锑矿阶段载金矿物为辉锑矿, 成矿物质来源以燕山期岩浆岩为主。 本次工作对东至及皖南地区金矿床的寻找勘探具有重要的指示意义。     

黑矿型矿床成矿物质来源：日本上向黑矿铼—锇和氦同位素证据

上向黑矿（Uwamuki Kuroko)是日本最典型的黑矿型矿床，它形成于日本岛弧中新世矢折岛弧裂谷环境，产于双峰式岩石组合的长英质火山岩系中。矿床由下部筒状硅矿带和上部块状黑矿带构成，后者显示典型的上黑（黑矿）下黄（黄矿）金属分带。为探索研究长期争议的成矿物质来源，系统测定了矿石和主岩的Os,He同位素组成。含矿流纹岩系的R／RA值介于0．93－1．14间，证实该岩浆可能主要来源于陆壳重熔。上向黑矿的上部块状黑矿矿石具较高的^187Os/^188Os值（2．246－7．608），反映矿石Os主体来源于壳源沉积物或矿区基底岩系；下部脉状－网脉状硅矿、块状黄矿和少量黑矿则具低^187Os/^188Os值（0．423－0．793），证实矿石Os具两源性，估计幔源物质贡献约57％－89％，壳源物质贡献约11％－43％。此外，在上部块状黑矿带内部，矿石 ^187Os/^188O显示清楚的垂向韵律性变化，揭示了成矿流体及成矿物质的周期性混合，据此，本文提出了一个新的两阶段成矿模式。