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121.
Glacier change and glacier runoff variation in the Tuotuo River basin,the source region of Yangtze River in western China 总被引:3,自引:0,他引:3
Glaciers in the Tuotuo River basin, western China, have been monitored in recent decades by applying topographical maps and
high-resolution satellite images. Results indicate that most of glaciers in the Tuotuo River basin have retreated in the period
from 1968/1971 to 2001/2002, and their shrinkage area is 3.2% of the total area in the late 1960s. To assess the influence
of glacier runoff on river runoff, a modified degree–day model including potential clear-sky direct solar radiation has been
applied to the glaciated regions of the river basin over the period 1961–2004. It was found that glacier runoff has increased
in the last 44 years, especially in the 1990s when a two-thirds increase in river runoff was derived from the increase in
glacier runoff caused by loss of ice mass in the entire Tuotuo River basin. 相似文献
122.
Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined
aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai
area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths
through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results
indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO2, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the
unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths. 相似文献
123.
Yuan-Bao Wu Shan Gao Hong-Fei Zhang Sai-Hong Yang Wen-Fang Jiao Yong-Sheng Liu Hong-Lin Yuan 《Contributions to Mineralogy and Petrology》2008,155(1):123-133
The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP
eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic
evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an
eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons
are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies.
These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf
isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ LuN ≥ 14) and 176Lu/177Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental
subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and 176Lu/177Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age
are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U
ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon
cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that
their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf
model ages (T
DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
124.
By using continuous helium flow during the crushing of calcite speleothem samples, we are able to recover liberated inclusion waters without isotopic fractionation. A paleotemperature record for the Jacklah Jill Cave locality, Vancouver Island, BC, was obtained from a 30-cm tall stalagmite that grew 10.3-6.3 Ka ago, using δ18O values of the crushed calcite and of the inclusion water as inferred from its δD. It is found that the locality experienced mean annual temperature variations up to 11 °C over a 4-Ka period in the early Holocene. At the beginning of the period, local temperature quickly increased from a minimum of ∼1 °C to around 10 °C, but this early climate optimum, about 3 °C warmer than today, only lasted for ∼1200 years. About 8.6 Ka ago, temperature had declined to ∼7 °C, approximately the same as the modern cave temperature. Since then, the study area has experienced only minor temperature fluctuations, but there was a brief fall to ∼4 °C at around 7 Ka ago, which might be caused by a short lived expansion of local alpine glaciers. The long-term T-dependence of δD was 1.47‰/°C, identical to the value in modern precipitation. 相似文献
125.
Silicon isotope fractionation in bamboo and its significance to the biogeochemical cycle of silicon 总被引:2,自引:0,他引:2
A systematic investigation on silica contents and silicon isotope compositions of bamboos was undertaken. Seven bamboo plants and related soils were collected from seven locations in China. The roots, stem, branch and leaves for each plant were sampled and their silica contents and silicon isotope compositions were determined. The silica contents and silicon isotope compositions of bulk and water-soluble fraction of soils were also measured. The silica contents of studied bamboo organs vary from 0.30% to 9.95%. Within bamboo plant the silica contents show an increasing trend from stem, through branch, to leaves. In bamboo roots the silica is exclusively in the endodermis cells, but in stem, branch and leaves, the silica is accumulated mainly in epidermal cells. The silicon isotope compositions of bamboos exhibit significant variation, from −2.3‰ to 1.8‰, and large and systematic silicon isotope fractionation was observed within each bamboo. The δ30Si values decrease from roots to stem, but then increase from stem, through branch, to leaves. The ranges of δ30Si values within each bamboo vary from 1.0‰ to 3.3‰. Considering the total range of silicon isotope composition in terrestrial samples is only 7‰, the observed silicon isotope variation in single bamboo is significant and remarkable. This kind of silicon isotope variation might be caused by isotope fractionation in a Rayleigh process when SiO2 precipitated in stem, branches and leaves gradually from plant fluid. In this process the Si isotope fractionation factor between dissolved Si and precipitated Si in bamboo (αpre-sol) is estimated to be 0.9981. However, other factors should be considered to explain the decrease of δ30Si value from roots to stem, including larger ratio of dissolved H4SiO4 to precipitated SiO2 in roots than in stem. There is a positive correlation between the δ30Si values of water-soluble fractions in soils and those of bulk bamboos, indicating that the dissolved silicon in pore water and phytoliths in soil is the direct sources of silicon taken up by bamboo roots. A biochemical silicon isotope fractionation exists in process of silicon uptake by bamboo roots. Its silicon isotope fractionation factor (αbam-wa) is estimated to be 0.9988. Considering the distribution patterns of SiO2 contents and δ30Si values among different bamboo organs, evapotranspiration may be the driving force for an upward flow of a silicon-bearing fluid and silica precipitation. Passive silicon uptake and transportation may be important for bamboo, although the role of active uptake of silicic acid by roots may not be neglected. The samples with relatively high δ30Si values all grew in soils showing high content of organic materials. In contrast, the samples with relatively low δ30Si values all grew in soil showing low content of organic materials. The silicon isotope composition of bamboo may reflect the local soil type and growth conditions. Our study suggests that bamboos may play an important role in global silicon cycle. 相似文献
126.
Hydrogen sulfide (H2S) is known to catalyze thermochemical sulfate reduction (TSR) by hydrocarbons (HC), but the reaction mechanism remains unclear. To understand the mechanism of this catalytic reaction, a series of isothermal gold-tube hydrous pyrolysis experiments were conducted at 330 °C for 24 h under a constant confining pressure of 24.1 MPa. The reactants used were saturated HC (sulfur-free) and CaSO4 in the presence of variable H2S partial pressures at three different pH conditions. The experimental results showed that the in-situ pH of the aqueous solution (herein, in-situ pH refers to the calculated pH of aqueous solution under the experimental conditions) can significantly affect the rate of the TSR reaction. A substantial increase in the TSR reaction rate was recorded with a decrease in the in-situ pH value of the aqueous solution involved. A positive correlation between the rate of TSR and the initial partial pressure of H2S occurred under acidic conditions (at pH ∼3-3.5). However, sulfate reduction at pH ∼5.0 was undetectable even at high initial H2S concentrations. To investigate whether the reaction of H2S(aq) and occurs at pH ∼3, an additional series of isothermal hydrous pyrolysis experiments was conducted with CaSO4 and variable H2S partial pressures in the absence of HC at the same experimental temperature and pressure conditions. CaSO4 reduction was not measurable in the absence of paraffin even with high H2S pressure and acidic conditions. These experimental observations indicate that the formation of organosulfur intermediates from H2S reacting with hydrocarbons may play a significant role in sulfate reduction under our experimental conditions rather than the formation of elemental sulfur from H2S reacting with sulfate as has been suggested previously (Toland W. G. (1960) Oxidation of organic compounds with aqueous sulphate. J. Am. Chem. Soc.82, 1911-1916).Quantification of labile organosulfur compounds (LSC), such as thiols and sulfides, was performed on the products of the reaction of H2S and HC from a series of gold-tube non-isothermal hydrous pyrolysis experiments conducted at about pH 3 from 300 to 370 °C and a 0.1-°C/h heating rate. Incorporation of sulfur into HC resulted in an appreciable amount of thiol and sulfide formation. The rate of LSC formation positively correlated with the initial H2S pressure. Thus, we propose that the LSC produced from H2S reaction with HC are most likely the reactive intermediates for H2S initiation of sulfate reduction. We further propose a three-step reaction scheme of sulfate reduction by HC under reservoir conditions, and discuss the geological implications of our experimental findings with regard to the effect of formation water and oil chemistry, in particular LSC content. 相似文献
127.
A U–Pb sensitive high‐resolution ion microprobe (SHRIMP) age of 654.5 ± 3.8 Ma from an ash bed immediately below the Nantuo Formation in South China provides the lowest age constraint for the Nantuo glaciation, which has been correlated with the global ‘Marinoan’ glaciation. A U–Pb SHRIMP age of 636.3 ± 4.9 Ma from a fallout tuff within the basal layer of the Nantuo Formation, along with the existing age of 635.2 ± 0.6 Ma from its overlying Doushantuo cap carbonate, suggests that the traditionally defined Nantuo Formation may have been deposited in a short time period at the end of the Nantuo glaciation. In combination with available ages globally, the data support a relatively short duration and rapid termination of ‘Marinoan’ glaciations. 相似文献
128.
滑坡体三维地质建模与可视化分析 总被引:1,自引:0,他引:1
针对滑坡地质研究的自身特点,提出了面向滑坡地质体三维建模的NURBS-BRep混合数据结构和地质结构单元实体构造技术.通过对滑坡基础地质数据的预处理、滑坡数字地形和滑动面的三维建模、地质结构面的系统构造、地质结构体的生成和显示,形成了一套完整的滑坡三维地质模型的构建方法.将该方法应用于某水库滑坡,建立了相应的三维滑坡地质模型,并基于此模型进行了三维剖切分析、数字钻孔、等值线生成、滑块自动剖分、滑坡失稳可视化动态模拟和滑坡体方量精确计算等一系列实用的可视化分析,为滑坡稳定性的准确计算和客观评价提供了有力的支持. 相似文献
129.
130.
海拉尔盆地贝西斜坡北部地区储层特征及影响因素分析 总被引:2,自引:0,他引:2
通过测井曲线的标准化处理及信息提取、岩心及录井岩屑观察、铸体薄片、物性分析、扫描电镜、压汞分析等技术手段,研究了海拉尔盆地贝西斜坡北部地区南屯组储层的主要岩性特征、物性特征、储集空间类型和影响因素.研究结果表明.海拉尔盆地南屯组以内陆湖相碎屑岩为主,主要包括角砾岩、砾岩、砂砾岩、粗砂岩、细砂岩、粉砂岩、泥质砂岩及泥岩等.南一段储层孔隙度平均值为6.15%,渗透率平均值为0.31 × 10-3μm2,为低孔特低渗型孔隙特征;南二段储层孔隙度平均值为12.18%,渗透率平均值为2.79× 10-3μm2,属于中孔低渗型孔隙特征.储集空间类型以粒间孔隙为主,发育一定的次生孔隙.喉道分为4种类型(Ⅰ类、Ⅱ类、Ⅲ类、Ⅳ类).扇三角洲前缘分支水道砂体、扇三角洲平原辫状河道砂体和滨浅湖砂坝微相砂体为该区有利的储层砂体类型.储层性质主要受沉积相和成岩作用影响. 相似文献