Contrasting metamorphic evolution of metasedimentary rocks from the Çine and Selimiye nappes in the Anatolide belt, western Turkey

Abstract P–T conditions, mineral isograds, the relation of the latter to foliation planes and kinematic indicators are used to elucidate the tectonic nature and evolution of a shear zone in an orogen exhumed from mid‐crustal depths in western Turkey. Furthermore, we discuss whether simple monometamorphic fabrics of rock units from different nappes result from one single orogeny or are related to different orogenies. Metasedimentary rocks from the Çine and Selimiye nappes at the southern rim of the Anatolide belt of western Turkey record different metamorphic evolutions. The Eocene Selimiye shear zone separates both nappes. Metasedimentary rocks from the Çine nappe underneath the Selimiye shear zone record maximum P–T conditions of about 7 kbar and >550 °C. Metasedimentary rocks from the overlying Selimiye nappe have maximum P–T conditions of 4 kbar and c. 525 °C near the base of the nappe. Kinematic indicators in both nappes are related to movement on the Selimiye shear zone and consistently show a top‐S shear sense. Metamorphic grade in the Selimiye nappe decreases structurally upwards as indicated by mineral isograds defining the garnet‐chlorite zone at the base, the chloritoid‐biotite zone and the biotite‐chlorite zone at the top of the nappe. The mineral isograds in the Selimiye nappe run parallel to the regional S_R foliation, parallel the Selimiye shear zone and indicate that the Selimiye shear zone formed during this prograde greenschist to lower amphibolite facies metamorphic event but remained active after the peak of metamorphism. ⁴⁰Ar/³⁹Ar mica ages and the tectonometamorphic relationship with the Eocene Cyclades–Menderes thrust, which occurs above the Selimiye nappe in the study area, suggests an Eocene age of metamorphism in the Selimiye nappe. Metasedimentary rocks of the Çine nappe 20–30 km north of the Selimiye shear zone record maximum P–T conditions of 8–11 kbar and 600–650 °C. An age of about 550 Ma is indicated for amphibolite facies metamorphism and associated top‐N shear in the orthogneiss of the Çine nappe. Our study shows that simple monophase tectonometamorphic fabrics do not always indicate a simple orogenic development of a nappe stack. Preservation in some areas and complete overprinting of those fabrics in other areas apparently occur very heterogeneously.     

Oscillatory zoning in garnet from the Willsboro Wollastonite Skarn, Adirondack Mts, New York: a record of shallow hydrothermal processes preserved in a granulite facies terrane

Oscillatory zoning in low δ¹⁸O skarn garnet from the Willsboro wollastonite deposit, NE Adirondack Mts, NY, USA, preserves a record of the temporal evolution of mixing hydrothermal fluids from different sources. Garnet with oscillatory zoning are large (1–3 cm diameter) euhedral crystals that grew in formerly fluid filled cavities. They contain millimetre‐scale oscillatory zoning of varying grossular–andradite composition (X_Adr = 0.13–0.36). The δ¹⁸O values of the garnet zones vary from 0.80 to 6.26‰ VSMOW and correlate with X_Adr. The shape, pattern and number of garnet zones varies from crystal to crystal, as does the magnitude of the correlated chemistry changes, suggesting fluid system variability, temporal and/or spatial, over the time of garnet growth. The zones of correlated Fe content and δ¹⁸O indicate that a high Fe³⁺/Al, high δ¹⁸O fluid mixed with a lower Fe³⁺/Al and δ¹⁸O fluid. The high δ¹⁸O, Fe enriched fluids were likely magmatic fluids expelled from crystallizing anorthosite. The low δ¹⁸O fluids were meteoric in origin. These are the first skarn garnet with oscillatory zoning reported from granulite facies rocks. Geochronologic, stable isotope, petrologic and field evidence indicates that the Adirondacks are a polymetamorphic terrane, where localized contact metamorphism around shallowly intruded anorthosite was followed by a regional granulite facies overprint. The growth of these garnet in equilibrium with meteoric and magmatic fluids indicates an origin in the shallow contact aureole of the anorthosite prior to regional metamorphism. The zoning was preserved due to the slow diffusion of oxygen and cations in the large garnet and protection from deformation and recrystallization in zones of low strain in thick, rigid, garnetite layers. The garnet provide new information about the hydrothermal system adjacent to the shallowly intruded massif anorthosite that predates regional metamorphism in this geologically complex, polymetamorphic terrane.     

Paleozoic terranes of eastern Australia and the drift history of Gondwana

Critical assessment of Paleozoic paleomagnetic results from Australia shows that paleopoles from locations on the main craton and in the various terranes of the Tasman Fold Belt of eastern Australia follow the same path since 400 Ma for the Lachlan and Thomson superterranes, but not until 250 Ma or younger for the New England superterrane. Most of the paleopoles from the Tasman Fold Belt are derived from the Lolworth-Ravenswood terrane of the Thomson superterrane and the Molong-Monaro terrane of the Lachlan superterrane. Consideration of the paleomagnetic data and geological constraints suggests that these terranes were amalgamated with cratonic Australia by the late Early Devonian. The Lolworth-Ravenswood terrane is interpreted to have undergone a 90° clockwise rotation between 425 and 380 Ma. Although the Tamworth terrane of the western New England superterrane is thought to have amalgamated with the Lachlan superterrane by the Late Carboniferous, geological syntheses suggest that movements between these regions may have persisted until the Middle Triassic. This view is supported by the available paleomagnetic data. With these constraints, an apparent polar wander path for Gondwana during the Paleozoic has been constructed after review of the Gondwana paleomagnetic data. The drift history of Gondwana with respect to Laurentia and Baltica during the Paleozoic is shown in a series of paleogeographic maps.     

The early Caledonian (Finnmarkian) event reassessed in Finnmark: Ar/Ar cleavage age data from NW Varangerhalvøya, N. Norway

The relative significance of early (Finnmarkian) and late (Scandian) Caledonian deformation in N. Norway is uncertain. Early studies suggested pervasive Finnmarkian deformation whilst later results indicated a restricted Finnmarkian domain. The present work suggests it was more widespread than accepted and that inter Finnmarkian–Scandian deformation occurred. ⁴⁰Ar/³⁹Ar dating of 2–6 and 6–11 μm pelitic fractions from the lower to mid-greenschist facies Tanahorn Nappe (five samples; base Middle Allochthon) and the epizone Løkvikfjellet and Barents Sea Groups (three samples; North Varanger Region) in the north Scandinavian Caledonides show slightly discordant spectra. Most spectra from the Tanahorn Nappe preserve possible evidence of an early Caledonian event in the high temperature steps, with recoil/excess Ar effects in the low temperature steps; no pre-Caledonian relict component has been recorded. The results indicate Finnmarkian deformation continued to 460 Ma, with Scandian reactivation at 425–415 Ma. From the North Varanger Region, a strongly crenulated sample yielded plateau ages (444–442 Ma); means of combined young steps from weakly to uncrenulated samples gave 470–450 Ma, suggesting penetrative strike-slip deformation occurred in the late Finnmarkian to inter-Finnmarkian–Scandian period. No Scandian ages were recorded in the North Varanger Region. Reassessment of published data from the Laksefjord Nappe and Gaissa Thrust Belt suggests they were affected by Finnmarkian deformation.     

Eastern Laurentia in Rodinia: constraints from whole-rock Pb and U/Pb geochronology

Whole-rock Pb isotopic signatures and U/Pb geochronology refute a Rodinian correlation of northeastern Laurentia and proto-Andean Amazonia. According to this previously proposed model, the Labrador–Scotland–Greenland Promontory (LSGP) of northeastern Laurentia collided with the proto-Andean margin of Amazonia, at the Arica Embayment, during the Grenville/Sunsás Orogeny (ca. 1.0 Ga). Links between the two margins were based upon the correlation of the LSGP with Arequipa-Antofalla Basement (AAB), a Proterozoic block along the proto-Andean margin of Amazonia adjacent to the Arica Embayment. Specifically, similarities in 1.8–1.0 Ga basement rocks in both regions suggested that the AAB was originally a piece of the LSGP. Furthermore, similarities in unique, post-collisional, but pre-rift, glacial sedimentary sequences also supported a link between the AAB and LSGP.Tests of these apparent similarities fail to support correlation of the AAB and the LSGP and, thus, eliminate a direct link between northeastern Laurentia and southwestern Amazonia in Rodinia. However, Pb isotopic compositions and U/Pb geochronology provide the basis for two new correlations, namely, (1) the ca. 1.3–1.0 Ga basement in the central and southern Appalachians may be an allochthonous block that was transferred to Laurentia from Amazonia at ca. 1.0 Ga, and (2) an allochthonous AAB may be a piece of the Kalahari Craton that was transferred to Amazonia at ca. 1.0 Ga. Based on these new correlations and a previously proposed Grenvillian connection between southern Laurentia (Llano) and Kalahari, we propose that Amazonia may have collided with a contiguous southeastern Laurentia/Kalahari margin at ca. 1.0 Ga.     

From geometry to dynamics of microstructure: using boundary lengths to quantify boundary misorientations and anisotropy

The microstructure of a quartzite experimentally deformed and partially recrystallised at 900 °C, 1.2 GPa confining pressure and strain rate 10⁻⁶/s was investigated using orientation contrast and electron backscatter diffraction (EBSD). Boundaries between misoriented domains (grains or subgrains) were determined by image analysis of orientation contrast images. In each domain, EBSD measurements gave the complete quartz lattice orientation and enabled calculation of misorientation angles across every domain boundary. Results are analysed in terms of the boundary density, which for any range of misorientations is the boundary length for that range divided by image area. This allows a more direct comparison of misorientation statistics between different parts of a sample than does a treatment in terms of boundary number.The strain in the quartzite sample is heterogeneous. A 100×150 μm low-strain partially recrystallised subarea C was compared with a high-strain completely recrystallised subarea E. The density of high-angle (>10°) boundaries in E is roughly double that in C, reflecting the greater degree of recrystallisation. Low-angle boundaries in C and E are produced by subgrain rotation. In the low-angle range 0–10° boundary densities in both C and E show an exponential decrease with increasing misorientation. The densities scale with exp(−θ/λ) where λ is approximately 2° in C and 1° in E; in other words, E has a comparative dearth of boundaries in the 8–10° range. We explain this dearth in terms of mobile high-angle boundaries sweeping through and consuming low-angle boundaries as the latter increase misorientation through time. In E, the density of high-angle boundaries is larger than in C, so this sweeping would have been more efficient and could explain the relative paucity of 8–10° boundaries.The boundary density can be generalised to a directional property that gives the degree of anisotropy of the boundary network and its preferred orientation. Despite the imposed strain, the analysed samples show that boundaries are not, on average, strongly aligned. This is a function of the strong sinuosity of high-angle boundaries, caused by grain boundary migration. Low-angle boundaries might be expected, on average, to be aligned in relation to imposed strain but this is not found.Boundary densities and their generalisation in terms of directional properties provide objective measures of microstructure. In this study the patterns they show are interpreted in terms of combined subgrain rotation and migration recrystallisation, but it may be that other microstructural processes give distinctive patterns when analysed in this fashion.     

A statistical approach to evaluating distance metrics and analog assignments for pollen records

The modern analog technique typically uses a distance metric to determine the dissimilarity between fossil and modern biological assemblages. Despite this quantitative approach, interpretation of distance metrics is usually qualitative and rules for selection of analogs tend to be ad hoc. We present a statistical tool, the receiver operating characteristic (ROC) curve, which provides a framework for identifying analogs from distance metrics. If modern assemblages are placed into groups (e.g., biomes), this method can (1) evaluate the ability of different distance metrics to distinguish among groups, (2) objectively identify thresholds of the distance metric for determining analogs, and (3) compute a likelihood ratio and a Bayesian probability that a modern group is an analog for an unknown (fossil) assemblage. Applied to a set of 1689 modern pollen assemblages from eastern North America classified into eight biomes, ROC analysis confirmed that the squared-chord distance (SCD) outperforms most other distance metrics. The optimal threshold increased when more dissimilar biomes were compared. The probability of an analog vs no-analog result (a likelihood ratio) increased sharply when SCD decreased below the optimal threshold, indicating a nonlinear relationship between SCD and the probability of analog. Probabilities of analog computed for a postglacial pollen record at Tannersville Bog (Pennsylvania, USA) identified transitions between biomes and periods of no analog.     

Anthropogenic contributions to atmospheric Hg, Pb and As accumulation recorded by peat cores from southern Greenland and Denmark dated using the C “bomb pulse curve”

Mercury concentrations are clearly elevated in the surface and sub-surface layers of peat cores collected from a minerotrophic (“groundwater-fed”) fen in southern Greenland (GL) and an ombrotrophic (“rainwater-fed”) bog in Denmark (DK). Using ¹⁴C to precisely date samples since ca. AD 1950 using the “atmospheric bomb pulse,” the chronology of Hg accumulation in GL is remarkably similar to the bog in DK where Hg was supplied only by atmospheric deposition: this suggests not only that Hg has been supplied to the surface layers of the minerotrophic core (GL) primarily by atmospheric inputs, but also that the peat cores have preserved a consistent record of the changing rates of atmospheric Hg accumulation. The lowest Hg fluxes in the GL core (0.3 to 0.5 μg/m²/yr) were found in peats dating from AD 550 to AD 975, compared to the maximum of 164 μg/m²/yr in AD 1953. Atmospheric Hg accumulation rates have since declined, with the value for 1995 (14 μg/m²/yr) comparable to the value for 1995 obtained by published studies of atmospheric transport modelling (12 μg/m²/yr).The greatest rates of atmospheric Hg accumulation in the DK core are also found in the sample dating from AD 1953 and are comparable in magnitude (184 μg/m²/yr) to the GL core; again, the fluxes have since gone into strong decline. The accumulation rates recorded by the peat core for AD 1994 (14 μg/m²/yr) are also comparable to the value for 1995 obtained by atmospheric transport modelling (18 μg/m²/yr). Comparing the Pb/Ti and As/Ti ratios of the DK samples with the corresponding crustal ratios (or “natural background values” for preanthropogenic peat) shows that the samples dating from 1953 also contain the maximum concentration of “excess” Pb and As. The synchroneity of the enrichments of all three elements (Hg, Pb, and As) suggests a common source, with coal-burning the most likely candidate. Independent support for this interpretation was obtained from the Pb isotope data (²⁰⁶Pb/²⁰⁷Pb = 1.1481 ± 0.0002 in the leached fraction and 1.1505 ± 0.0002 in the residual fraction) which is too radiogenic to be explained in terms of gasoline lead alone, but compares well with values for U.K. coals. In contrast, the lowest values for ²⁰⁶Pb/²⁰⁷Pb in the DK profile (1.1370 ± 0.0003 in the leached fraction and 1.1408 ± 0.0003 in the residual fraction) are found in the sample dating from AD 1979: this shows that the maximum contribution of leaded gasoline occurred approximately 25 yr after the zenith in total anthropogenic Pb deposition.     

Determination of food web support and trophic position of the mummichog,Fundulus heteroclitus, in New Jersey smooth cordgrass (Spartina alterniflora), common reed (Phragmites australis), and restored salt marshes

The invasion ofPhragmites australis into tidal marshes formerly dominated bySpartina alterniflora has resulted in considerable interest in the consequences of this invasion for the ecological functions of marsh habitat. We examined the provision of trophic support for a resident marsh fish,Fundulus heteroclitus, in marshes dominated byP. australis, byS. alterniflora, and in restored marshes, using multiple stable isotope analysis. We first evaluated our ability to distinguish among potential primary producers using the multiple stable isotope approach. Within a tidal creek system we found significant marsh and elevation effects on microalgal isotope values, and sufficient variability and overlap in primary producer isotope values to create some difficulty in identifying unique end members. The food webs supportingF. heteroclitus production were examined using dual isotope plots. At both sites, the δ¹³C values ofF. heteroclitus were clustered over values for benthic microalgae (BMI) and approximately midway between δ¹³C values ofSpartina andPhragmites. Based on comparisons of fish and primary producer δ¹³C, δ¹⁵N, and δ³⁴S values, and consideration ofF. heteroclitus feeding habits, we conclude that BMI were a significant component of the food web supportingF. heteroclitus in these brackish marshes, especially recently-hatched fish occupying pools on the marsh surface. A 2‰ difference in δ¹³C betweenFundulus occupying nearly adjacentSpartina andPhragmites marshes may be indicative of relatively less reliance on BMI and greater reliance onPhragmites production inPhragmites-dominated marshes, a conclusion consistent with the reduced BMI biomass found inPhragmites marshes. The mean δ¹³C value ofF. heteroclitus from restored marshes was intermediate between values of fish from naturally occurringSpartina marshes and areas invaded byPhragmites. We also examined the isotopic evidence for ontogenetic changes in the trophic position of larval and juvenileF. heteroclitus. We found significant positive relationships betweenF. heteroclitus δ¹⁵N values and total length, reflective of an increase in trophic position as fish grow.F. heteroclitus δ¹⁵N values indicate that these fish are feeding approximately two trophic levels above primary producers.