Effects of Airflow Induced by Rainfall on Shallow Groundwater Table Fluctuations

An investigation of groundwater table fluctuations induced by rainfall should consider interactions between the liquid and gas phases in soils. In this study, a water‐air two‐phase flow model was initially verified by simulating an infiltration experiment. It was then employed to model the interactions between liquid and gas phases regarding actions of airflow on the groundwater table and the fluctuations of the phreatic level and water level in the well induced by rainfall. The effects of airflo7w caused by rainfall on phreatic level fluctuations were also studied quantitatively by comparing the results obtained using the proposed model with those obtained from a water single‐phase flow model. The simulation results show that in addition to actual recharge, compressed airflow in unsaturated zones causes the phreatic level to increase, but the rise in the phreatic level is lower than that in the pore‐air pressure head in unsaturated zones due to the mitigation of capillary fringe. The existence of airflow enhances the phreatic level rise during and after rainfall. In addition, the water level in the well, pushed by the phreatic level fluctuations, varies similarly to the phreatic level, but it experiences somewhat delayed and slightly attenuated. The Lisse effect precisely reflects the phreatic level fluctuations before actual recharge. Furthermore, the fluctuations in the phreatic level and water level in the well and the contributions of airflow to phreatic level fluctuations are affected by many factors: rain intensity, initial moisture, overlying aquitard, groundwater table depths, and screen depths of the well.     

乳山湾外邻近海域氮和磷的分布与收支过程研究

基于2009年6–9月,2014年5月,2014年7–8月在乳山湾外邻近海域的综合调查资料,分析了该开放海域水体与沉积物中氮、磷营养盐的组成和分布,并在潮汐潮流数值模式计算水通量的基础上分析了近岸开放区域无机氮(DIN)和无机磷(DIP)的循环与收支的主要过程,量化了潮汐潮流、初级生产的消耗与转化、底界面过程与内部循环等过程对氮和磷营养盐循环与收支的影响。结果表明,夏季乳山湾外邻近海域水体DIN和DIP的浓度与分布受陆源输入和潮汐潮流的共同影响,高值均出现在湾口区域;沉积物-水界面存在DIN和DIP从沉积物向上覆水释放的现象,使得底层水体的氮、磷营养盐浓度高于表层水体。氮的收支表明,研究海域水体内部循环过程是初级生产所需DIN的主要来源,占初级生产总消耗量的86%,其次是水交换作用(11%),底界面扩散对初级生产的贡献相对较小(3%);水体DIN的移出主要是通过埋藏、向外海的输送和水体反硝化作用,其比例分别为80%、16%和4%。磷的收支显示,研究海域水体内部循环过程贡献了初级生产所需DIP的91%,其次是水交换作用(9%),底界面扩散对初级生产的贡献小于1%;水体DIP支出主要是通过沉积埋藏和向外海的输送,其比例分别为67%和33%。研究结果表明内部循环过程是近海水体氮和磷获得补充的主要途径,不过外部来源的氮、磷营养盐结构与系统内部具有显著的差异,且系统内磷的埋藏效率要高于氮,其必将对乳山湾外邻近海域营养盐结构和初级生产产生长远的影响。     

Numerical simulation of non-linear regular and focused waves in an infinite water-depth

Inviscid three-dimensional free surface wave motions are simulated using a novel quadratic higher order boundary element model (HOBEM) based on potential theory for irrotational, incompressible fluid flow in an infinite water-depth. The free surface boundary conditions are fully non-linear. Based on the use of images, a channel Green function is developed and applied to the present model so that two lateral surfaces of an infinite-depth wave tank can be excluded from the calculation domain. In order to generate incident waves and dissipate outgoing waves, a non-reflective wave generator, composed of a series of vertically aligned point sources in the computational domain, is used in conjunction with upstream and downstream damping layers. Numerical experiments are carried out, with linear and fully non-linear, regular and focused waves. It can be seen from the results that the present approach is effective in generating a specified wave profile in an infinite water-depth without reflection at the open boundaries, and fully non-linear numerical simulations compare well with theoretical solutions. The present numerical technique is aimed at efficient modelling of the non-linear wave interactions with ocean structures in deep water.     

基于环境DNA技术的黄河流域下游山区河流大型底栖动物群落多样性特征及其影响要素分析

河流生物群落组成由多种环境因子共同作用形成,但其影响机制尚不清楚。本研究基于环境DNA技术,选择黄河流域下游4条山区河流(锦绣川、锦阳川、锦云川和三川汇合后河流)的10个样点开展大型底栖动物监测。结果发现:不同溪段水质状况有所差异,锦云川盐化程度(以电导率EC表征)和营养盐浓度较高,锦阳川抗生素浓度较高,锦绣川水质较好。山区河流大型底栖动物群落组成差异明显,锦绣川以水生昆虫为主,软体动物占比较低。其中,昆虫纲的大蚊(Tipula abdominalis)、天角蜉(Uracanthella punctisetae)和寡毛纲的顠体虫(Aeolosoma sp.)是造成锦绣川与其他河流大型底栖动物群落结构差异的关键物种。冗余分析和变差分解分析结果表明,盐化、营养盐和抗生素均会对大型底栖动物群落组成产生影响。其中,EC的解释率为22.86%,营养盐中的TP、NH₃-N和TN的解释率分别为20.12%、13.25%和7.81%;此外,盐化可与营养盐和抗生素通过耦合效应对大型底栖动物群落组成产生影响,贡献率分别为21.60%和16.20%;抗生素与营养盐的贡献率为19.60%。逐步判别回归模型结果显示,Margalef指数(d)受盐化(EC)和营养盐(NH₃-N和NO₃^--N)的共同影响;随着河流中EC浓度升高,d 与NH₃-N之间的正响应关系及其与NO₃^--N之间的负响应关系显著增强。因此,多环境因子对水生生物的影响不容忽视,在大型底栖动物生物多样性保护中应关注各类环境因子的影响贡献。     

重金属污染土壤修复的Pb2+钝化产物稳定性

自然状态下土壤中重金属元素是否稳定存在是重金属污染固化修复技术中的核心问题。本文以常见重金属离子Pb²⁺为例,分析土壤中重金属离子与常见离子基团结合的稳定性。将第一性原理应用于Pb的存在形态和稳定性的分析,计算了PbCO₃、PbSO₄、PbCl₂、Pb₃（PO₄）₂、PbAl₂O₄和Pb₃Fe₂（PO₄）₄的自由能、能带和态密度。首先推断Pb²⁺和CO₃^2-、SO₄^2-、Cl^-、PO₄^3-等土壤中常见阴离子的结合稳定性,再判断加入金属阳离子Al³⁺和Fe³⁺对体系稳定性的影响。结果表明：铅化合物自由能从高到低趋势为PbCl₂、PbAl₂O₄、PbCO₃、PbSO₄、Pb₃（PO₄）₂、Pb₃Fe₂（PO₄）₄,其相应的结构稳定性顺序从大到小为Pb₃Fe₂（PO₄）₄、Pb₃（PO₄）₂、PbSO₄、PbCO₃、PbAl₂O₄、PbCl₂。通过对能带和态密度的分析,首先确定了SO₄^2-和PO₄^3-的引入能够增强含Pb体系的稳定性,进一步加入金属阳离子Fe³⁺会使体系更稳定。推测SO₄^2-、PO₄^3-为治理Pb²⁺污染合适的官能团,应选择容易释放SO₄^2-、PO₄^3-的物质作为合适的钝化剂。在实际应用中可选择磷酸二氢钠、无水硫酸钠、脱硫石膏等作为钝化剂。     

A numerical model for onset of scour below offshore pipelines

A numerical model is developed to predict the onset of local scour below offshore pipelines in steady currents and waves. The scour is assumed to start when the pressure gradient underneath the pipeline exceeds the floatation gradient of the sediments. In this model, the water flow field above the bed is determined by solving the two-dimensional (2-D) Reynolds-averaged Navier–Stokes equations with a k-ω turbulence closure. The seepage flow below the seabed is calculated by solving the Darcy's law (Laplace's equation) with known pressure distribution along the common boundaries of the flow domains-seabed. The numerical method used for both the turbulent flow around the pipeline and Darcy's flow in the seabed is a fractional finite element method. The average pressure gradient along the buried pipe surface is employed in the evaluation of onset condition with a calibration coefficient. The numerical model is validated against experimental data available in literature. A unified onset condition for steady currents and waves is proposed. Influences of flow parameters, including water depth, embedment depth, boundary layer thickness, Reynolds number (Re) and Keuleagan–Carpenter (KC) number, on the pressure drop coefficient over the pipeline are studied systematically.     

Characteristics of permafrost degradation in Northeast China and its ecological effects: A review

Latitudinal permafrost in Northern Northeast(NNE)China is located in the southern margin of the Eurasian continent,and is very sensitive to climatic and environmental change.Numerical simulations indicate that air temperature in the permafrost regions of Northeast China has been on the rise since the 1950s,and will keep rising in the 21st century,leading to extensive degradation of permafrost.Permafrost degradation in NNE China has its own characteristics,such as northward shifts in the shape of a"W"for the permafrost southern boundary(SLP),discontinuous permafrost degradation into islandlike frozen soil,and gradually disappearing island permafrost.Permafrost degradation leads to deterioration of the ecological environment in cold regions.As a result,the belt of larch forests dominated by Larix gmelinii has shifted northwards and wetland areas with symbiotic relationships with permafrost have decreased significantly.With rapid retreat and thinning of permafrost and vegetation change,the CO2 and CH4 flux increases with mean air temperature from continuous to sporadic permafrost areas as a result of activity of methanogen enhancement,positively feeding back to climate warming.This paper reviews the features of permafrost degradation,the effects of permafrost degradation on wetland and forest ecosystem structure and function,and greenhouse gas emissions on latitudinal permafrost in NNE China.We also put forward critical questions about the aforementioned effects,including:(1)establish long-term permafrost observation systems to evaluate the distribution of permafrost and SLP change,in order to study the feedback of permafrost to climate change;(2)carry out research about the effects of permafrost degradation on the wetland ecosystem and the response of Xing'an larch to global change,and predict ecosystem dynamics in permafrost degradation based on long-term field observation;(3)focus intensively on the dynamics of greenhouse gas flux in permafrost degradation of Northeast China and the feedback of greenhouse gas emissions to climate change;(4)quantitative studies on the permafrost carbon feedback and vegetation carbon feedback due to permafrost change to climate multi-impact and estimate the balance of C in permafrost regions in the future.     

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东海海水中的溶存甲烷

基于1994年秋季航次在东海的调查资料,较详细地分析了溶存甲烷在水体中的分布规律、成因和来源.表层水中溶存甲烷呈过饱和状态,饱和度127%～254%,温跃层以上水体中,甲烷的断面分布不同于营养盐的分布,各站测值相近,没有显示出受长江冲淡水的影响,而呈现的舌状分布,在陆架底层水中有明显的高浓度甲烷水体,表明甲烷从沉积物中迅速扩散进入底层水.黑潮次表层水的涌升过程稀释了陆架边缘底层水中的甲烷.在陆架和大洋区测站上,甲烷的垂直分布不同,前者主要受物理混合过程所控制;后者呈大洋区分布特征,在温跃层附近出现甲烷的次表层最大,这可能是陆架底层高浓度甲烷沿等密度面的输送所致.     

Geochemistry and geological significance of the Upper Paleozoic and Mesozoic source rocks in the Lower Yangtze region

The Lower Yangtze region is one of the important marine sedimentation areas of oil and gas distribution in southern China,for its favorable source rocks,reservoirs and covers.However,the intense tectonic movements and complex hydrocarbon generation process made it highly impossible to form large-sized oil and gas reservoirs.So it was divided to different hydrocarbon-bearing preservation units in oil-gas exploration.Recent study shows that the Permian and Lower Triassic source rocks in the Lower Yangtze region are complicated in lithology.The hydrocarbon generation potential of limestone there is low while argillaceous source rocks are overall of high abundance with excellent organic types,now in the process of hydrocarbon generation,so differences in high maturity influence the evaluation of organic matter abundance and type.Biomarker characteristics indicate a reductive environment.n-alkanes are marked by a single peak,with no odd-even predominance.The composition and distribution of the carbon numbers of n-alkanes,and the high abundance of long-chain tricyclic terpanes are indicative of marine sedi-mentation.The high contents of pregnane,homopregnane,rearranged hopane suggest that the source rocks are of high maturity.There is a good linear correlation between methylphenanthrene index and vitrinite reflectance.The correlation of oil-source rocks indicated that the oil of Well HT-3 may come from the Permian Longtan Formation in the Huangqiao area,the oil of Wells Rong-2 and Juping-1 came from the Lower Triassic Qinglong Formation in the Jurong area.The exploration here is promising in those different source rocks which all have great potential in hy-drocarbon generating,and oil and gas were produced in the late stage of hydrocarbon generation.