Vertical distribution and source identification of polycyclic aromatic hydrocarbons in anoxic sediment cores of Chini Lake, Malaysia: Perylene as indicator of land plant-derived hydrocarbons

Four anoxic sediment cores were collected from Chini Lake, Malaysia in order to investigate the variability of polycyclic aromatic hydrocarbon (PAH) and perylene concentrations. The study also determined significant differences of perylene concentrations in different sediment layers. Total PAH concentrations ranged from 248 to 8098 ng g⁻¹ in the samples. Diagnostic PAH ratios such as methylphenanthrenes/phenanthrene (MP/P), phenanthrene/anthracene (P/A) and fluoranthene/(fluoranthene + pyrene) (Fl/(Fl + Py) revealed a dominance of pyrogenic influences and partial petrogenic inputs to the top sediment layers. Perylene concentrations were high in the top layers (<12 cm) and increased with increasing depth. There is a significant positive correlation (r = 0.705, p = 0.01) between perylene concentrations and TOC. Analysis of variance (ANOVA) and LSD revealed significant differences (p < 0.05) in TOC-normalized perylene concentrations between the upper (<12 cm) and bottom layers (>12 cm). The average perylene concentrations accounted for 26–50% (0–12 cm) and 50–77% (12–36 cm) of pentacyclic-aromatic hydrocarbon isomers (PAI) present whereas it made up 10–34% (0–12 cm) and 46–66% (12–36 cm) of the total PAH. The average pyrene concentrations decreased with increasing depth and accounted for 62% (0–3 cm), 20–23% (3–12 cm) and 3–1.4% (12–36 cm) of perylene present. The results of hierarchical cluster analysis based on these ratios suggested different input sources for the top and bottom layers. It is concluded that the activity of termites on woody plants produced perylene which is supplied to the lake by run-off from the heavy and frequent rains in this Asian tropical climate. In addition, there was also in situ formation of perylene in the bottom layers due to diagenetic processes.     

Linear genetic programming for prediction of circular pile scour

Genetic programming (GP) has nowadays attracted the attention of researchers in the prediction of hydraulic data. This study presents linear genetic programming (LGP), which is an extension to GP, as an alternative tool in the prediction of scour depth around a circular pile due to waves in medium dense silt and sand bed. Field measurements were used to develop LGP models. The proposed LGP models were compared with adaptive neuro-fuzzy inference system (ANFIS) model results. The predictions of LGP models were observed to be in good agreement with measured data, and quite better than ANFIS and regression-based equation of scour depth at circular piles. The results were tabulated in terms of statistical error measures and illustrated via scatter plots.     

Sedimentology, stratigraphic occurrence and origin of linked debrites in the West Crocker Formation (Oligo-Miocene), Sabah, NW Borneo

The West Crocker Formation (Oligocene–Early Miocene), NW Borneo, consists of a large (>20 000 km²) submarine fan deposited as part of an accretionary complex. A range of gravity-flow deposits are observed, the most significant of which are mud-poor, massive sandstones interpreted as turbidites and clast-rich, muddy sandstones and sandy mudstones interpreted as debrites. An upward transition from turbidite to debrite is commonly observed, with the contact being either gradational and planar, or sharp and highly erosive. Based on their repeated vertical relationship and the nature of the contact between them, these intervals are interpreted as being deposited from one flow event which consisted of two distinct flow phases: fully turbulent turbidity current and weakly turbulent to laminar debris flow. The associated bed is called a co-genetic turbidite–debrite, with the upper debrite interval termed a linked debrite. Linked debrites are best developed in the non-channellised parts of the fan system, and are absent to poorly-developed in the proximal channel-levee and distal basin floor environments. Due to outcrop limitations, the genesis of linked debrites within the West Crocker Formation is unclear. Based on clast size and type, it seems likely that a weakly turbulent to laminar debris-flow flow phase was present when the flow event entered the basin. A change in flow behaviour may have led to deposition of a sand-rich unit with ‘turbidite’ characteristics, which was subsequently overlain by a mud-rich unit with ‘debrite’ characteristics. Flow transformation may have been enhanced by the disintegration and incorporation into the flow of muddy clasts derived from the upstream channel floor, channel mouth or from channel-levee collapse. Lack of preservation of this debrite in proximal areas may indicate either bypass of this flow phase or that the available outcrops fail to capture the debris flow entry point. Establishing robust sedimentological criteria from a variety of datasets may lead to the increasing recognition of co-genetic turbidite-debrite beds, and an increased appreciation of the importance of bipartite flows in the transport and deposition of sediments in deepwater environments.     

Polycyclic aromatic hydrocarbon (PAHs) and hopanes in stranded tar-balls on the coasts of Peninsular Malaysia: applications of biomarkers for identifying sources of oil pollution

Malaysian coasts are subjected to various threats of petroleum pollution including routine and accidental oil spill from tankers, spillage of crude oils from inland and offshore oil fields, and run-off from land-based human activities. Due to its strategic location, the Straits of Malacca serves as a major shipping lane. This paper expands the utility of biomarker compounds, hopanes, in identifying the source of tar-balls stranded on Malaysian coasts. 20 tar-ball samples collected from the east and west coast were analyzed for hopanes and polycyclic aromatic hydrocarbons (PAHs). Four of the 13 tar-ball samples collected from the west coast of Peninsular Malaysia were identified as the Middle East crude oil (MECO) based on their biomarker signatures, suggesting tanker-derived sources significantly contributing the petroleum pollution in the Straits of Malacca. The tar-balls found on the east coast seem to originate from the offshore oil platforms in the South China Sea. The presence of South East Asian crude oil (SEACO) tar-balls on the west coast carry several plausible explanations. Some of the tar-balls could have been transported via sea currents from the east coast. The tankers carrying SEACO to other countries could have accidentally spilt the oil as well. Furthermore, discharge of tank washings and ballast water from the tankers were suggested based on the abundance in higher molecular weight n-alkanes and the absence of unresolved complex mixture (UCM) in the tar-ball samples. The other possibilities are that the tar-balls may have been originated from the Sumatran oil fields and spillage of domestic oil from oil refineries in Port Dickson and Malacca. The results of PAHs analysis suggest that all the tar-ball samples have undergone various extent of weathering through evaporation, dissolution and photo-oxidation.     

Response of flower and boll development to climatic factors in Egyptian cotton (Gossypium barbadense)

Fruiting of cotton plant is determined and influenced by cultivars, climatic conditions, management practices and pests. An understanding of the flowering and boll retention patterns of cotton cultivars can contribute to more efficient and economical crop management. The objective of this investigation was to study the effect of various climatic factors on flower and boll production, and also, the nature of its effects prevailing prior and subsequent to either flowering or boll setting on flower and boll production and retention in Egyptian cotton. This could be used in formulating advanced prediction of the effect of certain climatic conditions on the production of Egyptian cotton. Also, the study focused on four equal periods during the development of flower and bolls stage to study the response of these characters to climatic factors during these periods and to determine the most representative period corresponding to the overall crop pattern. Further, the study predicting effects of climatic factors during convenient intervals (in days) on cotton flower and boll production compared with daily observations to find the optimum interval. Evaporation, sunshine duration, humidity, surface soil temperature at 1800 h, and maximum air temperature, are the important climatic factors that significantly affects flower and boll production. Evaporation; minimum humidity and sunshine duration were the most effective climatic factors during preceding and succeeding periods on boll production and retention. There was a negative correlation between flower and boll production and either evaporation or sunshine duration, while that correlation with minimum humidity was positive. The fourth quarter period of the production stage was the most appropriate and usable time to collect data for determining efficient prediction equations for cotton production. Evaporation, humidity and temperature were the principal climatic factors that governed cotton flower and boll production during the fourth quarter. The five day interval was found to be adequately and sensibly related to yield parameters than other intervals and was closest to the daily observations. Evaporation was found to be the most important climatic variable affecting flower and boll production, followed by humidity. An accurate weather forecast 5–7 days in advance would provide an opportunity to avoid adverse effects of climatic factors on cotton production through utilizing proper cultural practices which would limit and control their negative effects.