Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

元谋干热河谷坡耕地土壤侵蚀造成的土地退化

在元谋干热河谷土壤侵蚀特征分析的基础上，对坡耕地土壤侵蚀造成的土地退化进行了模拟研究。结果表明，土壤侵蚀造成表层耕作土壤的物理性能下降、养分流失和水分入渗能力降低。表层耕作土壤的容重比下层土壤低12．7％，总孔隙度高10．9％，有机质高37．3％，120min累计入渗总量是下层土壤的1．6-2．2倍。模拟土壤侵蚀与土地生产力关系的小区试验结果显示，坡耕地每流失1cm表土，土地生产力水平平均下降4．54％。     

海岸线空间分形性质探讨——以江苏省为例

根据分形理论 ,借助于GIS技术的支持 ,以江苏省海岸线为例 ,对以往研究少有涉及的海岸线空间分形性质进行了初步探讨 ,包括不同比例尺下海岸线长度的分形标定、不同潮滩分界线是否具有分形性质等 ,在江苏省海岸线长度的分形标定中取得了实际应用 ,由此获得了对海岸线分形性质及其分维意义的一些深入认识。     

氯化锂电解条件对氯离子迁移的影响

电解氯化锂溶液制备氢氧化锂的过程中,水分子伴随阳离子通过离子膜发生移动,从而使阳极液中的氯离子迁移到阴极液中,增加了阴极液中Cl-的含量,影响氢氧化锂产品纯度。采用自制的电解槽装置,用DF988膜进行了较为系统的实验研究,在阳极液初始浓度、阴极液初始浓度、电流密度、循环流量和温度等不同条件下,测定了阴极液中氯离子的含量。结果表明,电流密度和温度对氯离子迁移有明显的影响。随着电流密度的增加,氯离子迁移的速率明显降低;反应温度越高,电解中氯离子的迁移速率越大;阴、阳极液初始浓度对氯离子迁移影响明显;循环流量对氯离子迁移的影响较小。     

基于哨兵数据的云南地表形变监测

云南省作为我国西南地区与西藏相连的省份,其地势由西北向东南逐渐降低且山峦众多,山区面积占全省面积的88％.除此之外,云南省还位于印度洋板块和亚欧板块交界处附近,其地震带众多,地质运动频繁,经常出现地震、滑坡、泥石流等地质灾害.因此,本文选取覆盖地势较高的云南西北部地区的哨兵数据,利用SBAS-InSAR技术进行数据处理...     

解耦的海洋性层积云顶边界层湍流与云微物理特征

基于POST观测计划中获得的海洋性层积云顶边界层内高频气象资料和云微物理资料,在选取解耦个例基础上研究解耦边界层湍流和云微物理特征及成因。结果表明,过渡层的大气静力稳定度较强,抑制向上浮力做功,使得湍流动能迅速消耗殆尽,实现边界层解耦。湍流动能最大值出现在云内,主要与云顶降温、大云滴下落沉降拖曳带来的下沉气流增强及云底之上附近凝结增长潜热释放产生向上浮力作用有关。近地面层的浮力项和切变项对湍流动能都起到增强作用,并以切变项的贡献更为显著,云内的湍流动能是以浮力项贡献为主。过渡层附近存在向下的热通量,抑制了热量向上输送和向上浮力项的增强,促进解耦发生。云内存在向上感热通量,其最大值及其出现高度主要与云顶冷却和云中下部的凝结潜热加热有关。云顶之上湿层促进了潜热通量的向下输送,增强了云内水汽含量,为解耦边界层云的发展起到正反馈作用。云顶浮力倒转引起的云中湍流混合呈现非均匀性,并进一步导致绝热或超绝热液滴出现,促进凝结和碰并增长的增强,同时云顶之上湿层进一步对云中的微物理增长起到了重要的推动作用。云底因夹卷混合表现为均匀混合特征。     

Evaluation of Precipitation Datasets from TRMM Satellite and Downscaled Reanalysis Products with Bias-correction in Middle Qilian Mountain,China

Accurate estimates of precipitation are fundamental for hydrometeorological and ecohydrological studies, but are more difficult in high mountainous areas because of the high elevation and complex terrain. This study compares and evaluates two kinds of precipitation datasets, the reanalysis product downscaled by the Weather Research and Forecasting(WRF) output, and the satellite product,the Tropical Rainfall Measuring Mission(TRMM) Multisatellite Precipitation Analysis(TMPA) product, as well as t...     

Machine Learning-based Weather Support for the 2022 Winter Olympics

<正>1.A key support for the 2022 Winter Olympics The XXIV Olympic Winter Games are scheduled to take place from 4 to 22 February 2022, followed by the Paralympic Games from 4 to 13 March, in Beijing and towns in the neighboring Hebei Province, China. Weather plays an extremely important role in the outcome of the games (Chen et al., 2018). It can not only cause a difference between a medal or not, but affect the safety of athletes. Success of the Winter Olympics will greatly depend on weath...     

川东北一次西北气流型强冰雹天气的成因分析

利用常规气象资料和NCEP／NCAR 1°×1° 6h再分析资料,从大气环流形势、物理量场等方面对2007年4月29日发生在川东北地区的一次强冰雹天气过程的成因进行了分析。结果表明：此次西北气流型冰雹天气是在低能量环境场条件下发生的;冰雹天气发生前12h内降雹区的对流有效位能激增、午后下垫面强烈加热对大气不稳定性增强的作用显著;大气层结对流不稳定、湿对称不稳定、充足的水汽以及干线（露点锋）的存在为此过程提供了有利条件。     

南海东部俯冲洋脊区段地震静态库伦应力分析

根据对马尼拉海沟及其邻区地震分布和震源机制解所反映的最大主压应力轴分布特征的分析,并结合古洋脊俯冲区段地震产生的静态库伦应力分析,发现在马尼拉海沟区域地震分布具有明显的分带特性,北部以NW向挤压应力为主,俯冲洋脊区段以近EW向的挤压应力为主;1999年7.2级地震使得2000年6.2级地震和2011年6.0级地震震中位置的静态库伦应力分别增加了约0.5和0.3 bar;2011年6.0级正断型地震和5.0级余震的静态库伦应力变化能较好地反映与余震分布的对应关系,大部分余震位于库伦应力变化值大于0.1 bar的触发阈值区域;计算古洋脊俯冲区段强震产生的静态库伦应力变化,结果显示海沟西侧小于10 km的深度范围内库伦应力增加值达到0.3~0.5 bar,呈NE向展布,吕宋岛弧一侧20 km深度范围内均表现为应力增加,应力增加区域与地震的分布较为吻合。