Tracing nitrogen in volcanic and geothermal volatiles from the Nicaraguan volcanic front

We report new chemical and isotopic data from 26 volcanic and geothermal gases, vapor condensates, and thermal water samples, collected along the Nicaraguan volcanic front. The samples were analyzed for chemical abundances and stable isotope compositions, with a focus on nitrogen abundances and isotope ratios. These data are used to evaluate samples for volatile contributions from magma, air, air-saturated water, and the crust. Samples devoid of crustal contamination (based upon He isotope composition) but slightly contaminated by air or air-saturated water are corrected using N₂/Ar ratios in order to obtain primary magmatic values, composed of contributions from upper mantle and subducted hemipelagic sediment on the down-going plate. Using a mantle endmember with δ¹⁵N = −5‰ and N₂/He = 100 and a subducted sediment component with δ¹⁵N = +7‰ and N₂/He = 10,500, the average sediment contribution to Nicaraguan volcanic and geothermal gases was determined to be 71%. Most of the gases were dominated by sediment-derived nitrogen, but gas from Volcán Mombacho, the southernmost sampling location, had a mantle signature (46% from subducted sediment, or 54% from the mantle) and an affinity with mantle-dominated gases discharging from Costa Rica localities to the south. High CO₂/N_{2 exc.} ratios (N_{2 exc.} is the N₂ abundance corrected for contributions from air) in the south are similar to those in Costa Rica, and reflect the predominant mantle wedge input, whereas low ratios in the north indicate contribution by altered oceanic crust and/or preferential release of nitrogen over carbon from the subducting slab. Sediment-derived nitrogen fluxes at the Nicaraguan volcanic front, estimated by three methods, are 7.8 × 10⁸ mol N/a from ³He flux, 6.9 × 10⁸ mol/a from SO₂ flux, and 2.1 × 10⁸ and 1.3 × 10⁹ mol/a from CO₂ fluxes calculated from ³He and SO₂, respectively. These flux results are higher than previous estimates for Central America, reflecting the high sediment-derived volatile contribution and the high nitrogen content of geothermal and volcanic gases in Nicaragua. The fluxes are also similar to but higher than estimated hemipelagic nitrogen inputs at the trench, suggesting addition of N from altered oceanic basement is needed to satisfy these flux estimates. The similarity of the calculated input of N via the trench to our calculated outputs suggests that little or none of the subducted nitrogen is being recycled into the deeper mantle, and that it is, instead, returned to the surface via arc volcanism.     

Interactive effects of the type of milling media and CuSO4 addition on the flotation performance of sulphide minerals from Merensky ore Part II: Froth stability

The limitations of pulp chemistry measurements in the flotation of a platinum group mineral (PGM) bearing Merensky ore were demonstrated in Part 1 of this article. In this paper the importance of the contribution of the froth structure due to changing froth stability is analysed using the batch flotation data. The effects of mild steel (MS) and stainless steel (SS) milling media and the addition of copper sulphate on the flotation performance of the sulphide minerals in Merensky ore have been evaluated in relation to the changes in stability of the froth phase. The effects of pulp chemistry and froth stability on the flotation of sulphide minerals were distinguished by using two different rate constants (k_t and k_w). The rate constant (k_w) calculated as a function of cumulative water recovery was used to describe characteristics of froth phase and k_t was calculated as a function of flotation time. The results revealed that the type of grinding media and copper sulphate addition had an interactive effect on the froth stability. While mild steel (MS) milling increased the froth stability due to the presence of hydrophilic iron hydroxides and colloidal metallic iron, the addition of copper sulphate reduced the stability, especially with stainless steel (SS) milling. Copper sulphate addition had a dual role in the flotation of Merensky ore in that it caused destabilisation of the froth zone as well as activation of selected sulphide minerals. The dominant effect was found to depend on the type of milling media and floatability of the mineral in question and this work has demonstrated the importance of using a combination of measurements to evaluate flotation performance holistically.     

The seismic hazard assessment of the Dead Sea rift, Jordan

The Dead Sea fault system and its branching faults represent one of the most tectonically active regions in the Middle East. The aim of this study is to highlight the degree of hazards related to the earthquake activities associated with the Dead Sea rift, in terms of speculating the possible future earthquakes. The present investigation mainly is based on available data and vertical crustal modeling of Jordan and the Dead Sea model for the Dead Sea basin with particular emphasis of the recent earthquake activities, which occurred on December 31st, 2003 (Mc = 3.7), February 11th, 2004 (strongest Mc = 4.9 R), and March 15th, 2004 (Mc = 4). The present research examines the location of the strong events and correlates them with the various tectonic elements in the area. The source mechanism of the main shock and the aftershock events is also examined. The analyses were based on the available short period seismogram data, which was recorded at the Natural Resources Authority of Jordan, Seismological Observatory. The seismic energy appears to have migrated from the south to the north during the period from December 31st up to March 12th, where the released seismic energy showed a migration character to the southern block of the eastern side of the Dead Sea, which led the seismic event to occur on March 15th.     

北京地区湿地高等植物区系分析

根据工作需要,在北京4个水系的主要河流的平原地段和山区的上、中游地段,选取不同生境的典型样地,以及城区的人工湖泊共设立了35个采集点,采用样方法和样带法相结合,共调查样方355个,采集样本4 152个。在该调查资料的基础上,运用区系学原理对北京地区湿地高等植物区系的种类组成、地理成分(科、属、种3个层次)等进行了系统的分析。结果表明,北京地区湿地高等植物共有108科311属552种(含山区湿地),占北京植物总数的近1/3。其中苔藓植物(B ryohyto)有9科15属18种;蕨类植物(Pteridophgta)5科5属8种;裸子植物(Gymnosperm ae)3科5属6种;被子植物(Angiosperm ae)91科286属520种。种子植物中含20种以上的有5科,共210种;含5种以上的属有14个属,共114种。北京地区湿地植物的分布(即地理成分)较复杂。北京湿地种子植物属的分布区类型有15个类型,9个变型,温带地区类型占主导,温带成分较丰富(属数、种类、比例均占首位)。本区植物区系的主要特征为:①草本植物发达;②温带成分占优势地位;③区系起源古老;④特有属、种匮乏;⑤分布区类型具多样性。     

Giant swarms of Precambrian mafic dikes and potential diamond resources of ancient platforms

By the examples of the Siberian Platform and Canadian Shield, it is shown that spatial juxtaposition of Phanerozoic diamond-bearing kimberlite fields with giant swarms of Precambrian mafic dikes is caused by both systematic and incidental events. The first of these include (1) origination of mantle plumes and associated lenses of high-temperature mantle melting in the subequatorial “hot belt” of the early Earth, (2) formation of magma chambers that generated mafic dikes in these asthenospheric lenses, (3) shear stress, and (4) ultrahigh-pressure metamorphism of igneous and country rocks. As a result, the association of diamond-bearing high-density mafic and ultramafic rocks was formed under favorable thermal and fluidal conditions. These processes occurred first in the embryonic (multiplate) Neoarchean tectonic setting at a depth of 40–60 km (present-day elevation marks) and then at a deeper (100–150 km) level during the transition to the Proterozoic true plate tectonics. These processes left behind giant swarms of Precambrian mafic dikes, as well as structurally and genetically related deep-seated morphological and density anomalies. The relatively high position of two lithospheric units of diamond-bearing rocks, each underlain by a thick layer of the cold mantle, prevented these units from thermal and mechanical erosion during subsequent plate-tectonic stages characterized by deeper location of asthenospheric layers. The occurrence of clusters of Phanerozoic diatremes in ancient giant swarms of mafic dikes, as well as the enrichment of pipes in xenogenic diamond-bearing material derived from different levels of the tectonically delaminated lithosphere, may be attributed to incidental events that controlled the fertility of a relatively small number of kimberlite pipes.     

Threshold velocity for wind erosion: the effects of porous fences

Porous fence is a kind of artificial windbreak that has many practical applications. The threshold wind velocities at different distances downwind from porous fences were measured and the corresponding characteristics of particle movement observed to assess their shelter effect. It is found that the fence’s porosity is the key factor that determines the resulting shelter effect. The area near a fence can be typically classified into five regions, each with a different mode of particle movement. Dense fences, and especially solid fences, favor the accumulation of sand upwind of the fences. Fences with porosities of 0.3–0.4 produce the maximum threshold wind velocity; those with porosities of 0.3–0.6 (depending on the fence height) provide the maximum effective shelter distance. It is confirmed that the fence porosities of 0.3–0.4 that have been proposed for practical application in previous research are the most effective for abating wind erosion.     

Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.