Heliocentric evolution of the degradation of polyoxymethylene: Application to the origin of the formaldehyde (H2CO) extended source in Comet C/1995 O1 (Hale-Bopp)

The H₂CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH₂O)_n, also called POM) into gaseous H₂CO. POM decomposition can indeed explain the H₂CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H₂CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.     

Spectral and geological study of the sulfate-rich region of West Candor Chasma, Mars

Sulfates have been discovered by the OMEGA spectrometer in different locations of the planet Mars. They are strongly correlated to light toned layered deposits in the equatorial regions. West Candor Chasma is the canyon with the thickest stack of layers and one with the largest area covered by sulfates. A detailed study coupling mineralogy derived from OMEGA spectral data and geology derived from HRSC imager and other datasets leads to some straightforward issues. The monohydrated sulfate kieserite is found mainly over heavily eroded scarps of light toned material. It likely corresponds to a mineral present in the initial rock formed either during formation and diagenesis of sediments, or during hydrothermal alteration at depth, because it is typically found on outcrops that are eroded and steep. Polyhydrated sulfates, that match any Ca-, Na-, Fe-, or Mg-sulfates with more than one water molecule, are preferentially present on less eroded and darker outcrops than outcrops of kieserite. These variations can be the result of a diversity in the composition and/or of the rehydration of kieserite on surfaces with longer exposure. The latter possibility of rehydration in the current, or recent, atmosphere suggests the low surface temperatures preserve sulfates from desiccation, and, also can rehydrate part of them. Strong signatures of iron oxides are present on sulfate-rich scarps and at the base of layered deposits scarps. They are correlated with TES gray hematite signature and might correspond to iron oxides present in the rock as sand-size grains, or possibly larger concretions, that are eroded and transported down by gravity at the base of the scarp. Pyroxenes are present mainly on sand dunes in the low lying terrains. Pyroxene is strongly depleted or absent in the layered deposits. When mixed with kieserite, local observations favor a spatial mixing with dunes over layered deposits. Sulfates such as those detected in the studied area require the presence of liquid water to form by precipitation, either in an intermittent lacustrine environment or by hydrothermal fluid circulation. Both possibilities require the presence of sulfur-rich groundwater to explain fluid circulation. The elevation of the uppermost sulfate signatures suggests the presence of aquifers up to 2.5 km above datum, only 1 km below the plateau surface.     

Correspondence analysis applied to volcanic aerosols

A statistical analysis of volcanic aerosol based on 1,083 variables including concentration, grain-size and site variabilities establishes correlations between sites and among chemical elements.Variation curves of element concentration show parallel behaviour. High coefficients of correlation between anions and cations confirm associations between elements.     

Incorporating GIS Building Data and Census Housing Statistics for Sub-Block-Level Population Estimation

This article presents a deterministic model for sub-block-level population estimation based on the total building volumes derived from geographic information system (GIS) building data and three census block-level housing statistics. To assess the model, we generated artificial blocks by aggregating census block areas and calculating the respective housing statistics. We then applied the model to estimate populations for sub-artificial-block areas and assessed the estimates with census populations of the areas. Our analyses indicate that the average percent error of population estimation for sub-artificial-block areas is comparable to those for sub-census-block areas of the same size relative to associated blocks. The smaller the sub-block-level areas, the higher the population estimation errors. For example, the average percent error for residential areas is approximately 0.11 percent for 100 percent block areas and 35 percent for 5 percent block areas.     

Titan's surface at 2.2-cm wavelength imaged by the Cassini RADAR radiometer: Calibration and first results

The first comprehensive calibration and mapping of the thermal microwave emission from Titan's surface is reported based on radiometric data obtained at 2.2-cm wavelength by the passive radiometer included in the Cassini Radar instrument. The data reported were accumulated from 69 separate observational segments in Titan passes from Ta (October 2004) through T30 (May 2007) and include emission from 94% of Titan's surface. They are diverse in the key observing parameters of emission angle, polarization, and spatial resolution, and their reduction into calibrated global mosaic maps involved several steps. Analysis of the polarimetry obtained at low to moderate resolution (50+ km) enabled integration of the radiometry into a single mosaic of the equivalent brightness temperature at normal incidence with a relative precision of about 1 K. The Huygens probe measurement of Titan's surface temperature and radiometry obtained on Titan's dune fields allowed us to infer an absolute calibration estimated to be accurate to a level approaching 1 K. The results provide evidence for a surface that is complex and varied on large scales. The radiometry primarily constrains physical properties of the surface, where we see strong evidence for subsurface (volume) scattering as a dominant mechanism that determines the emissivity, with the possibility of a fluffy or graded-density surface layer in many regions. The results are consistent with, but not necessarily definitive of a surface composition resulting from the slow deposition and processing of organic compounds from the atmosphere.     

Ground-based electromagnetic studies combined with remote sensing based on Demeter mission: A way to monitor active faults and volcanoes

The identification of magnetic, electric and electromagnetic (EM) precursory signals related to volcanic activities and earthquakes is still a matter of debate. Some examples are now well established, but they are often based on a few parameters recorded on sparse equipments and with no multi-disciplinary approach. Demeter program takes into account a more complete approach of EM phenomena related to volcanic eruptions and earthquakes, by combining both ground-based and satellite EM monitoring, from direct current to several kilohertz, i.e. from ULF, ELF to VLF frequency domains.The research program stands in two parts: one is the identification of EM signals at the satellite altitude and the other consists in detailed studies in a few pilot sites on the ground. Two main test sites have been considered: La Fournaise volcano in Réunion Island and the seismogenic Corinth rift in Greece. Both sites allow for performing EM studies in a multi-disciplinary environment.La Fournaise volcano erupts on average two times a year. The self-recording Demeter EM station is composed of three modules measuring the components of the magnetic and electric fields in three different frequency domains: DC to 0.5 Hz, 0.0033-160 Hz and 8-10 kHz. Preliminary observations made during the May 2003 eruption show that electric and magnetic signals appeared before the eruption. Some signals present sharp step-like variations, with amplitudes up to several hundreds mV per km and a few hour duration, followed by periods with a higher spectral frequency content. The frequency of these signals can be of several tens of Hz.The Corinth rift is a highly seismic area, frequently affected by seismic swarms. In 2004 the region has experienced tens of earthquakes of magnitude less than 4.6. A Demeter station has been set up on the Trizonia Island along the northern mainland coast, where a 30 km long seismic gap has been identified. The station is composed of two modules recording the three components of the magnetic field and the two horizontal components of the electric field in the ULF and ELF-VLF frequency bands. The audiomagnetotelluric soundings show that the station is close to a regional conductive fault connected to the sea. The first 4 months of observation clearly show that 29 earthquakes, even of low magnitude (M?2.8), occurring at less than 140 km of distance of the station, have generated electric signals when the seismic waves have passed the EM station. For a given magnitude of the earthquake, the energy of the electric signal is independent of the distance between the focal source and the EM station, which points out local electric source mechanisms. The greater the magnitude of the earthquake, the greater is the energy of the electric signal is. The co-seismic electric signals have the same morphology as that of the passing seismic wave, and there is no noticeable time delay between the electric and the seismic signals. This simultaneity between the seismic and the electric signal is best explained by the generation of an electrokinetic effect due to the passage of the seismic wave through the seawater-saturated ground.     

Radiative Feedbacks and Monsoon Circulations: A View from Simplified Models

The modulation of radiative processes by changes in water vapor and cloudiness is at the origin of important feedbacks which control climate variability as well as climate changes. These feedbacks are especially active in the intertropical area, where it is possible to diagnose a combination of partially compensating positive and negative feedbacks. The characteristics and the strength of those feedbacks is closely associated with the dynamical regimes in which they develop. Reverse changes in dynamical patterns may cause a modulation of the radiative processes. A first approach to these problems is to distinguish between two ascending and subsiding circulation patterns. This bimodality of the circulation is well established in the tropical area, and favors the use of simplified models as an appropriate tool to carry out a first-order quantification of these processes. In particular, this combination of radiative and dynamical feedbacks characterizes the development of the monsoons and their variability. Simple conceptual models can thus serve to characterize some of the factors which will affect the intraseasonal variations of the monsoon.