台风过境期间辽河口滨海湿地水动力特征的数值模拟研究

本研究基于FVCOM环流模型,耦合ECMWF背景风场和Jelesnianski台风经验模型形成合成风场,对9711台风“温妮”过境辽河口区域的水动力进行模拟研究。模型通过在动量方程、湍流方程中加入附加源项来表达盐沼植被对水动力的阻碍作用。使用研究区域实测的潮位、流速、流向等数据对水动力模型进行验证,模拟结果与实测数据吻合较好。结果表明：潮滩盐沼植被对台风过境期间的潮位变化无明显影响,但对流速具有显著的衰减作用,且芦苇对潮流的衰减作用大于盐地碱蓬植被,芦苇区的速度最大衰减率达81.43%。此外,台风路径变化对辽河口湿地海域的增减水及流速影响较大,台风强度越强,局部区域造成的风暴潮增水和流速也相应越大。     

错列不等直径双圆柱绕流特性数值研究

为研究低亚临界雷诺数Re情况下错列角度θ对不等直径双柱体绕流特性的影响,利用Fluent软件模拟了Re为3 900、间距比G/D为2.0、直径比D/d为0.5、θ=0°~180°之间9种角度的绕流过程,得到了流场涡量图、斯特鲁哈数St_1和St_2、平均阻力系数C_(d1)和C_(d2)以及平均升力系数C_(l1)和C_(l2)。研究结果表明,随着θ的从小到大,St_1先增大后减小,且在θ=30°和180°时有两个值,St_2在θ=120°~150°时明显小于其它角度;C_(d1)和C_(d2)的整体趋势都是先增大后减小,C_(l1)在θ=150°时取得极大值,C_(l2)在θ=30°时取得极小值。θ=0°时,两柱后方有单一涡脱落形态;θ=30°时,小柱后方有稳定漩涡脱落产生,大柱后方涡脱落受到干扰,且大柱有两个涡脱落频率;θ=45°~90°时,在间隙流的作用下,两柱后方均有漩涡脱落,尾流中有两列涡街;θ=120°~180°时,大柱后有稳定漩涡脱落,小柱涡脱落受到抑制。研究结果可为相关海洋工程设计提供参考。     

Compression behaviors of distorted rutile-type hydrous phases, MOOH (M?=?Ga, In, Cr) and CrOOD

X-ray diffraction measurements of distorted rutile-type oxyhydroxides β-GaOOH, InOOH, β-CrOOH, and β-CrOOD were taken at a maximum pressure of up to 35 GPa under quasi-hydrostatic conditions, at ambient temperature. Anomalies in the evolution of the relative lattice constants and the axial ratios of β-GaOOH, InOOH, and β-CrOOD suggest anisotropic stiffening along the a- and/or b-axes where the hydrogen bond is formed. The changes were observed at 15 GPa in β-GaOOH and InOOH and at 4 GPa in β-CrOOD. The pressures were higher in oxyhydroxides that have longer O…O distances of the hydrogen bond at ambient pressure. In contrast, such stiffening behavior was not observed in CrOOH, which has a significant short O…O distance and strong hydrogen bond. The stiffening behaviors observed in the present study can be attributed to the symmetrization of the hydrogen bonds in oxyhydroxides, as was previously found in δ-AlOOH(D).     

Induction of tributyltin-binding protein type 2 in Japanese flounder, Paralichthys olivaceus, by exposure to tributyltin-d27

In this study, individual Japanese flounder were intraperitoneally injected with 2 μg tributyltin-d27 (TBT-d27) fish⁻¹. Blood samples were collected on day 7 after injection. TBT-binding protein types 1 and 2 (TBT-bp1, -bp2) in the blood serum were quantified by western blotting analysis. As a result, the concentration of TBT-bp2 in TBT-d27 treated group increased to 220% of that in the solvent control, whereas the TBT-bp1 concentration decreased to 65% of that in the solvent control. Additionally, a positive relationship between the concentrations of TBT-bp2 and TBT was observed in blood sera of wild and cultured flounder. We suggest that TBT-bp2 is produced in response to TBT exposure and may play an important role in fish physiology.     

A DEM-based evaluation of potential flood risk to enhance decision support system for safe evacuation

A practical, DEM-based practical method is proposed to enhance flood risk management in fluvial areas by quantifying relative risk as a function of vulnerability to inland and evacuation difficulty. Both measures are based mainly on the topography of the region, so the method does not require detailed data on the physical characteristics of the land. First, we use the deterministic 8-node method on a digital elevation map (DEM) to trace storm waterways. Second, we repeat the process on a reversed DEM to trace evacuation routes that avoid the waterways and zones dangerously close to the rivers. Finally, on the basis of such two flow lines of evacuee and storm water, we proposed the protocol to evaluate the flood risk at every point on the map taking into account both the minimum time required for floodwater to arrive and duration of an evacuation from that location. The time that must be allocated for safe evacuation is defined as the potential flood risk of evacuation (PFRE). The method is demonstrated on a fluvial area of the Kaki River in Nagaoka city, Japan. In addition, we illustrated the application of the PFRE map to divide the region into areas of greater or lesser evacuation urgency.     

Performance of dry-separation processes in the recovery of cenospheres from fly ash and their implementation in a recovery unit

Cenospheres recovery is one of the coal fly ash beneficiations, providing economic as well as environmental benefits. Current techniques, such as lagoon or other wet-separation processes, consume large amounts of water and add to water pollution due to leaching of toxic materials from fly ash. The other possible disadvantage is the need for a wide operational area, which is unsuitable for densely populated countries. As wet-separation processes have some disadvantages, an improved and/or sustainable alternative recovery technique is required. An air classifier is one of the alternative techniques. In this study, two types of air classifiers, namely a closed-type pneumatic separator and a micron separator, have been investigated. In terms of separation efficiency, it was found that the micron separator has the potential to be applied in cenospheres recovery from coal fly ash, giving a Newton's efficiency of 0.44, as compared to a value of about 0.26 for the closed-type pneumatic separator. The cenospheres recoveries of both pieces of equipment at their optimum Newton's efficiencies were similar at over 60 wt.%. The separation performance was further assessed from the particle distributions of the overflow and underflow products obtained from both pieces of equipment, as well as from SEM images. It was found that the lower Newton's efficiency of the closed-type pneumatic separator was due to the re-concentration of fine particles in the underflow product at air-flow rates higher than 2.2 m/s (the underflow product yield was about 55 wt.%).In order to further confirm the applicability of this technique, the micron separator, which had provided higher separation efficiency and cenospheres recovery, was deployed in a cenospheres recovery unit prior to the use of a wet-separation process (float and sink tank). About 80% of the cenospheres was recovered, with an 87.8% reduction in the total mass of fly ash to be separated in the float and sink tank. Consequently, much less water was needed for the process of cenospheres recovery. Moreover, it was also confirmed that the micron separator could yield higher quality fly ashes, that is, fly ash types I and II, from lower feed quality of fly ash type IV, which is the lowest category in commercial classification of fly ash according to JIS A6201.     

Elasticity of CaIrO<Subscript>3</Subscript> with perovskite and post-perovskite structure

Compression behaviors of CaIrO₃ with perovskite (Pv) and post-perovskite (pPv) structures have been investigated up to 31.0(1.0) and 35.3(1) GPa at room temperature, respectively, in a diamond-anvil cell with hydrostatic pressure media. CaIrO₃ Pv and pPv phases were compressed with the axial compressibility of β _a > β _c > β _b and β _b > β _a > β _c, respectively and no phase transition was observed in both phases up to the highest pressure in the present study. The order of axial compressibility for pPv phase is consistent with the crystallographic consideration for layer structured materials and previous experimental results. On the other hand, Pv phase shows anomalous compression behavior in b axis, which exhibit constant or slightly expanded above 13 GPa, although the applied pressure remained hydrostatic. Volume difference between Pv and pPv phases was gradually decreased with increasing pressure and this is consistent with the results of theoretical study based on the ab initio calculation. Present results, combined with theoretical study, suggest that these complicate compression behaviors in CaIrO₃ under high pressure might be caused by the partially filled electron of Ir⁴⁺. Special attention must be paid in case of using CaIrO₃ as analog materials to MgSiO₃, although CaIrO₃ exhibits interesting physical properties under high pressure.     

High-pressure phase behavior of MnTiO<Subscript>3</Subscript>: decomposition of perovskite into MnO and MnTi<Subscript>2</Subscript>O<Subscript>5</Subscript>

The phase relations and compression behavior of MnTiO₃ perovskite were examined using a laser-heated diamond-anvil cell, X-ray diffraction, and analytical transmission electron microscopy. The results show that MnTiO₃ perovskite becomes unstable and decomposes into MnO and orthorhombic MnTi₂O₅ phases at above 38 GPa and high temperature. This is the first example of ABO₃ perovskite decomposing into AO + AB₂O₅ phases at high pressure. The compression behavior of volume, axes, and the tilting angle of TiO₆ octahedron of MnTiO₃ perovskite are consistent with those of other A²⁺B⁴⁺O₃ perovskites, although no such decomposition was observed in other perovskites. FeTiO₃ is also known to decompose into two phases, instead of transforming into the CaIrO₃-type post-perovskite phase and we argue that one of the reasons for the peculiar behavior of titanate is the weak covalency of the Ti–O chemical bonds.     

In situ observation of a garnet/perovskite transition in CaGeO<Subscript>3</Subscript>

We used an in situ measurement method to investigate the phase transition of CaGeO₃ polymorphs under high pressures and temperatures. A multi-anvil high-pressure apparatus combined with intense synchrotron X-ray radiation was used. The transition boundary between a garnet and a perovskite phase at T = 900–1,650 K and P = 3–8 GPa was determined as occurring at P (GPa) = 9.0−0.0023 × T (K). The transition pressure determined in our study is in general agreement with that observed in previous high-pressure experiments. The slope, dP/dT, of the transition determined in our study is consistent with that calculated from calorimetry data.