三种仿寿山“坑头冻”印材的宝石矿物学特征

为研究缅甸翡翠中的哪些部位适合做烧红处理以及该部位能被烧红的原因,采用加热实验、偏光显微镜、红外光谱及差热分析方法对缅甸翡翠样品的原生部位、雾部位的加热前、后的特征进行了测试与分析。结果显示,翡翠中的蓝雾部位及黄雾部位适合做烧红处理,原生部位不适合烧红处理,蓝雾部位可以被烧成黄色及红色,黄雾部位可以被烧成红色。雾部位适合用来做烧红处理的原因在于,在低温的加热条件下,蓝雾部位中的大量的Fe2＋发生价态变化,实现由绿泥石向针铁矿的转变所导致,该过程由表及里逐步进行。原生部位的主要矿物硬玉需被加热更高的温度,在破坏其晶格的情况下,才可以呈现出红色,且该红色不具有褐色调。     

鄱阳湖组(第四系)的修订及特征

根据对鄱阳湖地区 Zk0 1钻孔柱状剖面的研究 ,对鄱阳湖组的定义进行修订、补充 ,认为鄱阳湖组为一套以青灰色淤泥质粘土、黄褐色粘土、粉质粉土为主夹少量粉砂或细砂的湖泊—河口三角洲相沉积。年代地层为第四系全新统 ,底界年龄约 6 2 10± 12 5 a B.P.,开阔湖泊沉积始于 32 4 0± 180 a B.P.,且由北向南时代渐新 ,具有明显的穿时性     

江苏固城湖流域1951-2000年农业非点源氮、磷输移的数值模拟研究

选择位于长江下游的固城湖流域作为研究区域,基于分布式流域水文模型SWAT,采用数值模拟的手段,反演了1951～2000年流域农业非点源氮、磷的输移规律。模拟结果与实测值的一致性反映了模型的良好模拟能力。比较两个时段的模拟结果发现,1981～2000年,流域农业非点源氮、磷年平均浓度和输移量分别为:总氮0.82mg/L和411.88×103kg/a,总磷0.084mg/L和43.04×103kg/a;远高于1951～1960年的氮、磷年平均浓度和输移量分别为:总氮0.22mg/L和49.55×103kg/a,总磷0.036mg/L和7.67×103kg/a。模拟主要反映了流域下垫面条件和农作物耕作模式对农业非点源氮、磷浓度及输移量的影响。     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

Geochemical, Sr–Nd and zircon U–Pb–Hf isotopic studies of Late Carboniferous magmatism in the West Junggar, Xinjiang: Implications for ridge subduction?

Voluminous granitic intrusions are distributed in the West Junggar, NW China, and they can be classified as the dioritic rocks, charnockite and alkali-feldspar granite groups. The dioritic rocks (SiO₂ = 50.4–63.8 wt.%) are calc-alkaline and Mg enriched (average MgO = 4.54 wt.%, Mg^# = 0.39–0.64), with high Sr/Y ratios (average = 21.2), weak negative Eu (average Eu/Eu = 0.80) and pronounced negative Nb–Ta anomalies. Their Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7035–0.7042, ε_Nd(t) = 4.5–7.9, ε_Hf(t) = 14.1–14.5) show a depleted mantle-like signature. These features are compatible with adakites derived from partial melting of subducted oceanic crust that interacted with mantle materials. The charnockites (SiO₂ = 60.0–65.3 wt.%) show transitional geochemical characteristics from calc-alkaline to alkaline, with weak negative Eu (average Eu/Eu = 0.75) but pronounced negative Nb–Ta anomalies. Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7037–0.7039, ε_Nd(t) = 5.2–8.0, ε_Hf(t) = 13.9–14.7) also indicate a depleted source, suggesting melts from a hot, juvenile lower crust. Alkali-feldspar granites (SiO₂ = 70.0–78.4 wt.%) are alkali and Fe-enriched, and have distinct negative Eu and Nb–Ta anomalies (average Eu/Eu = 0.26), low Sr/Y ratios (average = 2.11), and depleted Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7024–0.7045, ε_Nd(t) = 5.1–8.9, ε_Hf(t) = 13.7–14.2). These characteristics are also comparable with those of rocks derived from juvenile lower crust. Despite of the differences in petrology, geochemistry and possibly different origins, zircon ages indicate that these three groups of rocks were coevally emplaced at ~ 305 Ma.A ridge subduction model can account for the geochemical characteristics of these granitoids and coeval mafic rocks. As the “slab window” opened, upwelling asthenosphere provided enhanced heat flux and triggered voluminous magmatisms: partial melting of the subducting slab formed the dioritic rocks; partial melting of the hot juvenile lower crust produced charnockite and alkali-feldspar granite, and partial melting in the mantle wedge generated mafic rocks in the region. These results suggest that subduction was ongoing in the Late Carboniferous and, thus support that the accretion and collision in the Central Asian Orogenic Belt took place in North Xinjiang after 305 Ma, and possibly in the Permian.     

城市土地利用对植被特征影响的研究

城市土地利用对植被的影响是城市生态学中研究的重要问题。简单综述了国内外在该领域中的研究现状。通过在北京市进行的研究，对城市植被的特点及其与土地利用的关系进行了分析，结论为：①藜科（Chenpodiac eae）和蓼科（Polygonac eae）植物种类数量相对增加，归化植物占的比例大是城市植物区系的特征；②与非城市区域相比，生活型谱中一二年生植物比例增高，属的区系地理成分构成中世界分布属所占比例也明显提高；③城市土地利用类型对生境和植物群落特征的影响明显；④生境多样化对维持城市植物物种多样性而言，比面积大小具有更为显著的作用。     

水泥—丙烯酸盐复合浆液的实验性研究

水泥-丙烯酸盐复合浆液是在丙烯酸盐浆液的基础上研制出来的一种复合浆液，它既保留了丙烯酸盐浆液流动性好，固结体弹性好的优点，又大幅度地提高了浆液的抗压强度和粘结强度，因此在注浆时可以带来良好的综合灌注效果，还对复合浆液的粘度和强度进行了试验性研究。     

航空重力数据常用滤波方法对比研究

航空重力测量中,存在着各种各样的噪声干扰,严重影响了异常的精度和分辨率。低通滤波器在航空重力测量数据处理中对于去掉高频噪声干扰有着重要的作用;因此,对航空测量信号进行异常恢复和噪声信号衰减的一个重要步骤就是设计低通性能更优越的滤波器。通过模型实验,对比6×20_s RC滤波器、Kalman滤波器和FFT滤波器输出结果,以确定各种滤波器的可靠性,并分析了3种滤波器的影响因素,为以后对数字滤波器的研究奠定基础。     

滇西保山地块金厂河矿集区铁铜金铅锌多金属矿床成矿系统

滇西保山地块是西南“三江”特提斯构造带的重要组成部分,其大地构造位置处于藏-滇-泰-马中间板块中段,是近年来科学研究和地质找矿的热点地区之一。受区域构造演化的影响,保山地块先后历经原、古、中、新特提斯演化,并发生了多期成岩成矿事件,在北部形成了以金厂河铁铜铅锌矿、核桃坪铅锌矿、陡崖铁铜多金属矿、黑牛凹金矿、黄家地金矿等为代表的金厂河铁铜金铅锌多金属矿集区。区内矿床在成矿空间上具有明显的分带性,单个矿床在垂向上、平面上均呈有规律地分布,其分带标志除了矿床类型外,还表现在有用矿物组合及元素分带。由下往上、由内向外均有Fe→Cu-Fe→Cu-Pb-Zn→Au矿种分带及“矽卡岩型→构造蚀变岩型→石英脉型”的矿床类型分带,成矿元素均从高温到中低温变化。成矿系统的分析表明,区内各代表性矿床中矿石的硫、铅同位素组成和变化范围较为一致性,矿床的形成具有相似的成矿流体,表明不同类型的矿化可能形成于早白垩世中特提斯洋的闭合过程。本文综合区内构造演化、典型矿床地质特征、各地质事件发生的先后关系,建立了金厂河矿集区铁铜金铅锌多金属矿床成矿模式,以期为该区深边部地质找矿提供科学依据。     

东昆仑大干沟火山岩SHRIMP锆石U-Pb测年及其地质意义

东昆仑大干沟以北地区造山后形成的牦牛山组磨拉石建造不整合覆盖于前泥盆系之上,其形成时代对限定柴达木盆地加里东造山作用的结束时间及晚古生代裂解作用的开始时间具有重要意义。应用单颗粒锆石离子探针质谱仪(SHRIMP)方法,对牦牛山组上部火山岩段的样品进行精确的锆石U-Pb测年。结果表明,牦牛山组上段火山岩样品DG01和DG02中的岩浆锆石206Pb/238U平均年龄分别为403.6±5.1Ma和409±3.4Ma。综合前人研究认为,造山后牦牛山组伸展型磨拉石的形成时代为晚志留世-早泥盆世,限定了晚古生代裂解的开始时间,也意味着早古生代加里东造山运动在晚志留世-早泥盆世之前已经结束。