The Caledonian Structures of Shetland – Funzie and Norwick Geological Conservation Review sites

Locations at Funzie on the island of Fetlar, and at Norwick on the island of Unst contain excellent examples of structures relating to the Caledonian age disruption and emplacement of the Shetland Ophiolite Complex. The Caledonian age Shetland Ophiolite Complex contains exceptionally well developed and exposed sections of the lower parts of the characteristic ophiolite sequence, including layered gabbro, cumulates and mantle rock. Composed of two tectonic units (the Lower Nappe and Upper Nappe) each underlain by an imbricate zone, it is among the finest and most accessible examples of ophiolitic rocks in Europe. The sites at Funzie and Norwick have been selected to be part of the Caledonian Structures of Great Britain Geological Conservation Review (GCR) network, as the best examples in Britain of structures relating to Caledonian ophiolite disruption and emplacement. As the Funzie GCR site and the Norwick GCR site they form the Caledonian Structures of Shetland GCR block.Accounts of all other sites in the Caledonian Structures of Great Britain Geological Conservation Review (GCR) network are already published (Treagus, 1992). Accounts of the Caledonian Structures of Shetland GCR block sites are, therefore, presented in this paper to complete publication of the Caledonian Structures of Great Britain Geological Conservation Review (GCR) network.     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

栖霞地区金矿床特征及找矿方向

栖霞地区金矿点繁多,但仅有两处规模近中型的金矿床。根据对马家窑、台前金矿床特征及成矿地质条件的分析,并与招莱地区金矿床进行类比,认为栖霞地区金矿成矿条件与招莱地区基本相似,但由于重熔花岗岩体侵位较深,含矿热液未能运移至浅部,因而热液矿床赋存深度较大,地表及浅部金矿呈现“矿点多,规模小”的分布特点。栖霞地区深部找金潜力很大,重点勘查区应为隐伏的深熔、重熔花岗岩发育区,以及ＮＥ、ＮＮＥ向断裂及其下盘次级断裂所在部位。     

Measuring place-based accessibility under travel time uncertainty

Travel time uncertainty has significant impacts on individual activity-travel scheduling, but at present these impacts have not been considered in most accessibility studies. In this paper, an accessibility evaluation framework is proposed for urban areas with uncertain travel times. A reliable space-time service region (RSTR) model is introduced to represent the space-time service region of a facility under travel time uncertainty. Based on the RSTR model, four reliable place-based accessibility measures are proposed to evaluate accessibility to urban services by incorporating the effects of travel time reliability. To demonstrate the applicability of the proposed framework, a case study using large-scale taxi tracking data is carried out. The results of the case study indicate that the proposed accessibility measures can evaluate large-scale place-based accessibility well in urban areas with uncertain travel times. Conventional place-based accessibility indicators ignoring travel time reliability can significantly overestimate the accessibility to urban services.     

黑龙江省浅覆盖区地物化特征与找矿标志——以黑河市340高地金矿化区为例

黑龙江省黑河市340高地金矿点大地构造上位于兴安地块东北缘,多宝山Cu-Au-Mo-W-Fe成矿亚带内,其地貌为浅覆盖区,找矿较为困难。本文采用浅钻技术取样,对研究区进行基岩填图,圈定出以硅化为中心、青磐岩化为外围的蚀变矿化带。对基岩样品进行岩石地球化学分析,通过主成分分析,确定有6个主成分特征值大于1,其中第二主成分与金元素关系密切,是研究区有效的找矿标志。高精度磁测结果显示区内构造以NNW向为主,且其线性低值异常或与蚀变引起的退磁有关。对区内的地物化异常进行工程查证,发现金矿点1处,圈定预测靶区1处。     

The music of the spheres and the prosaicness of statistical criteria: A response to B.L. Berry’s paper “Heliogeophysical and other natural processes,periods of their oscillations,and forecasts”

According to B.L. Berry’s “harmonic model,” any natural or social process is a superposition of several cosmic rhythms. The author assumes that stability of these rhythms allows prediction of earth phenomena over an unlimited time. We show that the statistical criteria supposedly substantiating the harmonic model were applied incorrectly. The initial data for the analysis were biased and selected incompetently; the adequacy of the methods used was not verified. Predictions of natural catastrophes (earthquakes, weather anomalies, etc.) and various social events according to Berry’s model are unsatisfactory. Statistics do not confirm that these predictions are at least slightly better than random guessing. Berry’s model is unacceptable; it is untenable both in detail and in general.     

Scenarios of nonlinear wave transformation in the coastal zone

On the basis of field experiments and numerical modeling, we show that coastal zones are classifiable according to manifestations of wind wave nonlinearity, which herein is recognized as periodic energy exchange between the first and second nonlinear wave harmonics depending on the average bottom slope and the Iribarren and Ursell numbers. The results offer a basis for developing vulnerability criteria for the coastal zone taking into account its nonlinear dynamics.     

赣南狮吼山硫铁多金属矿区花岗岩地球化学、年代学特征及其成因

狮吼山矿区是江西省内规模最大的矽卡岩型硫铁多金属矿床,伴生W、Cu、Au多种成矿元素,成矿作用与矿区出露的茶山迳复式花岗岩体有关。岩体主要包括茶山迳似斑状黑云母二长花岗岩和莲湖细粒二长花岗岩两期,为研究成矿岩体的侵位时代、岩石成因及与成矿的关系,本次工作进行了U-Pb锆石定年、岩相学和岩石地球化学等测试分析。结果表明：岩体具有高硅、高钾、富铝的特征,属高钾钙碱性系列花岗岩;轻重稀土元素分馏明显,均为右倾型,弱Eu负异常,以富集Cs、Rb、Th、U、Pb,亏损Ba、Nb、Sr、和Ti等元素为主要特征,属于低Ba-Sr壳源花岗岩类;锆石具较好晶形,具典型岩浆锆石特征,利用LA-ICP-MS进行U-Pb测年,获得谐和年龄为（162.4±0.6）Ma（MSWD=1.8）,加权平均年龄为（162.4±1.4）Ma（MSWD=1.4）,谐和年龄与加权平均年龄在误差范围内高度一致,表明茶山迳复式岩体侵位于燕山早期中侏罗世;综合考虑岩体矿物组合、主微量元素及高分异特征,认为其成因分类应属于S型花岗岩;对比中国花岗岩成矿元素平均含量,茶山迳两期花岗岩均具有较高的W、Mo、Bi、Pb等成矿元素含量,可同时为成矿作用提供热源、流体及物质。