Preconcentration/Separation of Gold and Palladium by a Microcolumn Packed with Azadirachta Indica Leaf Powder and Their Determination in Geological Samples by ICP‐OES

A new method using a microcolumn (20 mm length × 2.0 mm i.d.) packed with Azadirachta Indica leaf powder (Neem leaf) as an adsorbent for the preconcentration/separation of Au and Pd prior to their determination by ICP‐OES in geological samples is presented. Various factors affecting the separation and preconcentration of the target analytes such as pH, sample flow rate and volume, eluent concentration and volume and interfering ions were studied and the optimal experimental conditions were established. The adsorption capacity of Azadirachta Indica leaf for Au and Pd was found to be 39.2 and 9.8 mg g⁻¹, respectively. The detection limits (3s) of this method for Au and Pd with an enrichment factor of 50 were 47 ng l⁻¹ and 59 ng l⁻¹ and the relative standard deviations were 4.8% and 5.7% (n = 7, adsorption capacity C = 5 ng ml⁻¹), respectively. In order to validate the proposed method, the certified reference material, GBW07293, was analysed, and a good agreement was obtained between the certified and determined values.     

The 1992 Tafilalt seismic crisis (Anti-Atlas, Morocco)

The Tafilalt region, located at the eastern end of the Anti-Atlas chain in Morocco, was shaken on 23 and 30 October 1992 by two moderate earthquakes of magnitude mb ∼ 5 and intensity ∼ VI MSK64, which caused two deaths and great damage in the area between Erfoud and Rissani. The review of data available on the seismic crisis allowed us to improve the knowledge on the macroseismic, instrumental and source parameters of the earthquakes. The main results of the present study are: (1) location of the epicentres with the help of data from a close portable network allowed us to propose new epicentral coordinates at 31.361° N, 4.182° W (23 October) and 31.286° N, 4.347° W (30 October); both events have focal depths of 2 km; (2) the shock of 30 October was followed by a series of 305 aftershocks, most of which were located west of Rissani; the 61 best-constrained events had focal depths of 5 to 19 km and magnitudes 0.7 to 3; (3) the largest damage was located in an area between the two epicentres within the Tafilalt valley and was probably amplified by site effects due to the proximity of the water table within the Quaternary sediments; (4) focal mechanisms of the main events correspond to strike-slip faulting with fault planes oriented N–S (left lateral) and E–W (right lateral); the only mechanism available for the aftershocks also corresponds to strike-slip faulting; (5) spectral analysis shows that the scalar seismic moment (Mo) of the first event is slightly larger than the second; the corresponding values of Mw are 5.1 and 5.0, respectively; (6) the dimensions of the faults for a circular fault model are 7.7 ± 1.4 and 7.4 ± 1.2 km, respectively; the average displacement is 4 cm for the first event and 3.7 cm for the second; the stress drop is 0.4 and 0.3 MPa, respectively, in agreement with standard values; (7) the Coulomb Stress test performed for both earthquakes suggests a relationship between both events only when the used location is at the limit of the horizontal uncertainty; (8) finally, the occurrence of these shocks suggests that the Anti-Atlas is undergoing tectonic deformation in addition to thermal uplift as suggested by recent publications.     

Evidence for reduced post-spill recovery by the halophyte Sporobolus iocladus (Nees ex Trin.) Nees in oil-contaminated sediments

The germination behavior of Sporobolus iocladus seeds including germination percentage, accumulated germination percentage, the average incubation period to germination and germination velocity was studied under laboratory conditions. Treatments included six salinity regimes (0, 70, 140, 210, 280 and 350 mM NaCI) and three sources of oil hydrocarbons; Light Arabian Crude, polynuclear aromatic hydrocarbons (PAHs) including diaromatic or triaromatic hydrocarbons (in crude oil equivalent concentrations, COEC). The average incubation period needed for seeds to germinate was significantly longer for seeds germinated in 350 mM NaCl (6 +/- 1.16 days) compared with the control (4 +/- 00 days). The accumulated germination percentage gradually decreased with increasing salinity (control: 90 +/- 10, while 350 mM NaCl: 63 +/- 8.8). Oil hydrocarbons significantly affected all germination parameters of S. iocladus seeds regardless of salinity levels. COEC of di- and triaromatic hydrocarbons suppressed seed germination more than crude oil. Seeds exposed to diaromatic hydrocarbons failed to germinate. Hydrocarbon's salinity interaction significantly reduced the number of germinated S. iocladus seeds. It is concluded that hydrocarbon pollutants adversely affect S. iocladus through reducing germination. It is also suggested that the toxic effect of hydrocarbons on seeds is not solely mediated through their interaction with salinity. The ecological implications of these findings are discussed in relation to other studies on the post-spill recovery of halophytes.     

Evaluation of seismic site factors in the Mississippi Embayment. I. Estimation of dynamic properties

Deep deposits of the Mississippi Embayment, overlying the New Madrid Seismic Zone, present unique challenges for the estimation of local site effects on propagated ground motion. Limited information is available on the dynamic properties of these deposits. This paper develops generalized depth dependent modulus degradation and damping curves specific to the embayment deposits. Depth dependent small strain damping is estimated using weak motion recordings during the Enola earthquake, 2001. Modulus degradation and damping curves are further constrained using limited laboratory test data of embayment soils at low confining pressure. At high confining pressures embayment specific data is unavailable and test data from outside the embayment is used in developing the dynamic properties. The representative modulus degradation and damping curves are used in non-linear and equivalent linear one-dimensional site response analyses. A companion paper describes a large-scale probabilistic seismic hazard analysis study in the Mississippi Embayment that integrates non-linear site effects.     

First microbialites associated to organic-rich facies of the Oceanic Anoxic Event 2 (Northern Tunisia,Cenomanian–Turonian transition)

From northern Tunisia, small-scale well-preserved microbialites, contemporaneous to the global oceanic anoxic event 2 (OAE 2) are first reported on the southern Tethyan Margin. These microbialites are encased within the pelagic organic-rich black shales of the Bahloul Formation (Cenomanian–Turonian transition). Biostratigraphic, petrographic, and geochemical investigations carried out to constrain their biogenicity and genesis character led to consider them as thrombolites and stromatolites occurring in lenticular bioherms/biostromes and columnar bodies co-relatable to the global ‘filament event’ of the authors, close to the base of the Watinoceras ammonite zone. Abundant clotted micrite, cyanobacterial filaments, and algal tissues point to the key process of microbial carbonate precipitation and to a major role played by microbes in the stabilisation and subsequent lithification, which in turn favoured the preservation of the original structure of the microbialites. These microbially induced carbonate formations are considered as favoured by chemosynthetic fauna of bivalve molluscs and lithistid sponges which were able to host symbiotic microbial communities. The latter contributed to the precipitation of authigenic calcite and non-carbonate minerals (e.g. pyrite) fuelled by microbial activity under sulphate-reducing conditions. The carbonate body onset is considered to be initiated by seafloor instability due to syndepositional fault acting that induced the appraisal of uplifted tilted blocks within oxygenated waters but near the anoxic water masses. Generated depressions allowed the development of chemosynthetic-based communities. Deep faults related to Triassic salt domes acted as conducts for hydrocarbon and salt brine expulsion to the seafloor and the microbialite growth was enhanced by an abrupt uprising sea level under warmer conditions.     

Characterization of some bacterial strains isolated from the Egyptian eastern and northern coastlines with antimicrobial activity of Bacillus zhangzhouensis OMER4

Marine microorganisms were considered to be important sources of marine bioactive compounds. The major objective of the study was to isolate and characterize bacteria with antimicrobial activities from the various marine environment of Egypt. In this respect, thirty-five bacterial isolates were recovered from sediment samples collected from different spots along the Egyptian Red Sea coastline and Alexandria coastline during the summer season of 2017 and 2018. According to the morphological, phys...