地理信息系统（GIS）在地下水领域中的应用及最新进展

ＧＩＳ是信息时代的产物，在地下水资源领域的研究日益广泛和深入。笔者着重阐述了ＧＩＳ在地下水领域的应用及最新发展，同时对ＧＩＳ在地下水应用中的优点和局限性提出了自己的观点。     

极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

A brief comparison of lava flows from the Deccan Volcanic Province and the Columbia-Oregon Plateau Flood Basalts: Implications for models of flood basalt emplacement

The nature and style of emplacement of Continental Flood Basalt (CFB) lava flows has been a matter of great interest as well as considerable controversy in the recent past. However, even a cursory review of published literature reveals that the Columbia River Basalt Group (CRBG) and Hawaiian volcanoes provide most of the data relevant to this topic. It is interesting to note, however, that the CRBG lava flows and their palaeotopographic control is atypical of other CFB provinces in the world. In this paper, we first present a short overview of important studies pertaining to the emplacement of flood basalt flows. We then briefly review the morphology of lava flows from the Deccan Volcanic Province (DVP) and the Columbia-Oregon Plateau flood basalts. The review underscores the existence of significant variations in lava flow morphology between different provinces, and even within the same province. It is quite likely that there were more than one way of emplacing the voluminous and extensive CFB lava flows. We argue that the establishment of general models of emplacement must be based on a comprehensive documentation of lava flow morphology from all CFB provinces.     

Pollution history and recovery of a boreal lake exposed to a heavy bleached pulping effluent load

We examined the effects of heavy pulp mill discharges on the Lake Lievestuoreenjärvi ecosystem and the later recovery of diatom and chironomid communities from age-dated short core samples. Beginning in 1927 the lake received a heavy effluent load from a sulphite pulp mill. Except for the recession during the Second World War and the temporary closure of the mill from 1967 to 1971, the industrial load, containing large quantities of nutrients, organic matter and toxic compounds, increased continuously. In the early 1980s, laboratory documents were falsified by the directors of the mill and the systematic illegal effluent overload led to a collapse of the whole lake ecosystem. In 1985, the outdated plant was finally closed down. Based on the assessment of chemical properties and biological remains of the sediment, we distinguished five developmental phases in the ecological state of the lake. In the pre-industrial phase, the pelagic and profundal benthic communities were dominated by species preferring ultraoligotrophic or oligotrophic lakes. Concomitant with the increasing discharge and deposition of chlorine compounds, resin acids, and mercury, as well as strong acidity and hypolimnetic and epilimnetic anoxia, the ecological status changed in a short period from excellent to bad. Finally, in the early 1960s, the majority of the lake was virtually dead and the aquatic life survived only in the uppermost littoral zone. Since 1985, a fast recovery in the water quality has led to a strong, but temporary eutrophy in pelagic communities. The main peak of eutrophication was caused by the invasion of a species new to the lake,Aulacoseira granulata var.angustissima. Later, the pelagic communities shifted towards oligotrophy, but the original, pre-industrial status has not been re-established. The profundal benthic communities have not achieved the pre-industrial structure, but at present indicate mesotrophy.     

基于二维小波变换的FMI图象分割

为了从FMI资料中定量提取参数，一个重要的步骤是从实际FMI资料中分离出反映溶孔、溶洞、裂缝的子图像。本文给出的方法，考虑图像像元邻域的特征，应用二维小波变换求出目标与背景边缘的点集，按这个边缘点集的坐标点所对应的原图像像素灰度值的平均值作为分割阈值进行图像分割。实际资料处理表明，应用这种方法可以从实际的FMI资料中准确地分割出孔洞、裂缝的子图像并且可以按深度段连续自动处理，为后续定量计算参数奠定了良好基础。     

Assessing the Comparability of Ammonium,Nitrate and Sulfate Concentrations Measured by Three Air Quality Monitoring Networks

Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice.     

Analysis of the environmental sensitivities of a typical dynamic epikarst system at the Nongla monitoring site, Guangxi, China

Nongla, a typical karst dynamic system (KDS) monitoring site, is located at Nongla Village, Mashan County, Guangxi, China. The data from a Greenspan CTDP300 multichannel data logger indicates that the KDS is highly sensitive to environmental changes. Multi-day and diurnal physico-chemical composition of epikarst spring water is quite different under different climatic conditions. During a day with no rainfall, water temperature and air temperature have similar variations. Electrical conductivity (EC) has good positive correlation with pH value and water temperature. During rainstorms, the physico-chemical composition of the spring water is initially strongly effected by dilution, pH and EC drop rapidly. However, half to one hour later, EC returns to normal and the CO₂ effects will be the dominant physical effect. This is due to the high fissure rates and high permeability in the epikarst zone. Dilution effects were observed during the entire rainstorm event,whereas, it only acts during the earliest period of light rain. Therefore, it is necessary to examine the water–rock–CO₂ combination as a whole system to explain the hydrochemical behavior of epikarst processes.