退火对B掺杂纳米金刚石薄膜微结构和电化学性能的影响

采用热丝化学气相沉积法制备B掺杂纳米金刚石薄膜,并对薄膜进行真空退火处理,系统研究了不同退火温度对B掺杂纳米金刚石薄膜的微结构和电化学性能的影响.结果表明,当退火温度升高到800 ℃后,薄膜的Raman谱图中由未退火时在1157,1346,1470,1555 cm^-1处的4个峰转变为只有D峰和G峰,说明晶界上的氢大量解吸附量减少;并且D峰和G峰的积分强度比I_D/I_G值变为最小,即sp²相团簇     

Role of buffer layer in electronic structures of iron phthalocyanine molecules on Au(111)

We investigate the electronic structures of one and two monolayer iron phthalocyanine (FePc) molecules on Au(111) surfaces. The first monolayer FePc is lying flat on the Au(111) substrate, and the second monolayer FePc is tilted at ～15° relative to the substrate plane along the nearest neighbour [101^-] direction with a lobe downward to the central hole of the unit cell in the first layer. The structural information obtained by first-principles calculations is in agreement with the experiment results. Furthermore, it is demonstrated that the electronic structures of FePc molecules in one-monolayer FePc/Au(111) system are perturbed significantly, while the electronic structures of FePc molecules in the second monolayer in two-monolayer FePc/Au(111) system remain almost unchanged due to the screening of the buffer layer on Au(111).     

Modelling the effect of wave overtopping on nearshore hydrodynamics and morphodynamics around shore-parallel breakwaters

Wave overtopping nearshore coastal structures, such as shore-parallel breakwaters, can significantly alter the current circulation and sediment transport patterns around the structures, which in turn affects the formation of tombolos and salients in the nearshore area. This paper describes the implementation of a wave overtopping module into an existing depth-averaged coastal morphological mode: COAST2D and model applications to investigate the effect of wave overtopping on the hydrodynamics and morphodynamics around a group of shore-parallel breakwaters. The hydrodynamic aspects of the model were validated against a series of laboratory conditions. The model was then applied to a study site at Sea Palling, Norfolk, UK, where 9 shore-parallel segmented breakwaters including 4 surface-piercing and 5 low-crested breakwaters are present, for the storm conditions in Nov 2006. The model results were compared with laboratory data and field measurements, showing a good agreement on both hydrodynamics and morphological changes. Further analysis of wave overtopping effect on the nearshore hydrodynamics and morphodynamics reveals that wave overtopping has significant impacts on the nearshore circulation, sediment transport and the resulting morphological changes within such a complex breakwater scheme under the storm and macro-tide conditions. The results indicate the importance of including the wave overtopping in modelling nearshore morphodynamics with the presence of coastal structures.     

西藏甲玛矿床南坑高分异Ⅰ型花岗斑岩及黑云母矿物学特征

高硅花岗岩对于理解浅部岩浆房的行为具有重要意义.本文对西藏甲玛矿区南坑矿段的花岗斑岩开展了岩相学、岩石地球化学及黑云母矿物学研究.结果显示,该花岗斑岩具有高SiO2(73.39％～77.99％)、高K2O(4.34％～6.45％)和低P2O5(0.03％～0.06％)特征,铝饱和指数为0.97～0.98,富集Rb、Th...     

反向沙丘近地层气流变化及其对沙丘形态的影响

反向沙丘形态-动力学过程是风沙地貌的重要研究内容.选择腾格里沙漠东南缘推平沙地发育的反向沙丘为研究对象,采用二维超声风速仪对沙丘表面5个位置0.25 m和0.5 m高度的气流进行野外观测.结果表明:(1)气流方向影响近地层气流特征.以沙丘脊线垂线为轴,0.25 m高度处沙丘脊线的垂线两侧风向变化不完全对称.当丘顶气流方...     

基于自然资源价值理论的自然岸线价值核算——以辽宁省大连市为例

以自然资源价值理论为指导,构建以使用价值和生态价值为基础的自然岸线资源二元价值结构。结果表明：通过建立自然岸线资源物质量与价值量核算方法,得出大连市自然岸线资源物质总量为766.6 km,全市自然保有率为46.9%。到“十四五”末,大连市海岸线资源价值总量约1 792.88亿元,自然资源岸线价值组成中生态价值占主导地位,价值量占比为99.8%。该核算方法实现了自然岸线资源生态价值的内部化过程,解决了岸线资源的价值以使用价值为主、对生态价值的忽视或考虑不足、导致整体价值被低估的核心问题。过度的资源开发是造成自然岸线资源稀缺的原因,加之资源保护与开发的高质量发展模式,自然岸线资源价值将不断攀高。自然岸线资源价值也将成为沿海地区核心价值的重要组成部分。     

The effect of pore water pressure on tunnel face stability

The kinematic approach in combination with numerical simulation is used to examine the effect of pore water pressure on tunnel face stability. Pore water pressure distribution obtained by numerical calculations using FLAC^3D is used to interpolate the pore water pressure on a 3D rotational collapse mechanism. Comparisons are made to check the present approach against other solutions, showing that the present approach improves the existing upper bound solutions. Results obtained indicate that critical effective face pressure increases with water table elevation. Several normalized charts are also presented for quick evaluation of tunnel face stability. At the end of the paper, the influence of anisotropic permeability on tunnel face stability is also discussed, showing that the isotropic model leads to an overestimation of the necessary tunnel face pressure for anisotropic soils. Copyright © 2016 John Wiley & Sons, Ltd.     

A FUMIGATION DIFFUSION MODEL DURING THE MOUNTAIN-VALLEY WIND SHIFT PERIOD

The fumigation during the mountain-valley wind shift has been first identified as a special type of pol-lutant diffusion using the monitoring measurements of Dukou,Southwest Sichuan,China.Such a pheno-menon occurs frequently all year around but summer,particularly in winter months.A new model for thefumigation during the mountain-valley wind shift period is developed that allows satisfactory explanation ofthe fact.Analyses indicate that the model can more accurately predict not only the high concentration ofPollutants but the time and locality of the occurrence as well.The ground concentration of SO_2 during fumigation is several times up to over a decade higher thanthe daily mean for the whole region,one of the main contamination processes that affect the air quality ofthe city.The medel analyses provide a basis for more effective prediction of the quality and precautionstudy against the disaster.     

大连新港的红粘土及其工程特性的形成

在大连新港油罐区的建设中,发现了一种具有高孔隙性、高含水量、高塑性、中低压缩性的特殊土。作者对这种土及其母岩的矿物学、岩石学、地球化学、物理化学和工程特性进行了系统研究,揭示了该区红粘土及其工程特性的形成机理,该区红粘土乃是蒙脱石化的粗玄岩,在中温带气候区红土花作用的产物。