豫西地区早二叠世碳酸盐岩台地沉积环境及地球化学特征

焦作-禹州地区下二叠统太原组沉积相可划分为5类：开阔台地相、局限台地相、障壁岛相、泻湖-沼泽相和潮坪相,海相碳酸盐岩地层中风暴沉积事件普遍发育。开阔台地主要发育生物碎屑灰岩,生物碎屑含量高且较为破碎,以LREE明显富集,∑REE、(LREE/HREE)N值与Fe含量正相关为特点,反映古水体开阔、动荡且富含生物碎屑和胶体。局限台地主要沉积泥晶灰岩,古水体环境表现为受限、相对安静的特点。研究区太原组下部灰岩段的底部灰岩形成于海侵体系域(TST),生物碎屑含量、∑REE相对较高且轻重稀土无显著分异,Sr/Ba比值小而Ba丰度高;顶部灰岩形成于高水位体系域(HST),显示台地水体逐渐受到限制,陆源控制作用减弱,演化为更加安静低能环境。不同体系域中局限台地灰岩的对比分析,可为恢复南华北二叠纪陆表海盆地古地理特征及演化提供重要资料。     

围限压力下煤岩孔隙度的变化特征及应用

在对30多个煤岩样品在不同围限压力下测得的孔隙度进行研究的基础上,结合煤层甲烷开采的生产特点,讨论了煤岩孔隙度在围限压力下的变化特征。进而探讨了煤岩地下孔隙度的计算方法和煤岩有效孔隙体积压缩系数的变化特征。     

蚌埠隆起区石榴辉石岩变质P-T轨迹的构建

蚌埠隆起区位于华北克拉通东南缘,胶—辽—吉造山带的最南端,主体由五河杂岩组成。前人对该地区的研究主要集中于同位素年代学和变质温压条件研究,其中变质P-T条件研究结果差异较大,以压力变化最为显著,对峰期变质P-T条件缺乏统一认识。本文对蚌埠隆起区石榴辉石岩进行了大量的岩相学、矿物化学成分分析,表明该岩石记录了3期变质作用,其中S-M1和S-M2的矿物组合类似为Grt+Cpx+Opx+Amp+Pl+Ilm,S-M3的矿物组合为Cpx+Amp+Pl+Grt （极边窄带）。结合变质温压条件分析和锆石U-Pb年代学分析,本次主要取得以下几点认识：1）石榴辉石岩WS047-1中记录的3期变质作用,温压条件分别为T-M1 = 616 ℃～647 ℃、P-M1 = 1.03～1.08 GPa,T-M2 = 721 ℃～837 ℃、P-M2 = 1.11～1.29 GPa和T-M3 = 531 ℃～607 ℃、P-M3 = 0.81～0.91 GPa,经历了由较高压力的角闪岩相→中-低麻粒岩相→角闪岩相的变质过程;2）据变质温压条件分析知,蚌埠隆起区具有顺时针的P-T轨迹特征,S-M1→S-M2和S-M2→S-M3分别为近等压升温和近等压降温的缓慢过程;3）石榴辉石岩锆石U-Pb年代学结果主要分为4组：1 839±13 Ma、1 925±31 Ma、2 041±55 Ma和2 762±14 Ma,其中峰值变质年代为1.93～1.84 Ga;4）结合温压条件和锆石U-Pb年代学分析结果,本文认为蚌埠隆起区的P-T轨迹与弗朗西斯科型俯冲或大陆碰撞环境的P-T轨迹较为类似,其应与1.93～1.84 Ga华北克拉通东、西陆块的碰撞拼合及胶—辽—吉造山带形成时限基本吻合。本次研究为深入理解华北克拉通的构造演化特征和蚌埠隆起区的变质作用及演化,提供了大量可靠的科学资料。     

Defining physico-chemical variables, chlorophyll-a and Secchi depth reference conditions in northeast eco-region lakes, China

Establishing reference conditions for regional lakes is necessary to assess human impact on aquatic ecosystems, protect water quality and biotic integrity. The northeast eco-region lakes often present a marked seasonal variability in hydrological, biological and geochemical processes, which could affect physico-chemical variables, chlorophyll-a and Secchi depth reference conditions. Reference conditions were calculated using two different methods: lake population distribution method and trisection method. General physico-chemical reference conditions (pH, conductivity, BOD and nutrients) and chlorophyll-a, and Secchi depth reference conditions were established using the two approaches combined with the analysis of seasonal variability for each parameter for shallow and deep lake types in the northeast eco-region lakes. The results indicated that depth was an important factor affecting physico-chemical variables, chlorophyll-a and Secchi depth reference values. Moreover, the seasonal differences in parameters were also assessed using a non-parametric repeated measure ANOVA (Friedman test) in the shallow and deep lakes. Some parameters showed a seasonal variability for shallow and deep lakes. The least restrictive reference values of the four seasons were proposed to simplify the water quality assessment for regional lake management goals. These results indicated that the 50th percentile (median) value from the best one-third of the nutrient-concentration data distributions is more appropriate for the northeast eco-region lakes.     

静压桩承载力时间效应的研究进展

由于静压桩沉桩后桩周土重塑,静压桩承载力表现出随着休止期的延长而增长的特性。本文从静压桩沉桩后桩周土体内孔隙水消散固结的角度出发,对静压桩承载力时间效应的理论和试验分别进行归纳,结合孔隙水消散路径及固结模型,对桩周土体初始超静孔隙水压力大小及其分布特征进行总结,分析承载力各种测试方法的优缺点,对静压桩承载力的时效性进行深化研究,并探讨了不同地质条件、不同桩的类型对休止期内静压桩承载力的影响,进一步对基于实测数据得出的经验公式进行总结。讨论了基于不同本构关系模型的应力场及位移场解答和沉桩后孔隙水压力消散解答,在此基础上总结了桩基极限承载力理论公式;探讨了黏性土、砂土条件下,考虑超固结比、不排水抗剪强度和塑性指数比对桩基极限承载力系数A的影响,在此基础上归纳了桩基极限承载力经验公式。建议在经验公式基础上设置多重参数,以提升经验公式的精确度,并完善对不同桩、土类型的参数解答;利用BP神经网络,导入静压桩承载力相关参数,以得到针对不同地质条件、桩型、休止期的承载力最优解。     

Public cognition and response to earthquake disaster: from the 2008 Mw7.9 Wenchuan to the 2013 Mw6.6 Lushan earthquakes in Sichuan Province,China

Natural Hazards - China is one of the countries most affected by earthquakes. Improving public cognition and response to earthquake disaster (EDCR) is an effective means to reduce seismic risk and...     

Experimental Study on Mechanical Properties Degradation and Acoustic Emission Characteristics of Coal Rock Caused by CO2 Injection

Geotechnical and Geological Engineering - Geological sequestration of greenhouse gases has gained extensive attentions in recent years, but the degradation law of mechanical parameters and the...     

MC-ICP-MS高精度测定Li同位素分析方法

以不同浓度Li元素标准样品和K、Ca、Na、Mg、Fe单元素标准样品的混合溶液为研究对象,采用3根阳离子交换树脂（AG 50W X8,200~400目）填充的聚丙烯交换柱和石英交换柱对Li进行分离富集,淋洗液分别为28 mol/L HCl、015 mol/L HCl以及05 mol/L HCl 30%乙醇,淋洗液体积小,仅为38 mL。分离回收率高,均大于976%。国际标样AGV 2（相对于IRMM 016）、BHVO 2（相对于IRMM 016）和IRMM 016（相对于L SVEC）的δ7Li值分别为(513±094)‰(2σ,n=10)、(408±060)‰(2σ,n=4)和(0038±073)‰(2σ,n=10),与前人分析结果吻合,分析精度与国际同类实验室水平相当。并对比了马里兰大学同位素实验室和笔者实验室对同种岩石矿物样品的分析结果,在误差范围内具有很好的一致性。此外,对美国地质调查局提供的准标样NKT 1霞石岩（相对于IRMM 016）给出了定值,δ7Li值为(871±046)‰(2σ,n=4)。因此,本方法可用于测定天然样品的Li同位素组成。     

Evaluation of petroleum hydrocarbon biodegradation in shallow groundwater by hydrogeochemical indicators and C, S-isotopes

Biodegradation is one of the main natural attenuation processes in groundwater contaminated with petroleum hydrocarbons. In this work, preliminary studies have been carried out by analyzing the concentrations of total petroleum hydrocarbons (TPH), dissolved inorganic carbon (DIC), dominant terminal electron accepters or donors, as well as δ ¹³C_DIC and δ ³⁴S_SO4, to reveal the biodegradation mechanism of petroleum hydrocarbons in a contaminated site. The results show that along groundwater flow in the central line of the plume, the concentrations of electron acceptors, pH, and E _h increased but TPH and DIC decreased. The δ ¹³C_DIC values of the contaminated groundwater were in the range of ?14.02 to ?22.28 ‰_PDB and ?7.71 to 8.36 ‰_PDB, which reflected a significant depletion and enrichment of ¹³C, respectively. The increase of DIC is believed to result from the non-methanogenic and methanogenic biodegradation of petroleum hydrocarbon in groundwater. Meanwhile, from the contaminated source to the downgradient of the plume, the ³⁴S in the contaminated groundwater became more depleted. The Rayleigh model calculation confirmed the occurrence of bacterial sulfate reduction as a biodegradation pathway of the petroleum hydrocarbon in the contaminated aquifers. It was concluded that stable isotope measurements, combined with other biogeochemical measurements, can be a useful tool to prove the occurrence of the biodegradation process and to identify the dominant terminal electron-accepting process in contaminated aquifers.