Seasonal variation of bromocarbons at Hateruma Island,Japan: implications for global sources

High-frequency measurements of dibromomethane (CH₂Br₂) and bromoform (CHBr₃) at Hateruma Island, in the subtropical East China Sea, were performed using automated preconcentration gas chromatography/mass spectrometry. Their baseline concentrations, found in air masses from the Pacific Ocean, were 0.65 and 0.26 ppt, respectively, in summer and 1.08 and 0.87 ppt, respectively, in winter. Air masses transported from Southeast Asia were rich in bromocarbons, suggesting strong emissions in this area. The passage of cold fronts from the Asian continent was associated with sharp increases in observed concentrations of bromocarbons derived from coastal regions of the continent. Comparison of the relationships between [CH₂Br₂]/[CHBr₃] and [CHBr₃] in the Hateruma Island data with those in monthly mean data from 14 globally distributed U.S. National Oceanic and Atmospheric Administration ground stations suggested that these gases are produced primarily from a common process on a global scale.     

Validation of ADEOS-II GLI ocean color products using in-situ observations

The Global Imager (GLI) aboard the Advanced Earth Observing Satellite-II (ADEOS-II) made global observations from 2 April 2003 to 24 October 2003. In cooperation with several institutes and scientists, we obtained quality controlled match-ups between GLI products and in-situ data, 116 for chlorophyll-a concentration (CHLA), 249 for normalized water-leaving radiance (nLw) at 443 nm, and 201 for aerosol optical thickness at 865 nm (Tau_865) and Angstrom exponent between 520 and 865 nm (Angstrom). We evaluated the GLI ocean color products and investigated the causes of errors using the match-ups. The median absolute percentage differences (MedPD) between GLI and in-situ data were 14.1–35.7% for nLws at 380–565 nm, 52.5–74.8% nLws at 625–680 nm, 47.6% for Tau_865, 46.2% for Angstrom, and 46.6% for CHLA, values that are comparable to the ocean-color products of other sensors. We found that some errors in GLI products are correlated with observational conditions; nLw values were underestimated when nLw at 680 nm was high, CHLA was underestimated in absorptive aerosol conditions, and Tau_865 was overestimated in sunglint regions. The error correlations indicate that we need to improve the retrievals of the optical properties of absorptive aerosols and seawater and sea surface reflection for further applications, including coastal monitoring and the combined use of products from multiple sensors.     

Estimation of property loss and business interruption loss caused by storm surge inundation due to climate change: a case of Typhoon Vera revisit

This paper estimates property loss and business interruption loss under scenarios of storm surge inundation to explore the economic impact of climate change on Ise Bay, Japan. Scenarios-based analyses are conducted with respect to Typhoon Vera, which caused the most severe storm surge in the recorded history of Japan in 1959. Four different hazard scenarios are chosen from a series of typhoon storm surge inundation simulations: Typhoon Vera’s landfall with respect to the condition of the past seawall; Typhoon Vera’s landfall with respect to the condition of the current seawall; intensifying Typhoon Vera, but retaining its original tracks; and intensifying Typhoon Vera, but choosing the worst tracks from various possible typhoon tracks. Our economic loss estimation takes advantage of fine geographical scale census and economic census data that enable us to understand the spatial distribution of property loss and business interruption loss as well as identify the most potentially affected areas and business sectors on a sub-city scale. By comparing the property loss and business interruption loss caused by different hazard scenarios, the effect of different seawalls is evaluated and the economic impact of future climate change is estimated. The results indicate that although the current seawall can considerably reduce the scale of losses, climate change can cause Ise Bay to experience more serious storm surge inundation. Moreover, the resulting economic losses would increase significantly owing to a combination of climate change and the worst track scenario. It is, therefore, necessary to consider more countermeasures to adapt to climate change in this area.     

Evaluation of various satellite sensors for waterline extraction in a coral reef environment: Majuro Atoll, Marshall Islands

The ability of five satellite sensor bands (IKONOS band 4, Terra ASTER bands 3 and 4, and Landsat ETM+ bands 4 and 5) was examined to extract the waterline at coral reef coasts (Majuro Atoll, Marshall Islands) using different wavelength regions (near infrared [NIR] and shortwave infrared [SWIR]) and different spatial resolutions (4, 15, and 30 m). After performing georeferencing and normalization of the images, density slicing was used to extract the waterline. Comparisons of extracted waterline positions with ground-level data for eight transects and global positioning system (GPS) tracks of the island shorelines showed that NIR bands were superior to SWIR bands because of the characteristics of the coral reef coasts, including a lack of foam and suspended sediments (which can affect the NIR wavelength region, if present) and the presence of remnant water on reef flats during low tide (which can affect the SWIR wavelength region). A linear relationship was found between the estimation errors of waterline positions and the spatial resolutions of the NIR sensors. Analysis on estimation errors and image costs showed that Terra ASTER band 3 was the most cost-effective sensor for extracting waterlines with reasonable accuracy. The results serve as general guidelines for using satellite-derived data to estimate intertidal topography and detect and monitor shorelines in coral reef environments.     

Chemostratigraphy of the Ediacaran basinal setting on the Yangtze platform,South China: Oceanographic and diagenetic aspects of the carbon isotopic depth gradient

The Ediacaran Yangtze platform in South China, which represents depositional settings ranging from coastal to basinal, provides valuable information for understanding climate changes and animal evolution during the Ediacaran Period. Although the shallower settings have been investigated, research on the basinal sections has been limited. This has hampered efforts to establish stratigraphic correlations and understand the oceanographic setting of the Yangtze platform. In this paper, the chemostratigraphy of a basinal section at Fengtan, Hunan Province, is reported based on analyses of stable carbon isotope profiles in carbonates (δ¹³C_carb), organic matter (δ¹³C_org), total organic carbon, ⁸⁷Sr/⁸⁶Sr ratios, and Mn, Rb, and Sr concentrations. The basinal section of the Doushantuo Formation, which is represented at Fengtan, provides data supporting regional correlations and oceanography. Three intervals in the Doushantuo Formation are correlated with the Three Gorges: (i) a negative δ¹³C_carb anomaly with stable δ¹³C_org values and altered ⁸⁷Sr/⁸⁶Sr ratios in the lower section can be correlated to the boundary between Doushantuo Members 2 and 3 (Interval A); (ii) a relatively high δ¹³C_carb anomaly with unaltered ⁸⁷Sr/⁸⁶Sr ratios (up to 0.7086) in the middle section corresponding to the lower part of Doushantuo Member 3 (Interval B); and (iii) a negative δ¹³C_carb anomaly with lowered δ values in the upper section can be correlated to the long interval of negative δ¹³C_carb (Interval C). The Gaskiers glaciation is likely represented in Interval A, and Interval C corresponds to the Shuram excursion reported for other Ediacaran localities. Our correlations confirm the depth gradient of δ¹³C_carb in the Yangtze platform and imply that reductive conditions prevailed in the basinal section from the Early to Middle Ediacaran. Under such conditions, anaerobic degradation of organic carbon or methane perturbed the inorganic carbon isotopic compositions and was at least partly responsible for the depth gradient of δ¹³C_carb.     

Distribution of Changjiang Diluted Water detected by satellite chlorophyll-a and its interannual variation during 1998–2007

Sea-viewing Wide Field-of-view Sensor (SeaWiFS) chlorophyll-a distribution in summer in the East China Sea during 1998–2007 was analyzed. Statistical analysis with K-means clustering technique allowed us to define the proper satellite chlorophyll-a concentration indicating the Changjiang Diluted Water (CDW). The spatial distributions of the higher satellite chlorophyll-a concentrations (>0.48 mg m⁻³) corresponded well with the distributions of lower salinity CDW (<30–32) every year. Interannual variation of the CDW area, indicated by the high satellite chlorophyll-a, correlated with the interannual variation of the Changjiang summer freshwater discharge. The correlation analysis indicated that the CDW spread eastward in the East China Sea with a time lag of 1 to 2 months after the discharge.     

Time series of carbonate system variables off Otaru coast in Hokkaido, Japan

We report several biogeochemical parameters (dissolved inorganic carbon (DIC), total alkalinity (TA), dissolved oxygen (DO), phosphate (PO₄), nitrate + nitrite (NO₃ + NO₂), silicate (Si(OH)₄)) in a region off Otaru coast in Hokkaido, Japan on a “weekly” basis during the period of April 2002–May 2003. To better understand the long-term temporal variations of the main factors affecting CO₂ flux in this coastal region and its role as a sink/source of atmospheric CO₂, we constructed an algorithm of DIC and TA using other hydrographic properties. We estimated the CO₂ flux across the air–sea interface by using the classical bulk method. During 1998–2003 in our study region, the estimated fCO_2sea ranged about 185–335 μatm. The maximum of fCO_2sea in the summer was primarily due to the change of water temperature. The minimum of fCO_2sea in the early spring can be explained not only by the change of water temperature but also the change of nutrients and chlorophyll-a. To clarify the factors affecting fCO_2sea (water temperature, salinity, and biological activity), we carried out a sensitivity analysis of these effects on the variation of fCO_2sea. In spring, the biological effect had the largest effect for the minimum of fCO_2sea (40%). In summer, the water temperature effect had the largest effect for the maximum of fCO_2sea (25%). In fall, the water temperature effect had the largest effect for the minimum of fCO_2sea (53%). In winter, the biological effect had the largest effect for the minimum of fCO_2sea (35%).We found that our study region was a sink region of CO₂ throughout a year (−0.78 mol/m²/yr). Furthermore, we estimated that the increase of fCO_2sea was about 0.56 μatm/yr under equilibrium with the atmospheric CO₂ content for the period 1998–2003, with the temporal changes in the variables (T, S, PO₄) on fCO_2sea, thus as the maximum trend of each variable on fCO_2sea was 0.22 μatm/yr, and the trend of residual fCO₂ including gas exchange was 0.34 μatm/yr. This result suggests that interaction among variables would affect gas exchange between air and sea effects on fCO_2sea. We conclude that this study region as a representative coastal region of marginal seas of the North Pacific is special because it was measured, but there is no particular significance in comparison to any other area.     

Seasonal transition of hydrological processes in a slow‐moving landslide in a snowy region

A comprehensive understanding of seasonal hydrological dynamics is required to describe the influence of pore‐water pressure on the stability of landslides in snowy regions. This study reports on the results of continuous meteorological and hydrological observations over 2 years on a landslide body comprising Neogene sedimentary rocks in northern Japan, where a thick (3–5 m) seasonal snowpack covers the land surface. Monitoring of the volumetric water content in shallow unsaturated zones (<0.8 m depth) and pore‐water pressure in saturated bedrock at depths of 2.0 and 5.2 m revealed clear seasonality in hydrological responses to rainfall and meltwater supply. During snow‐free periods, both the shallow soil moisture and deep pore‐water pressure responded rapidly to intense rainwater infiltration. In contrast, during snowmelt, the deep pore pressure fluctuated in accordance with the daily cycle of meltwater input, without notable changes in shallow moisture conditions. During occasional foehn events that cause intense snow melting in midwinter, meltwater flows preferentially through the layered snowpack, converging to produce a localized water supply at the ground surface. This episodically triggers a significant rise in pore‐water pressure. The seasonal differences in hydrological responses were characterized by a set of newly proposed indices for the magnitude and quickness of increases in the pressure head near the sliding surface. Under snow‐covered conditions, the magnitude of the pressure increase tends to be suppressed, probably owing to a reduction in infiltration caused by a seasonal decrease in the permeability of surface soils, and effective pore‐water drainage through the highly conductive colluvial layer. Deep groundwater flow within bedrock remained in a steady upwelling state, enhanced by increasing moisture in shallow soils under snow cover, reflecting the convergence of subsurface water from surrounding hillslopes.     

Organohalogen and organotin compounds in killer whales mass-stranded in the Shiretoko Peninsula, Hokkaido, Japan

Blubber and liver samples were obtained for analysis of wide ranges of contaminants from killer whales (Orcinus orca) which were locked away in drifting sea ice on the coast of Rausu, the Shiretoko Peninsula in Eastern Hokkaido, Japan in February 2005. Among the organohalogen compounds analyzed, DDTs were the predominant contaminants with concentrations ranging from 28 to 220 microg/g on a lipid-weight basis followed by PCBs and other organochlorine pesticides. PBDEs levels were two or three orders of magnitude lower than those of PCBs and DDTs. 2,3,7,8-Tetrachlorodibenzo-p-dioxin toxic equivalents (TEQs) derived by WHO mammal-TEF in killer whales were in the range of 110-440 pgTEQ/g. Mono-ortho coplanar PCBs contributed to 75-98% of total TEQs, indicating coplanar PCBs are significant contaminants for risk assessment in this species. The fact that hepatic residue levels of butyltins (from 13 to 770 ng/g wet weight) were much higher than those of phenyltins may be reflecting extensive use of tributyltin as antifouling paint.