Silicon flux and distribution of biogenic silica in deep-sea sediments in the western North Pacific Ocean

We investigated biogenic silica, several biological components, and silicate in pore-water in the abyssal sediment to determine silicon flux of western North Pacific during several cruises. The surficial sediment biogenic silica content was high at high latitudes with the boundary running along the Kuroshio Extension, and maximum values (exceeding 20%) were found in the Oyashio region. In the subtropical region to the south, most stations showed less than 5% biogenic silica content. This distribution pattern reflected primary production and ocean currents in the surface layer very well. Pore-water samples were collected from 4 stations along the east coast of Japan. The highest asymptotic silicic acid concentration (670 μmol L^?1) in pore-water was observed at the junction of Kuroshio and Oyashio, followed by samples from the Oyashio region. It is at the southern station that the lowest value (450 μmol L^?1) was observed, and the primary production is low under the influence of Kuroshio there. The diffusive flux followed the same geographic trend as the asymptotic silicic acid concentrations did, ranging 77–389 mmol m^?2 yr ^?1. Multiple sampling of pore-water was conducted throughout the year at one station at high latitude. The average annual biogenic silica rain flux observed using sediment traps was 373 mmol m^?2 yr^?1; the diffusive flux and burial flux at the sediment–water interface were 305 and 9 mmol m^?2 yr^?1, respectively. We concluded that most of the settling silica particles dissolved and diffused at the sediment–water interface and approximately 3% only were preserved in this area. In addition, the obvious time lag observed between the peak rain flux and the maximum diffusive flux suggested that primary production in the surface layer has a great influence on the sedimentation environment of abyssal western North Pacific. These transitions of Si flux at the sediment–water interface were considerably greater in northwestern North Pacific than in southwestern North Pacific. In addition, a station in the Philippine Sea indicated high biogenic silica content because of Ethmodiscus ooze, which are scattered randomly on the sea floor in the subtropical region.     

Holocene coastal uplift in the western Pacific Rim in the context of late Quaternary uplift

This paper reviews recent studies of Holocene coastal uplift in tectonically active areas near the plate boundaries of the western Pacific Rim. Emergent Holocene terraces exist along the coast of North Island of New Zealand, the Huon Peninsula of Papua New Guinea, the Japanese Islands, and Taiwan. These terraces have several features in common. All comprise series of subdivided terraces. The highest terrace is a constructional terrace, underlain by estuarine or marine deposits, and the lower terraces are erosional, cutting into transgressive deposits or bedrock. The highest terrace records the culmination of Holocene sea-level rise at ca. 6–6.5 ka BP. Lower terraces were coseismically uplifted. Repeated major earthquakes have usually occurred at ka intervals and meter-scale uplift. The maximum uplift rate and number of terraces are surprisingly similar, about 4 m/ka and seven to four major steps in North Island, Huon Peninsula, and Japan. Taiwan, especially along the east coast of the Coastal Range, is different, reaching a maximum uplift rate of 15 m/ka with 10 subdivided steps. They record a very rapid uplift. Comparison between short-term (Holocene) and long-term since the last interglacial maximum (sub-stage 5e) uplift rates demonstrates that a steady uplift rate (Huon Peninsula) or accelerated uplift toward the present (several areas of Japan and North Island) has continued at least since isotope sub-stage 5e. Rapid uplift in eastern Taiwan probably started only in the early Holocene, judging from the absence of any older marine terraces. Most of the causative faults for the coastal uplift may be offshore reverse faults, branched from the main plate boundary fault, but some of them are onshore faults, which deformed progressively with time.     

Review of paleoseismological and active fault studies in Taiwan in the light of the Chichi earthquake of September 21, 1999

This paper reviews the research on active and earthquake faults in Taiwan conducted prior and after the 1999 Chichi earthquake. The Chichi earthquake plays as a turning point of the relevant studies, since the 1999 coseismic surface rupture exactly follows preexisting fault scarps, created in turn by previous seismic events along the Chelungpu Fault. This fact indicates that the precise mapping on the other active faults is fundamental to predict the location of surface rupture caused by large future earthquakes. Since 1999, many trenching studies have been carried out along the Chichi earthquake fault. A few of them demonstrates that the penultimate event is as young as probably only 200–430 years old; however, some others show a rather old age of several hundreds years or even older for the last faulting event before 1999. More trenching studies are necessary for such a long fault in order to understand the possible segmentation features and the correlation of the paleoseismic events identified along the entire fault length. In addition, we further discuss the offshore faulting associated with seismic event along the eastern coast of Taiwan, where the multiple Holocene terraces are well known.     

Effect of the contraction of Zn-O bonds on X-ray emission spectra

Physics and Chemistry of Minerals - The X-ray emission spectra were measured for tetrahedrally coordinated Zn ion in several synthetic compounds. Intensity ratios of L β and L α spectral...     

Effects of coastal erosion on landslide activity revealed by multi-sensor observations

Coastal erosion is becoming an increasingly serious consequence of climate change. This study demonstrates the effects of coastal erosion on landslide activity while considering the amount of erosion and changes in pore water pressure. To determine the factors related to landslide slip generation, we specifically measured the displacement, deformation, pore water pressure, and amount of erosion with high temporal resolution (1 s–1 h) for a coastal landslide in Hokkaido, north-eastern Japan, for 7 months. It has been determined that landslides occur simultaneously with high pore water pressure. Toe erosion events also occurred several times, while the landslide exhibited major displacement. Because toe erosion and the increase in pore water pressure occurred simultaneously, we tried to determine which of the two contributed majorly to the landslide displacement by conducting a stability analysis that incorporates the effects of the two factors. From the actual observed data, toe erosion and the increase in pore water pressure had comparable effects on the destabilization of the studied landslide. Specifically, the time series for the safety factor shows that the landslide in the case with toe erosion was destabilized more than that in the case with no erosion, with a difference of more than 5% in the safety factor. The model with toe erosion provided a better explanation for the landslide displacement. Furthermore, the inclination data suggested that erosion took place at least 1 month before the landslide displacement. This implied that coastal erosion played a role in the preparation and ongoing displacement of the coastal landslide. Inland landslides with toes that are subject to undercutting due to river incision or artificial construction have geomorphological settings that are similar to those of the studied landslide. The knowledge obtained here can contribute to the understanding of destabilization mechanisms and terrain changes related to such landslides. © 2020 John Wiley & Sons, Ltd.     

A regression model-based method for indoor positioning with compound location fingerprints

ABSTRACT

This paper proposed and evaluated an estimation method for indoor positioning. The method combines location fingerprinting and dead reckoning differently from the conventional combinations. It uses compound location fingerprints, which are composed of radio fingerprints at multiple points of time, that is, at multiple positions, and displacements between them estimated by dead reckoning. To avoid errors accumulated from dead reckoning, the method uses short-range dead reckoning. The method was evaluated using 16 Bluetooth beacons installed in a student room with the dimensions of 11 × 5 m with furniture inside. The Received Signal Strength Indicator (RSSI) values of the beacons were collected at 30 measuring points, which were points at the intersections on a 1 × 1 m grid with no obstacles. A compound location fingerprint is composed of RSSI vectors at two points and a displacement vector between them. Random Forests (RF) was used to build regression models to estimate positions from location fingerprints. The root mean square error of position estimation was 0.87 m using 16 Bluetooth beacons. This error is lower than that received with a single-point baseline model, where a feature vector is composed of only RSSI values at one location. The results suggest that the proposed method is effective for indoor positioning.     

Single particle analysis of oceanic suspended matter during the SEEDS II iron fertilization experiment

Suspended particles collected from surface seawater during the SEEDS II (Subarctic Iron Experiment for Ecosystem and Dynamics Study II) experiment were analyzed individually using an electron probe X-ray micro analyzer and characterized by size and elemental composition. Their numbers, relative abundances, and relative particle volume all showed clear differences between samples collected inside vs. outside the phytoplankton bloom that developed following the addition of iron. Throughout the study, Si-rich, Ca-rich and Organic particles were dominant and their number increased inside the fertilized patch; these particles accounted for 21%, 13% and 58% of the particles examined, respectively. Si-rich or Ca-rich particles commonly consisted of fragments of diatom frustules and coccolithophorids. There was consistently greater percentage of Ca-rich particles and lower percentage of Si-rich particles inside the patch than outside of it in number, but both types of these particles apparently occupied a larger volume inside the patch than outside of it. Organic particles, that showed having peaks in smaller diameter particles, increased apparently inside the patch with time after iron fertilization. The Organic particles had a more diverse mixture of both bio-related and crustal trace elements than the other types of particles. These results suggest that the increase in suspended particles following the iron enrichment was due to a combination of detrital material and live phytoplankton.     

Rapid precipitation of amorphous silica in experimental systems with nontronite (NAu-1) and Shewanella oneidensis MR-1

Nanometer-size (<50 nm) precipitates of amorphous silica globules were observed in laboratory systems containing nontronite NAu-1, Shewanella oneidensis strain MR-1, and lean aqueous media. Their formation was attributed to the release of polysilicic acids at the expense of dissolving NAu-1, and subsequent polymerization and stabilization mediated by biomolecules. Rapid (<24 h) silica globule formation was confirmed in the immediate vicinity of bacterial cells and extracellular polymeric substances in all experimental systems that contained bacteria, whether the bacteria were respiring dissolved O₂ or Fe(III) originating from NAu-1, and whether the bacteria were viable or heat-killed. Silica globules were not observed in bacteria- and biomolecule-free systems. Thermodynamic calculations using disilicic acid, rather than monomeric silica, as the primary aqueous silica species suggest that the systems may have been supersaturated with respect to amorphous silica even though they appeared to be undersaturated if all aqueous silica was assumed to be monomeric H₄SiO₄. The predominant aqueous silica species in the experimental systems was likely polysilicic acids because aqueous silica was continuously supplied from the concurrent dissolution of aluminosilicate. Further polymerization and globule formation may have been driven by the presence of polyamines, a group of biologically produced compounds that are known to drive amorphous silica precipitation in diatom frustules. Globules were likely to be positively charged in our systems due to chemisorption of organic polycations onto silica surfaces that would have been otherwise negatively charged. We propose the following steps for the formation of nanometer-size silica globules in our experimental systems: (i) continuous supply of polysilicic acids due to NAu-1 dissolution; (ii) polysilicic acid polymerization to form <50 nm silica globules and subsequent stabilization mediated by microbially produced polyamines; (iii) charge reversal due to chemisorption of organic polycations; and (iv) electrostatic attraction of positively charged silica globules to net negatively charged bacterial cells. Rapid, biogenic precipitation of silica may be common in soil and sediment systems that appear to be undersaturated with respect to amorphous Si.     

Diamond xenolith and matrix organic matter in the Sutter's Mill meteorite measured by C‐XANES

The Sutter's Mill (SM) meteorite fell in El Dorado County, California, on April 22, 2012. This meteorite is a regolith breccia composed of CM chondrite material and at least one xenolithic phase: oldhamite. The meteorite studied here, SM2 (subsample 5), was one of three meteorites collected before it rained extensively on the debris site, thus preserving the original asteroid regolith mineralogy. Two relatively large (10 μm sized) possible diamond grains were observed in SM2‐5 surrounded by fine‐grained matrix. In the present work, we analyzed a focused ion beam (FIB) milled thin section that transected a region containing these two potential diamond grains as well as the surrounding fine‐grained matrix employing carbon and nitrogen X‐ray absorption near‐edge structure (C‐XANES and N‐XANES) spectroscopy using a scanning transmission X‐ray microscope (STXM) (Beamline 5.3.2 at the Advanced Light Source, Lawrence Berkeley National Laboratory). The STXM analysis revealed that the matrix of SM2‐5 contains C‐rich grains, possibly organic nanoglobules. A single carbonate grain was also detected. The C‐XANES spectrum of the matrix is similar to that of insoluble organic matter (IOM) found in other CM chondrites. However, no significant nitrogen‐bearing functional groups were observed with N‐XANES. One of the possible diamond grains contains a Ca‐bearing inclusion that is not carbonate. C‐XANES features of the diamond‐edges suggest that the diamond might have formed by the CVD process, or in a high‐temperature and ‐pressure environment in the interior of a much larger parent body.