云南地区GPS基准站噪声模型分析

以云南地区陆态网27个全球定位系统(GPS)基准站在2011-2017年不同时间跨度的观测数据为例,使用赤池信息量和贝叶斯信息量估计准则(AIC/BIC)对解算结果进行分析,从而确定其最优有色噪声模型.结果表明,不同时间跨度基准站各坐标分量上噪声特性主要体现为白+闪烁噪声(WN+FN)、幂律噪声(PL)模型组合.部分基准站在北向和垂向的最优噪声模型会随着观测时间的累积而改变,PL模型所占比例有所下降,WN+FN模型所占比例有所上升.当时间跨度大于5 a时,基准站噪声模型的稳定性显著提高.随着坐标时间序列积累时长的增加,未知噪声分量出现的可能性也相应提高.     

Sr isotope evolution during chemical weathering of granites —Impact of relative weathering rates of minerals

The Sr isotopic systematics in the weathering profiles of biotite granite and granite porphyry in southern Jiangxi Province were investigated. The results showed that during the chemical weathering of granites, remarked fractionation occurred between Rb and Sr. During the early stages of chemical weathering of granites, the released Sr/Si and Sr/Ca ratios are larger than those of the parent rocks, and the leaching rate of Sr is higher than those of Si, Ca, K, Rb, etc. Dynamic variations in relative weathering rates of the main Sr-contributing minerals led to fluctuation with time in⁸⁷Sr/⁸⁶Sr ratios of inherent and released Sr in the weathering crust of granite. Successive weathering of biotite, plagioclase and K-feldspar made⁸⁷Sr/⁸⁶Sr ratios in the weathering residues show such a fluctuation trend as to decrease first, increase, and then decrease again till they maintain stable. This work further indicates that when Sr isotopes are used to trace biogeochemical processes on both the catchment and global scales, one must seriously take account of the preferential release of Sr from dissolving solid phase and the fluctuation of⁸⁷Sr/⁸⁶Sr ratios caused by the variations of relative weathering rates of Sr-contributing minerals.     

Sr isotope evolution during chemical weathering of granites -- impact of relative weathering rates of minerals

The Sr isotopic systematics in the weathering profiles of biotite granite and granite porphyry in southern Jiangxi Province were investigated. The results showed that during the chemical weathering of granites, remarked fractionation occurred between Rb and Sr. During the early stages of chemical weathering of granites, the released Sr/Si and Sr/Ca ratios are larger than those of the parent rocks, and the leaching rate of Sr is higher than those of Si, Ca, K, Rb, etc. Dynamic variations in relative weathering rates of the main Sr-contributing minerals led to fluctuation with time in 87Sr/86Sr ratios of inherent and released Sr in the weathering crust of granite. Successive weathering of biotite, plagioclase and K-feldspar made 87Sr/86Sr ratios in the weathering residues show such a fluctuation trend as to decrease first, increase, and then decrease again till they maintain stable. This work further indicates that when Sr isotopes are used to trace biogeochemical processes on both the catchment and global scales, one must seriously take account of the prefer-ential release of Sr from dissolving solid phase and the fluctuation of 87Sr/86Sr ratios caused by the variations of relative weathering rates of Sr-contributing minerals.     

热带印度洋海温的年际变化与ENSO

文中讨论了热带印度洋海表温度距平空间分布的年际变化与赤道中东太平洋海温的关系。EOF分析的结果表明 ,印度洋海温的变化主要存在全区符号一致的单极型和西部与东南部符号相反的偶极型 ,它们具有显著的年际变化。小波凝聚谱揭示了单极、偶极的变化与Nino3区海表温度距平存在密切关系 ,印度洋海温距平从偶极到单极的变化对应着ElNi no事件从发展到衰减的过程。平均而言 ,印度洋偶极超前Nino3区海温距平约 4个月 ,单极滞后约 6个月。整个热带印度洋 -太平洋地区海气耦合特征的演变表明 ,与ElNino从发展到衰减相联系的热带西太平洋海气耦合相互作用在印度洋海温距平从偶极到单极的演变过程中起着非常重要的作用。     

The Second Modified Perpendicular Drought Index (MPDI1): A Combined Drought Monitoring Method with Soil Moisture and Vegetation Index

Since soil moisture and vegetation index are direct and important indicators for surface drought status, a new drought monitoring method (MPDI1) is developed in NIR-Red reflectance space. It is a combination of two satellite-derived variables—a soil moisture component using the Perpendicular Drought Index (PDI), and a vegetation component using the Perpendicular Vegetation Index (PVI). Enhanced Thematic Mapper Plus (ETM+) image and in-situ ground observation are introduced to validate the accuracy of the proposed method. Results indicate that MPDI1 is highly consistent to the in-situ ground observation with the coefficient of determination (R²?=?0.49) between MPDI1 and 5–20 cm mean soil moisture, which is slightly higher than the coefficient of determination (R²?=?0.42) between MPDI1 and 10 cm soil moisture. Compared with drought indices such as PDI and the Modified Perpendicular Drought Index (MPDI), MPDI1 provides quite similar trends for bare soil or lower vegetated surface, but it demonstrates a better performance in measuring densely vegetated surface. This paper concludes that MPDI1 provides correct and sufficient information on surface drought status in soil-plant continuum, which appears to have robust available and great potential for surface drought estimation in China and other countries.     

高层建筑荷载引发地面沉降与隆起变形三维数值模拟

针对地下水埋深较浅地区,由高层建筑荷载引起的土体变形问题,以比奥固结理论为基础,结合土体非线性流变理论,将土体本构关系推广到黏弹塑性;同时考虑土体力学参数及水力参数的动态变化关系,建立了高层建筑荷载引发地面沉降与隆起变形的三维有限元数值模型,详细研究了高层建筑荷载影响下的土体变形特征及此过程中土体力学参数及水力学参数的变化特征。结果表明：由高层建筑荷载引起的地面沉降呈现漏斗状,以建筑物中心为漏斗中心,高层建筑荷载施加初期,高层建筑周围出现隆起,到达最大值后隆起逐渐消失;高层建筑底部浅层土体孔隙度、渗透系数及泊松比均呈现缓慢减小趋势,弹性模量呈现缓慢增大趋势;而高层建筑周围浅层土体的孔隙度、渗透系数及泊松比呈现先增大后减小的变化趋势,弹性模量则呈现先减小后增大的变化趋势;高层建筑影响区域浅部土体参数的变化趋势与土体的回弹及压缩有关。     

中国及邻区印支运动特征及其意义

通过概要论述印支运动在中国及邻区的表现特征,探讨了印支运动的主要成矿作用,指出印支运动首次使长期以来游离于全球主要大陆外的扬子、中朝、塔里木等小陆块拼合在一起,为新生代大型聚煤盆地的形成奠定了基础,也为燕山期和喜马拉雅山期二次大规模的对流地幔输入大陆事件奠定了重要基础,使之成为中国及邻区大陆上最重要的成矿时期。     

Zero-valent iron/persulfate(Fe0/PS) oxidation acetaminophen in water

Zero-valent iron (Fe⁰), as an alternative iron source, was evaluated to activate persulfate (PS) to degrade acetaminophen (APAP), a representative pharmaceutically active compound in water. Effects of key factors in the so-called Fe⁰/PS process, including Fe⁰ dosage, initial pH, temperatures and chelating agents, were studied. Under all the conditions tested, the APAP degradation followed a pseudo-first-order kinetics pattern. The degradation efficiency of APAP was highest when the Fe⁰ to PS molar ratio increased to 1:1, and the degradation rate constant and removal were 23.19 × 10^?3 min^?1 and 93.19 %, respectively. Comparing with Fe²⁺, Fe⁰ served as an alternative iron source that can gradually release Fe²⁺ into water, thereby consistently activating PS to produce sulfate radicals. The Fe⁰/PS system was effective in a broader pH range from 3 to 8.5. Heat could facilitate production of sulfate radicals and enhance the APAP degradation in the Fe⁰/PS system. High reaction temperature also improved the Fe²⁺/PS oxidation of APAP. Finally, sodium citrate (a chelating agent) at an appropriate concentration could improve the APAP degradation rate in the Fe²⁺/PS and Fe⁰/PS system. The optimal molar ratio of Fe⁰ to citrate depended on solution pH. Our results demonstrated that Fe⁰ was an alternative iron source to activate PS to degrade APAP in water.     

苏北榴辉岩的稀土元素地球化学及其成因讨论

江苏北部的榴辉岩出露于东海群变质岩系中，榴辉岩的产状是：１）呈似层状或透镜状产于东海群片麻岩中；２）呈不规则团块状产于超镁铁岩中，或与超镁铁岩伴生。全岩分析表明，前者相当橄榄拉斑玄琥岩或石英拉斑玄武岩，后者相当橄榄玄武岩或橄榄拉斑玄武岩。     

Distribution Characteristics of Gold and Other Trace Elements in the Proterozoic Lengjiaxi Group,Northeastern Hunan Province

Systematic geochemical studies of the Proterozoic Lengjiaxi Group in northeastern Hunan Province suggest that the Lengjiaxi Group is a Au-As-Sb-W association-type Au-bearing turbidite formation.The contents of Au,As,Sb,W,Cr,Mn,Pb and Zn in the turbidite formation are more than two times as high as the average contents of trace elements in the upper continental crust.The low abundance of Ag and the close correlation between Au and As are two important characteristic features.In the Au-bearing turbidite formation the enrichment of gold is due to the extensive occurrence of Au-bearing pyrites.Higher contents of Au,W,Sb and Ag in the greywacke indicate that they also exist in the form of heavy minerals.Au,Ag,As,Sb,W and REE in the Au-bearing turbidite formation have a close genetic relation with the chemistry of the gold deposits.