2-D crustal Poisson’s ratio from seismic travel time inversion in Changbaishan Tianchi volcanic region

Based on the inversion method of 2D velocity structure and interface, the crustal velocity structures of P-wave and S-wave along the profile L ₁ are determined simultaneously with deep seismic sounding data in Changbaishan Tianchi volcanic region, and then its Poisson’s ratio is obtained. Calculated results show that this technique overcomes some defects of traditional forward calculation method, and it is also very effective to determine Poisson’s ratio distribution of deep seismic sounding profile, especially useful for study on volcanic magma and crustal fault zone. Study result indicates that there is an abnormally high Poisson’s ratio body that is about 30 km wide and 12 km high in the low velocity region under Tianchi crater. Its value of Poisson’s ratio is 8% higher than that of surrounding medium and it should be the magma chamber formed from melted rock with high temperature. There is a high Poisson’s ratio zone ranging from magma chamber to the top of crust, which may be the uprise passage of hot substance. The lower part with high Poisson’s ratio, which stretches downward to Moho, is possibly the extrusion way of hot substance from the uppermost mantle. The conclusions above are consistent with the study results of both tomographic determination of 3D crustal structure and magnetotelluric survey in this region. Foundation item: Key Project from China Earthquake Administration and the Project (95-11-02-01) from Ministry of Science and Technology (2001DIA10003). Contribution No. RCEG200401, Geophysical Exploration Center, China Earthquake Administration.     

Major reactive species of ambient volatile organic compounds (VOCs) and their sources in Beijing

Volatile organic compounds (VOCs) are important precursors of atmospheric chemical processes. As a whole mixture, the ambient VOCs show very strong chemical reactivity. Based on OH radical loss rates in the air, the chemical reactivity of VOCs in Beijing was calculated. The results revealed that alkenes, accounting for only about 15% in the mixing ratio of VOCs, provide nearly 75% of the reactivity of ambient VOCs and the C4 to C5 alkenes were the major reactive species among the alkenes. The study of emission characteristics of various VOCs sources indicated that these alkenes are mainly from vehicle exhaust and gasoline evaporation. The reduction of alkene species in these two sources will be effective in photochemical pollution control in Beijing.     

Anisotropy from full waveform inversion of multicomponent seismic data using a hybrid optimization method

Seismic waveforms contain valuable information about the media, but the waveform inversion is a non‐linear problem. We present a waveform inversion method that combines a local optimization method with a genetic algorithm to determine the anisotropic parameters of a horizontally stratified medium. Synthetic seismograms for a horizontally stratified anisotropic medium are calculated using the reflectivity technique. In the initial stage of the inversion, the global space‐sampling properties of the genetic algorithm are used to direct the search to the region close to the global solution. This solution is then further improved using a conjugate‐gradient method. The numerical experiments performed with noisy synthetic data show that our hybrid optimization method satisfactorily reconstructs the anisotropic parameters at a reasonable computing cost while the range of slowness is adequate. We found that (i) for small‐angle data neither single‐ nor multiple‐component data are sufficient to determine the anisotropic parameters uniquely; (ii) for medium‐angle data the multiple‐component data are sufficient to determine the anisotropic parameters exactly whereas the single‐component data are not sufficient; and (iii) for wide‐angle data, either single‐ or multiple‐component data are sufficient to determine the anisotropic parameters accurately.     

致密砂岩的形成机制及其地质意义——以塔里木盆地英南2井为例

砂质岩的孔隙和喉道被网格状粘土矿物和次生加大矿物充填成微细孔喉状结构时,形成具有较高毛细管压力的致密砂岩。它与地层水发生水锁效应,可大大降低渗透率,成为致密砂岩盖层。当含水饱和度在50%以下时,束缚水饱和度比较低,致密砂岩储层可以产气;当含水饱和度在50%～90%区间时,具有较高的束缚水饱和度,相对渗透率非常低,它既不能产气也不能产水,反映为渗透率瓶颈区(具有盖层性质);当含水饱和度大于90%以上时,致密砂岩储层仅微量产水。塔里木盆地英南2井侏罗系气藏盖层由致密砂岩构成,不含水时的气体渗透率在(0.027～0.081)×10-3μm2,不能构成封堵;当含水饱和度达到60%以上时,相对渗透率几乎为零,构成有效盖层。     

深基坑支护方案的分析与优化

针对武汉市南湖岸边复杂的地质条件及周边环境,在某高层建筑的深基坑支护结构设计中,结合实际因地制宜地对基坑的支护方法进行了分析比较。支护效果及实测数据表明,该工程所采用的混合式支护实施方案技术安全可靠,经济合理,可为同类型基坑工程设计提供借鉴。     

黄土塬区地震勘探测量方法研究

黄土塬区地形地貌复杂,地震勘探测量施工困难：一是GPS参考站如何布设;二是在大落差等特殊地形区域的GPS测量作业如何实施;三是在GPS作业盲区测量作业如何实现.针对以上难点,提出了三种测量施工方法：一是分阶段,逐步加密控制点进行工区内GPS参考站的布设;二是通过增加参考站电台天线的高度、发展多个参考站或使用中继站来解决GPS参考站主站信息覆盖不到区域的实测问题;三是通过全站仪、测绳等常规测量方法来实现GPS作业盲区物理点的逐点实测.应用以上测量方法,可有效解决地震勘探测量在黄土塬区遇到的问题,实现黄土塬区物理点的逐点实测.     

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.