Geochemical Evidence for Subduction Fluxes, Mantle Melting and Fractional Crystallization Beneath the South Sandwich Island Arc

The volcanoes of the South Sandwich island arc follow threedistinct series: low-K tholeiitic (followed by Zavodovski, Candlemas,Vindication, Montagu and Bristol), tholeiitic (followed by Visokoi,Saunders and Bellinghausen) and calcalkaline (followed by Leskov,Freehand and part of Cook and Thule). Flux calculations indicatethat the percentage contribution of the subduction componentto the mantle source of all three series varies from undetectable(e.g. Zr) through small (e.g. Nd=20%) and moderate (e.g. La,Ce, Sr=50–80%) to dominant (e.g. Pb, K, Ba, Rb, Cs >90%)with little change along the arc. Isotope systematics (Pb, Nd,Sr) show that this subduction component obtains a greater contributionfrom altered oceanic crust than from pelagic sediment. Elementsfor which the subduction contribution is small show that themantle is already depleted relative to N-MORB mantle (equivalentto loss of an 2•5% melt fraction) before melting beneaththe arc. After addition of the subduction component, dynamicmelting of this depleted mantle then causes the variations inK that distinguish the three series. The estimated degree ofpartial melting (20%) is slightly greater than that beneathocean ridges, though geothermometry suggests that the primarymagma temperature (1225C) is similar to that of primary MORB.About half of the melting may be attributed to volatile addition,and half to decompression. Dynamic melting involving three-dimensional,two-phase flow may be needed to explain fully the inter-islandvariations. KEY WORDS: geochemistry; petrology; fluxes; melting; subduction ^*Corresponding author     

Structural Variations of Bottom Sediments in the Rybinsk Reservoir

Long-standing variations in the structure of bottom sediments within typical habitats of the aquatic life are characterized using the Volzhskii Pool of the Rybinsk Reservoir as an example. The role of hydrodynamic processes of the littoral zone in the formation of the ground complex of shallow water areas of the pool is discussed. The trends in variation in the quality of bottom substrate in fish habitats are analyzed. The peculiarities of long-standing variations in the distribution of types of bottom sediments in the entire reservoir are shown.     

On a homogeneous representation of seismic history in large regions

The possibility to obtain a more complete and unbiased long-term history of seismic shakings over large territories than is explicitly reported from inhabited localities is discussed in the paper. An approach proposed for this purpose consists in complementing the spatial distribution of the macroseismic effect of earthquakes by calculated intensities at localities where information on felt shakings is absent. The calculated intensity is obtained on the basis of data on the epicentral intensity and location of epicenters provided by earthquake catalogs. This approach is applied to the analysis of the history of seismic shaking in Spain. The calculated intensities are shown to be comparable in accuracy with the ordinary practice of intensity determinations at national seismological centers.     

Two tiltmeters and an integrating seismometer for the monitoring of volcanic activity, and the results of some trials on Mount Etna

Two types of continuously recording tiltmeter and a new “integrating seismometer” were tested on Etna during the period September to December 1976. The primary object was the investigation of techniques for the surveillance and prediction of volcanic activity, but some information on the internal structure and mechanism of Etna was also obtained. It was concluded that a network of tiltmeters combined with seismic monitoring (using standard and/or integrating seismometers) offers the best dual approach to the problem of determining the true state of dormant volcanoes, and predicting the date and site of possible future eruptions.     

Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Late Holocene paleoecology of the Southern Plains

Analyses of pollen and land snails from rocksheter sites in the Osage Hills of northeastern Oklahoma indicate that the period 2000-1000 yr B.P. was moister than today. During that time, colonies of the prairie vole Microtus ochrogaster were present in the Texas Panhandle. About 1000 yr B.P. the climate changed to dry conditions that have persisted to the present. Disjunct colonies of small mammals in Texas became extinct at the beginning of the dry episode, thereby establishing the composition of the modern fauna. The climatic model for the origin of the Panhandle Aspect (A.D. 1200–1500) is questioned on the grounds that the Southern Plains experienced a long period of dry climate commencing A.D. 950.     

A GEOGRAPHIC INFORMATION SYSTEM FOR PHYSICAL-GEOGRAPHIC REGIONALIZATION

The design and functioning of a geographic information system established for the purpose of objectively delineating the boundaries of major physical geographic regions in the USSR is described. The basic components include an information input block for data collection and preliminary image processing; a recognition block for feature classification and analysis; a data base management system providing for repeated revision, addition, and use of spectral information; and a block for displaying results of processing in various forms. Applications of the system are demonstrated in the mapping of physical regions in a steppe and semi-desert area of the southern USSR. Translated from: Izvestiya Akademii Nauk SSSR, seriya geograficheskaya, 1988, No. 2, pp. 89-94.     

Analyses of pre-injection reservoir data for stable carbon isotope trend predictions in CO2 monitoring: preparing for CO2 injection

Baseline monitoring at the proposed enhanced gas recovery site in Altmark (Germany) was carried out in combination with theoretical and laboratory investigations to describe and predict the principles of expected stable carbon isotope and dissolved inorganic carbon (DIC) trends during CO₂ injection in reservoirs. This provides fundamental data for site-specific characterisation for monitoring purposes. Baseline ??¹³C values at the Altmark site ranged between ?1.8 and ?11.5??? and DIC values were about 2?mmol?L^?1. These baseline values form the basis for a theoretical study on the influences of the ambient reservoir conditions on the state of geochemical and isotope equilibrium of the reservoir fluids. Transferring this theoretical study to the Altmark site enables predictions on geochemical trends during potential injection. Assuming that CO₂ would be injected at the Altmark site to pCO₂?=?100?bar and with a ??¹³C of ?30???, at isotopic and geochemical equilibrium, ??¹³C_DIC values would approach this end-member, and DIC concentrations of 1,000?mmol L^?1 would be expected. Laboratory experiments were conducted at low pCO₂ levels (4?C35?bars) to mimic the approach of a CO₂ plume at a monitoring well. These results support field investigations from other sites: that ??¹³C_DIC is a sensitive tool for monitoring CO₂ migration in the subsurface and simultaneously allows quantification of geochemical trapping of CO₂.     

Rainfall over Oman and its teleconnection with El Niño Southern Oscillation

The Sultanate of Oman is located in the south-eastern part of the Arabian Peninsula and covers the larger part of the southern coasts of the Arabian Peninsula in both arid and semi-arid environments except for the southern part which is swept by the monsoon affecting the Arabian Sea during the period from June to September. The summer rainfall over Oman shows year-to-year variability, and this is caused by oceanic and atmospheric influences. In the present study, we tried to explore the influence of El Niño on the rainfall over Oman using different data sets. The empirical orthogonal function (EOF) technique employed to the zonal wind at 850 hPa for the 30-year period shows that the second and third modes of EOF are showing high variability over the Oman regions. The corresponding PCs were subjected to FFT analysis, and it showed a peak about 5–6 years. In addition to this, the zonal wind over the Oman regions is correlated with the global zonal wind and found a significant correlation (1 % significant level). It has already been proved that the wind and rainfall during summer monsoon is in phase. Moreover, the spectral analysis of rainfall at Masirah station and the Niño3.4 index show the similar mode of variability indicating a direct relationship. The correlation between rainfall and the Niño3.4 index is also showing a positive significant value, and therefore, it can be concluded that the El Niño in the Pacific favours rainfall over the Oman region.     

Storm activities during the sedimentation of late Paleocene-middle Eocene Subathu Formation,western Himalayan foreland basin

Late Paleocene-middle Eocene Subathu Formation represents the earliest deposits of the western Himalayan foreland basin. A large part of this formation is comprised of impure limestone and grey shale intercalations. The limestones contain sole marks, intraformational conglomerates, hummocky cross stratification and wave ripples. The occurrence of sole marks suggests that they are developed by the unidirectional currents at the initial phase of the storm that resulted erosion and subsequent deposition. The intraformational limestone conglomearate also suggests erosion of the earlier deposited limestone hardgrounds as a consequence of storm associated transgression. The hummocky cross stratification formed by the oscillatory flows during the long-shore littoral drift. The depth of formation of the hummocky cross stratified limestone facies was less than 40 m and most likely deposited between shore-face to backshore regions of the gulf similar to present day Persian Gulf. The identification of deeper facies (shelf facies) from Pakistan and coastal facies from India suggest that the gulf was open from the west and closed from the east.