福清沙浦——平潭马腿推覆型韧性剪切带基本特征

福清沙浦－－平潭马腿推覆型性剪切带位于福建东南沿海褶皱变质带的北段，在“三山、平潭、高山、观音澳”幅１：５万区调工作中，我们首次发现并肯定了该推覆型韧性剪切带的存在，并作了详细的工作。     

Ultrahigh-pressure metamorphism in the forbidden zone: the Xugou garnet peridotite, Sulu terrane, eastern China

The Xugou garnet peridotite body of the southern Sulu ultrahigh‐pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo₉₁), enstatite (En_92?93), garnet (Alm_20?23Prp_53?58Knr_6?9Grs_12?18), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high‐Mg number, very low CaO, Al₂O₃ and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp_44?58) clinopyroxenites are foliated. Except for rare kyanite‐bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm_29?34Prp_32?50Grs_15?39) + omphacite (Jd_24?36) + minor rutile. Clinopyroxenite and eclogite exhibit LREE‐depleted and LREE‐enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high‐pressure crystal accumulation (+ variable trapped melt) from melts resulting from two‐stage partial melting of a mantle source. Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (< 5 °C km^?1), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K‐feldspar indicate low‐temperature metasomatism.     

Spatial and seasonal distributions of soil phosphorus in a typical seasonal flooding wetland of the Yellow River Delta,China

Soil samples from 0 to 100 cm depth were collected in four sampling sites (Sites A, B, C and D) along a 250-m length of sampling zone from the Yellow River channel to a tidal creek in a seasonal flooding wetland of the Yellow River Delta of China in fall of 2007 and spring of 2008 to investigate spatial and seasonal distribution patterns of total phosphorous (TP) and available phosphorus (AP) and their influencing factors. Our results showed that TP contents in spring and AP contents in both seasons in surface soils increased with increasing distances away from the Yellow River channel. TP contents in surface soils (0–10 cm) followed the order Site A (698.6 mg/kg) > Site B (688.0 mg/kg) > Site C (638.8 mg/kg) > Site D (599.2 mg/kg) in fall, while Site C (699.6 mg/kg) > Site D (651.7 mg/kg) > Site B (593.6 mg/kg) > Site A (577.5 mg/kg) in spring. Generally, lower TP content (630.6 mg/kg) and higher AP level (6.2 mg/kg) in surface soils were observed in spring compared to fall (656.2 mg/kg for TP and 5.2 mg/kg for AP). Both TP and AP exhibited similar profile distribution patterns and decreased with depth along soil profiles with one or two accumulation peaks at the depth of 40–80 cm. Although the mean TP content in soil profiles was slightly higher in spring (635.7 mg/kg) than that in fall (628.0 mg/kg), the mean TP stock was obviously lower in spring (959.9 g/m²) with an obvious accumulation at the 60–80 cm soil depth compared to fall (1124.6 g/m²). Topsoil concentration factors also indicated that TP and AP had shallower distribution in soil profiles. Correlation analysis showed that AP had significant and positive correlation with these soil properties such as soil organic matter, salinity, total nitrogen and Al (p < 0.01), but TP was just significantly correlated with TN and Al (p < 0.05).     

山西义兴寨金矿床地球化学研究

晋东北地区以唐河大断裂为核心的一组早燕山期 NW向张剪性断裂与区域 NE向复向斜复合部位 ,控制着区内燕山期中酸性浅成侵入体及其与之有关的铁、金、铜矿化 ,义兴寨金矿是该地区具代表性的典型矿床。金矿床为热液型脉状金 -多金属矿床 ,矿体受岩体和断裂构造控制。金矿床分 4个成矿期 ,8个亚期。对金矿床的矿床地质特征、成矿流体成分、性质、成矿物理化学条件及成矿时代的研究表明 ,成矿溶液的 p H值为 6 .1 6～ 6 .5 3:Eh值为 -0 .2 81～-0 .2 80 ;lgf O2 =-3.6～ -2 9,lgf CO2 =4 .3～ 5 .2 ;成矿温度为 1 90～ 349℃ ;成矿压力为 2 0 .0～ 76 .0 MPa;矿床主成矿期石英的 40 Ar— 3 9Ar坪年龄为 ( 1 31 .4± 3.1 ) Ma。     

Geochemical characteristics,cooling history and mineralization significance of Zhangtiantang pluton in South Jiangxi Province,P.R. China

The zircon SHRIMP dating of the Zhangtiantang granite gave an age of 159±7 Ma., which shows that the granite was produced at the early Late Jurassic. The Ar-Ar plateau ages of biotite and K-feldspar from the Zhangtiantang pluton are 153.2±1.1 Ma and 135.8±1.2 Ma, respectively. The Ar-Ar anti-isochrone ages of biotite and K-feldspar are 152.5±1.7Ma and 135.4±2.7Ma, respectively. The ages represent the isotopic closure ages of minerals in the pluton. The Zhangtiantang granites are regarded as peraluminous crust-derived type granites to possess the typical geochemical characteristics of calc-alkaline rocks on continental margin, with enriched Si, K, Al (average value of A/CNK as 1.18), HREE, Rb, U, and Th, heavily depleted V, Cr, Co, Ni, Ti, Nb-Ta, Zr, Sr, P, and Ba, strongly negative Eu and common corundum normative (average value of C as 1.84). The εNd_(t) values of the Zhangtiantang granite are −5.84 to −7.79, and t _2DM values are 1.69 to 1.83 Ga, which indicates partial melting of continental-crust metamorphic sedimentary rocks during the Middle Proterozoic. The cooling history of the Zhangtiantang granitic pluton indicates that the cooling velocity of pluton was faster (about 67°C/Ma) from zircon (158 Ma) to biotite (152 Ma), and was slower (about12°C/Ma) from biotite (152.5 Ma) to K-feldspar (135.8 Ma). It can be deduced that the temporal gap (about 10 Ma) between the granite formmation and W-Sn mineralization in South China may be related to ordinary magma-hydrothermal processes by the variational cooling curve of the pluton. The Zhangtiantang pluton was formed in a compressive setting, with differentiation evolution and mineralization occurring in a relative relaxation setting.     

微生物对碳酸盐岩的风化作用

微生物-矿物相互作用可以促进许多表生生物地球化学反应过程,是表生地球化学研究的重要内容。通过综合岩石表面的微生物类群及其地质作用,分析碳酸盐岩微生物风化的各种现象,特别是微观尺度上的各种形态,阐述碳酸盐岩的微生物风化机制与风化产物,笔者提出微生物对碳酸盐岩风化的4种途径:(1)通过微生物在岩石表面和缝隙中生长,导致岩石表层发生生物溶蚀、生物磨蚀和生物钻孔作用,加速岩石风化进程;(2)微生物群体形成的钻孔网络可以增强岩石化学溶蚀的有效表面积并导致其表面强度减弱而促进机械侵蚀作用,微生物对周围岩石颗粒胶结结构的破坏、疏松作用也会导致岩石矿物颗粒的分解;(3)微生物的持水作用,微生物分泌的有机酸以及微生物呼吸所释放的CO2对岩表水分的酸化过程亦加速岩石矿物的分解;(4)微生物生长过程中从岩石内摄取营养元素和产生复杂的有机配体,能促进矿物元素的释放。文中提出在开展微生物对碳酸盐岩风化过程和机理研究的基础上,有必要引入微生物生物技术来综合开发本地低品位含钾磷矿产资源,加速岩溶地区山地土壤的形成与演化。     

基于空三模型实现非接触式实测地质剖面解决方案研究

本文提出的"基于空三模型实现非接触式实测地质剖面解决方案",是通过导出空间三维模型剖面多段线三维坐标,使用自主开发的辅助软件,在AutoCAD中快捷生成剖面图。通过实践,该方案能快速完成无需人工到实地进行实测的实测剖面工作,尤其危岩体勘查中能精确反映高陡崖区微地貌起伏形态和结构面特征,解决了人工实测无法完成的工作。     

胶东金矿成矿构造──地球化学动力学研究

通过对胶东区域断裂构造时空演化的分析，提出郯庐大断裂的次级断裂为胶东金矿的控矿构造，并为导矿构造。晚燕山期区域右行走滑断裂活动产生的浅部张剪裂隙为容矿构造，其张裂变形产生的扩容作用是“泵吸”深部矿液上侵充填的驱动力。张剪断裂以脉动方式释放构造应力，实测差应力值为１２０～４０ＭＰａ；从早到晚有衰减趋势。容矿断裂脉动活动可划分为脆性破裂和脆韧性扩张两种动力学状态或阶段，并制约着热液反应体系中成矿和控制反应进行的方向和强度，从而控制成矿元素的富集和分散。热液成矿反应体系的热力学演化与构造动力学条件的耦合是金富矿石形成的机制。