AMS analysis of I in Japanese soil samples collected from background areas far from nuclear facilities

Analytical procedures in the determination of iodine-129 (half-life: 1.6×10⁷ y) have been studied using accelerator mass spectrometry (AMS), with special references to the separation procedures of iodine from soil samples for the AMS measurement. Iodine was successfully volatilized from soil samples by pyrohydrolysis at 1000 °C and collected in a trap solution. Iodine was purified from the matrix by solvent extraction. Finally, it was precipitated as silver iodide to make a target for AMS. In order to obtain information on the ¹²⁹I/¹²⁷I ratio in a chemical blank (or iodine carrier), we have determined the ratios in several iodine reagents and found that the ratios fell in a narrow range around 1.7×10⁻¹³. The detection limit for soil sample (1 g material) by the present method was about 0.01 mBq/kg or 4×10⁻¹¹ as the ratio of stable iodine (¹²⁹I/¹²⁷I ratio), i.e. these values were much better than that by neutron activation analysis (NAA) used in our previous studies. We have applied this method in the analysis of soil samples collected from different places in Japan. We could successfully determine ¹²⁹I in soil samples with low ¹²⁹I concentrations, which could not be detected by NAA. Sample size necessary for the soil analysis by AMS was only about 0.5 g or less, whereas about 100 g of the sample were required for NAA [Muramatsu, Y., Ohmomo, Y., 1986. Iodine-129 and iodine-127 in environmental samples collected from Tokaimura/ Ibaraki, Japan. Sci. Total Environ. 48, 33-43]. Using this method, new data were obtained for the ¹²⁹I levels in 20 soil samples collected from background areas far from nuclear facilities, and the ranges were 1.4×10⁻⁵−4.5×10⁻³ Bq/kg as ¹²⁹I concentrations and 3.9×10⁻¹¹−2.2×10⁻⁸ as ¹²⁹I/¹²⁷I ratios. These values are useful in understanding the ¹²⁹I levels in Japanese environments. Higher ¹²⁹I concentrations were observed in forest soils than those in field and rice paddy soils should be related to the interception effect of atmospheric ¹²⁹I due to tree canopies. Relatively high ¹²⁹I/¹²⁷I ratios found in rice paddy soils could be explained by their low stable iodine concentrations which were caused by the desorption of stable iodine from the rice paddies during the cultivation.     

Intermediate high-pressure exhumation of the northern segment of the Sanbagawa belt, Saruta-gawa area, central Shikoku, Japan

The retrograde chemical zonal structure of amphibole in hematite-bearing basic and quartz schists from the higher grade zone in the Saruta-gawa area of the Sanbagawa belt was studied to investigate the relationships between the prograde and retrograde P–T paths of the Sanbagawa metamorphism. This amphibole coexists with chlorite, epidote, muscovite, albite, quartz and hematite, and is composed of Al-rich core and Al-poor mantle. The core is fairly homogeneous and has a barroisitic composition. In the mantle part, ^[B]Na increases with decreasing ^[4]Al towards the margins, which have winchite–magnesioriebeckite compositions. The barroisite–winchite–magnesioriebeckite composite crystal is sometimes rimmed by actinolite and/or winchite with low ^[4]Al and ^[B]Na. The Al-rich core and Al-poor mantle are regarded as prograde and retrograde products, respectively. The retrograde mantle in the Saruta-gawa area: (1) is systematically richer in ^[B]Na [0.40–1.73 per formula unit (pfu; for O=23)] than that from the same grade zone in the Asemi-gawa area (0.19–0.78 pfu), about 8 km south of the studied area; (2) tends to be ^[B]Na-poorer (less than 1.73 pfu) than prograde sodic amphibole (up to 1.93 ^[B]Na pfu) produced in the peak temperature stage from the lower grade zone in the same and other areas; and (3) extends its compositional range towards higher ^[B]Na and lower ^[4]Al than prograde-formed amphibole from the same grade zone in the same area. These zonal characteristics imply that (1) the Saruta-gawa samples experienced retrograde metamorphism under higher P/T conditions than the Asemi-gawa samples, (2) the retrograde P–T path of the Saruta-gawa area passes on the lower pressure side of the metamorphic field gradient, and (3) the Saruta-gawa samples underwent retrograde metamorphism under higher P/T conditions than the prograde metamorphism. The higher P/T conditions of the retrograde metamorphism suggests an increasing dP/dT of the geotherm during exhumation. Retrograde P–T conditions during the formation of magnesioriebeckite can be roughly estimated at 7–8 kbar, 400–450°C based on semi-quantitative phase relations of actinolite–winchite–magnesioriebeckite–barroisite series associated with chlorite, epidote, muscovite, albite, quartz and hematite.     

Pigeonite-bearing basalts dredged from the Puerto Rico Trench: A microprobe study

A microprobe study was carried out on zoned clinopyroxene, composed of a pigeonite core mantled by augite, and plagioclase in six tholeiitic basalts dredged from the Puerto Rico Trench (20° 06.8′N, 65° 06.5′W). The pigeonite cores are characterized by high magnesium contents [Fe/Fe + Mg = 0.19 on the average]; their crystallization temperatures based on the three-pyroxene geothermometer are thus estimated to be higher than those of the well-studied tholeiitic pyroxene assemblages (Hakone, Weiselberg, Mull, Skaergaard, and Bushveld). It is suggested from textural and chemical relationships that pyroxene crystallization started first with precipitation of pigeonite followed by simultaneous precipitation of pigeonite and augite and finally by crystallization of augite alone in the groundmass.     

Morphodynamic effects of vegetation life stage on experimental meandering channels

Previous studies have demonstrated that riparian vegetation leads to channel transformation from a multi-bar to a single-thread channel planform. However, it still remains unclear how the presence of pioneer and mature vegetation affects the morphodynamics of single-thread meandering rivers. In this study, we therefore investigated the effects of vegetation strength on the morphodynamic evolution of an experimental meandering channel. Three physical laboratory experiments were conducted using alfalfa sprouts in different life stages – no vegetation, immature vegetation, and mature vegetation – to simulate different floodplain vegetation strengths. Our results demonstrate that vegetation plays a key role in mediating bank erosion and point-bar accretion, and that this is reflected in both the evolution of the channel bed as well as the sediment flux. The presence of mature vegetation maintained a deep, single-thread channel by reducing bank erosion, thereby limiting both channel widening and sediment storage capacity. Conversely, an unvegetated floodplain led to channel widening and high sediment storage capacity. Channel evolution in the unvegetated scenario showed that the active sediment supply from outer bank erosion led to slightly delayed point-bar accretion on the inner banks due to helical flow, deflecting the surface flow toward the outer banks and causing further erosion. In contrast, in the immature vegetation scenario, the outer banks were also initially eroded, but point-bar accretion did not clearly progress. This led to a greater width-to-depth ratio, resulting in a transition from a single- to a multi-thread channel with minor flow paths on the floodplain. The experimental results suggest that the eco-morphodynamic effects of young (low-strength) and mature (high-strength) vegetation are different. Notably, low-strength, early-stage vegetation increases channel complexity by accelerating both channel widening and branching, and therefore might promote the coexistence of multi-bars and pioneer vegetation.     

Tracing anthropogenic inputs to production in the Seto Inland Sea, Japan - A stable isotope approach

The Seto Inland Sea (SIS) receives waste runoff from ∼24% of Japan’s total population, yet it is also important in regional fisheries, recreation and commerce. During August 2006 we measured carbon and nitrogen stable isotopes of particulate organic matter (POM) and zooplankton across urban population gradients of the SIS. Results showed a consistent trend of increasing δ¹⁵N in POM and zooplankton from the western to eastern subsystems of the SIS, corresponding to increasing population load. Principal components analysis of environmental variables indicated high positive loadings of δ¹⁵N and δ¹³C with high chlorophyll-a and surface water temperatures, and negative loadings of low salinities related to inputs from large rivers and high urban development in the eastern SIS. Anthropogenic nitrogen was therefore readily integrated into the SIS food web from primary production to copepods, which are a critical food source for many commercially important fishes.     

Past,present and future of a meandering river in the Bolivian Amazon basin

Field observations on small rivers of the Amazon basin are less common due to their remote location and difficult accessibility. Here we show, through remote sensing analysis and field works, the planform evolution and riverbed topography of a small river located in the upper foreland Amazon basin, the Ichilo River. By tracking planform changes over 30 years, we identified the factors that control meander migration rates in the Ichilo River: cutoffs, climate and human interventions. The data suggest that neck cutoffs are the main controls in the Ichilo River, with an annual density of 0.022 cutoffs/km. In addition, climate controls have been identified in the form of high-precipitation events that may have promoted cutoffs, an increase in meander migration rate and channel widening. The width distribution of the Ichilo River is well represented by general extreme value and inverse Gaussian distributions. The spatiotemporal variability of meandering migration rates in the Ichilo River is analysed in two locations where neck cutoffs are expected. Analysing the distance across the neck in these two points, we predict the occurrence of a new cutoff. The combined methodology of bathymetric surveys and structure from motion photogrammetry shows us the Ichilo riverbed topography and banks at high resolution, where two scour holes were identified. Finally, we discuss the impact of planform changes of the Ichilo River on communities that are established along its riverbanks.     

Experiment and simulation of turbulent flow in local scour around a spur dyke

The turbulent flow in the local scour hole around a single non-submerged spur dyke is investigated with both experimental and numerical methods. The experiments are conducted under clear-water scour regime with an impermeable spur dyke. The scour geometry and flow velocities are measured in details with a high-resolution laser displacement meter, electro-magnetic velocimetries and PIV （Particle image velocimetry）. A 3D non-linear k-ε model is developed to simulate the complex local flow field around the scour area. The numerical model is formulated using FVM （Finite volume method） on a collocated unstructured mesh, capable of resolving complex geometries and boundaries. It is found that the simulation results are reasonably consistent with those of the experimental measurements. Based on the study results, the nature of the flow structure around a spur dyke with local scour hole is analyzed.     

Analysis of the global relationship of biennial variation of sea surface temperature and air-sea heat flux using satellite data

We investigated the phase difference and the cross correlation coefficient between the band-pass filtered biennial variations of sea surface temperature (SST) and air-sea heat flux estimated by the monthly mean 2°×2° satellite data of Advanced Very High Resolution Radiometer (AVHRR) and Special Sensor Microwave/Imager (SSM/I) from July 1987 to June 1991. Judging from the phase difference, it can be determined whether the biennial variation of SST is controlled by local thermal air-sea interaction or oceanic processes of horizontal transport. When the local air-sea heat flux controls the biennial variation of SST, the phase of SST advances /2 (6 months) against that of the air-sea heat flux. In contrast, when the biennial variation of SST is controlled by the oceanic process, the phase difference between the SST and the air-sea heat flux becomes 0 or (12 months). In this case, two types of the phase differences are determined, depending on which variability of SST and air-sea heat flux is larger. The close thermal air-sea interaction is noticeable in the tropics and in the western boundary current region. The phase difference of /2 appears mainly in the north Pacific, the southeast Indian Ocean, and the western tropical Pacific; zero in the eastern tropical Pacific and the northeast and equatorial Atlantic; and that of in the central equatorial Pacific and north of the intertropical convergence zone (ITCZ) of the Atlantic. Phase differences of 0, , or /2 are possible in the western boundary current regions. This fact indicates that each current plays a different role to the biennial variation of SST. It is inferred that SST anomalies in the tropics are mutually correlated, and the process in which marked SST anomalies in the tropics are transferred to the remote area was probed. In the equatorial Pacific, the SST anomaly is transferred by the long planetary wave. On the other hand, it is found from the phase relationship and the horizontal correlation of SST that the SST anomaly in the central and western equatorial Pacific is connected through atmospheric mediation. It is suggested that the biennial variation of SST in the eastern Indian Ocean is affected by heat transport due to the Indonesian throughflow from the western tropical Pacific. It is found that the mentioned pattern of the interannual variation of SST in the tropical Atlantic as a dipole is not tenable.     

Modelling artificial channel and land‐use changes and their impact on floods and sediment yield to the Ishikari basin

The potential for flooding and sediment transport is greatly affected by river channel form and changes in land use. Therefore the modelling of channel morphology prior to canalization and of land‐use change is important with respect to the prediction of floods and sediment yield and their consequences. A combination of land‐use transformation maps and soil properties shows certain decision rules for the conversion of forest into arable or vice versa. The model proposed, from this study, was used to simulate possible past and/or future channel and land‐use patterns. Subsequently, the outcome of this simulation was used to assess the risk of flooding, sediment transport and soil‐erosion under different conditions. In this study, channel morphology prior to canalization and land‐use change in the Ishikari basin, Hokkaido, Japan, were analysed by comparing three scenarios using a physical based channel and slope model. The results indicate that pre‐canalization channel morphology has a significant impact on flood peak, but no significant effect on sediment yield. In contrast, land‐use change has a significant effect on soil eroded from hillslopes, but no significant effect on flooding for Ishikari basin. This study also illustrates the challenges that a simple model, such as a physical based channel and slope model, can simulate large‐scale river basin processes using fewer hydrological data resources. Copyright © 2004 John Wiley & Sons, Ltd.