FTIR spectroscopy of Ti-chondrodite,Ti-clinohumite,and olivine in deeply subducted serpentinites and implications for the deep water cycle

Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/?0.017 ppm cm² based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm^?1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable.     

Market risk in carbon market: an empirical analysis of the EUA and sCER

The paper uses a capital asset pricing model to analyze the market risk in the European Union Emission Trading System (EU ETS) and clean development mechanisms (CDM) and Zipf analysis technology to analyze the carbon price volatility in different expectations of returns in the two markets. The results show that the systematic risk of the EU ETS market is around 0.07 %, but the CDM market is clearly divided into two stages; the systematic risk of the futures contracts in the first stage (DEC09–DEC12) is less than the EU ETS market, but the systematic risk of the futures contracts that enter the market is greater than the EU ETS market and has a higher market sensitivity, although on the unsystematic risk. The CDM market is always greater than the EU ETS market. Abnormal returns in the two carbon markets are both lower than 0.02 %, but CDM is higher. The probability of price down is greater than that of price up. The carbon price is affected by market mechanisms and external factors (economic crisis and environmental policies) in the low expectations of returns. However, in the high expectations of returns, compared with the CDM market, the carbon price change in the EU ETS market is less stable and has higher risks.

     

Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.     

“将今论古”思想视域下高中地理解题思路的建构

科学的地理解题思想和方法能搭建起地理知识和现实问题的“桥梁”,有效认识、思考与解决地理问题,适应新高考的考查要求。本文在充分解读“将今论古”思想内涵与外延的基础上,结合高考评价体系和新高考地理试题特点和要求,理清“将今论古”思想的思维路径;再将该思维路径进行实证研究,建构典型地理试题的解题思路,提升学生有效认识、思考和解决地理问题的能力。     

黄河流域煤炭富集区煤炭水足迹演变及驱动效应研究

煤炭与水资源相互影响和制约,如何评价煤炭耗水的演变趋势及其影响机制对煤炭和水资源进行协同管理具有重要意义。基于国际标准的煤炭水足迹测算模型,分析2000—2017年黄河流域煤炭富集区——晋陕蒙煤炭水足迹的时空演变趋势,构建煤炭水足迹压力指数评价区域煤炭和水资源的匹配关系,并运用LMDI模型定量分析煤炭水足迹的驱动效应。结论如下：① 煤炭水足迹总量在研究期内呈增长趋势,主要以原煤和火力发电水足迹为主,山西和内蒙古煤炭水足迹最高,陕西最低。② 研究区整体煤炭水足迹压力指数逐渐增大,由煤–水关系缓和型逐渐演变为煤–水关系制约型,从空间分异来看,山西最大,研究期内均属于煤–水紧张型,陕西次之,内蒙古最小,均由煤–水关系缓和型演变为煤–水关系制约型。③ 影响煤炭水足迹的主要驱动因素是经济效应和技术效应,前者对煤炭水足迹的影响逐渐增强,后者对煤炭水足迹压力的影响先增强后减弱,各驱动效应空间分异明显。研究结果可为煤炭富集区煤炭和水资源可持续利用提供决策参考,为黄河流域生态保护和高质量发展的资源管理提供决策支持。     

项目式学习中地理主题情境创设的优化——以农作物"水稻"为例

项目式学习以创设情境为过程,以问题解决为目标。本文立足地理新高考,通过探析一组经典真题,以代表区域为载体、以农作物为主题、以农作物种植的区位因素为项目,重点探讨依托农业的主题情境创设的优化意义及策略,深度开展项目式学习,从而培养学生地理核心素养,打造真正的地理高效课堂。     

西藏鄂雅错盐湖砷和汞的分布特征研究

本研究对西藏鄂雅错盐湖和主要支流中不同形态的砷(亚砷酸盐As(Ⅲ)、砷酸盐As(Ⅴ)、一甲基砷酸MMA、二甲基砷酸DMA)和总汞(THg)含量进行了测定,并与主要水质参数进行相关性分析研究,结果表明鄂雅错盐湖As主要以As(Ⅴ)形态存在,其次分别为As(Ⅲ)、DMA和MMA,其中无机砷的含量明显大于有机砷。相比较其他砷的形态,盐湖中As(Ⅲ)与主要水质参数的相关性显著,与总溶解性固体(TDS)、总溶解态氮(DTN)呈显著的强正相关性,与水温、溶解氧 (DO)、氧化还原电位(Eh)、pH呈显著负相关性。总汞浓度较低,且与主要水质参数相关性不显著。通过风险评价发现鄂雅错湖水中砷存在一定的致癌健康风险,汞不存在风险。本研究丰富了西藏盐湖和支流水体中砷、汞分布特征及其环境影响因素的认识,对于环境保护具有一定的意义。     

How is the precipitation distributed vertically in arid mountain region of Northwest China?

Precipitation in the arid region of Northwest China (NWC) shows high spatial and temporal variability,in large part because of the region's complex topography and moisture conditions.However,rain gauges in the area are sparse,and most are located at altitudes below 2000 m,which limits our understanding of precipitation at higher altitudes.Interpolated precipitation products and satellite-based datasets with high spatiotemporal resolution can potentially be a substitute for rain gauge data.In this study,the spatial and temporal proper-ties of precipitation in the arid region of NWC were analyzed using two gridded precipitation products:SURF_CLI_CHN_PRE_DAY_GRID_0.5 (CHN) and Tropical Rainfall Measuring Mission (TRMM) 3B43.The CHN and TRMM 3B43 data showed that in summer,precipitation was more concentrated in southern Xinjiang than in northern Xinjiang,and the opposite was true in winter.The largest difference in precipitation between mountainous areas and plains appeared in summer.High-elevation areas with high precipitation showed more stable annual precipitation.Different sub-regions showed distinctive precipitation distributions with elevation,and both datasets showed that the maximum precipitation zone appeared at high altitude.     

基于手势动作识别的地图浏览

针对当前热门的体感技术,研究基于手势动作识别的地图浏览方式。通过Microsoft Kinect手势的设计与识别,与搭建的OpenLayers等地图平台的浏览操作对接,实现基于人体自定义动作对地图浏览的操作,这种更人性化的人机交互方式在解放电脑对人的束缚的同时,也更促进了人机交互的融合。     

The Remote Sensing Image Matching Algorithm Based on the Normalized Cross-Correlation and SIFT

SIFT (scale invariant feature transform) is one of the most robust and widely used image matching algorithms based on local features. However, its computational complexity is high. In order to reduce the matching time, an improved feature matching algorithm is proposed in this paper under the premise of stable registration accuracy. This paper proposed a normalized cross-correlation with SIFT combination of remote sensing image matching algorithm. The basic idea of the algorithm is performing the space geometry transformation of the input image with reference to the base image. Then the normalized cross-correlation captures the relevant part of the remote sensing images. By this way, we can reduce the matching range. So some unnecessary calculations are properly omitted. By utilizing the SIFT algorithm, we match the preprocessed remote sensing images, and get the registration points. This can shorten the matching time and improve the matching accuracy. Its robustness is increased correspondingly. The experimental results show that the proposed Normalized cross-correlation plus SIFT algorithm is more rapid than the standard SIFT algorithm while the performance is favorably compared to the standard SIFT algorithm when matching among structured scene images. The experiment results confirm the feasibility of our methods.