Adsorbed silica in stalagmite carbonate and its relationship to past rainfall

Despite considerable work on other trace elements, the incorporation of dissolved silicon from cave waters into speleothems has not been previously investigated. In this study, the controls on dissolved Si in cave waters and on adsorbed Si in resulting speleothems are therefore investigated. Bedrock (dolomite), soil water, dripping water, and cave carbonates were retrieved from Heshang Cave situated in the central Yangtze valley of China and were subjected to analysis of dissolved Si content (plus accompanying Ca and Fe analyses). Soil waters have Si/Ca of 45.5 mmol/mol, compared to only 3.2 mmol/mol in the dolomite bedrock, demonstrating that >80% of the dissolved Si must come from dissolution of silicate minerals in the soil. Drip waters have a dissolved Si concentration of ≈4.2 μg/mL, similar to that in the overlying soil water. Actively growing cave carbonates have a Si/Ca of 0.075 mmol/mol suggesting a partition coefficient for incorporation of dissolved silicon of 0.0014, in good agreement with previous laboratory studies. Extrapolating the results of these laboratory studies to the cave environment suggests that changes in Si/Ca in cave carbonates are likely to be primarily controlled by changes in drip-water Si/Ca. The drip-water Si/Ca will, in turn, be controlled by the rate of wind-blown silicate supply; by soil weathering rates; by rainfall dilution; and by precipitation of calcite. The general expectation is that these effects combine to produce high Si/Ca in speleothems during times of low rainfall. A δ¹⁸O record from a Heshang Cave stalagmite which grew between 20 and 11 thousand years ago allows these controls to be tested. Correlation of high Si/Ca with high δ¹⁸O demonstrates that regional rainfall exerts significant (but not complete) control on speleothem Si/Ca. With further understanding, speleothem Si/Ca may provide a proxy for past rainfall to complement existing proxies such as δ¹⁸O and Mg/Ca.     

印度区域地质矿产概况

印度共和国是印度板块的主体,也是冈瓦纳大陆的重要组成部分,主要由七个古老克拉通（陆块群）、分隔克拉通的活动带与盆地等构成。自北向南依次为：①喜马拉雅活动带,主要为具有元古代基底的古近纪-新进纪活动带;②印度河-恒河平原过渡带（山前坳陷带）,主要由为第四系、古近系-新进系和第四系冲积物构成;③印度半岛克拉通,主要由西塔尔瓦尔、东塔尔瓦尔、巴斯塔、辛本,本德尔坎德、阿拉瓦利和印度南部麻粒岩地体等7个太古宙陆块（或次级克拉通）群构成;④萨德布尔活动带;⑤东高止山活动带;⑥德干高原玄武岩省（LIP）（图1）。     

中国区域性极端降水事件及人口经济暴露度研究

基于中国1960-2014年771个气象站的逐日降水资料,选取有效降水序列95百分位数作为极端降水阈值,将既定持续时间尺度和连续面积上超过阈值的降水事件定义为区域性极端降水事件。采用强度-面积-持续时间（Intensity-Area-Duration,IAD）法,根据极端降水事件空间和时间上的连续性特征,对不同持续时间的区域性极端降水事件演变趋势及暴露于极端降水事件下的人口和国内生产总值进行研究。结果表明:（1）相对强度最大的区域性极端降水事件主要集中在1960-1968、1991-1999和2006-2013年3个时段;（2）区域性极端降水事件最强中心主要分布在长江以南和东北地区,发生在北方的多为单日极端降水,南方多为持续多日的极端降水;（3）1960-2014年区域性极端降水事件影响面积有所增大,相对强度变化不明显;（4）暴露于极端降水事件影响区域内的人口和国内生产总值均呈显著增大趋势,暴露人口最多的年份在1983年,达到2408万人/d,暴露国内生产总值最多的年份在1998年,达到20亿元/d。      

珠江流域实际蒸散发与潜在蒸散发的关系研究

采用水量平衡模型和Penman公式分别计算了珠江流域七个子流域1961—2000年实际蒸散发(I_(ETa))和潜在蒸散发(I_(ETp)),并对供水条件变化下I_(ETa)与I_(ETp)的关系进行了定量化分析,对各子流域I_(ETa)和I_(ETp)关系的理论从属性进行判定,主要结论如下:1)珠江流域年实际蒸散发量远低于潜在蒸散发量,多数子流域I_(ETa)值不到I_(ETp)值的1/2。7个流域面积加权平均I_(ETa)为681.4 mm/a,I_(ETp)为1 560.8 mm/a。从蒸散发的变异性来看,则实际蒸散发I_(ETa)的变异性明显要高于潜在蒸散发I_(ETp)。2)东江、西江、北江、柳江和盘江等5个流域实际蒸散发I_(ETa)都与降水量呈现正相关关系,韩江、郁江两个流域I_(ETa)随降水变化的变化趋势不明显。各子流域的潜在蒸散发I_(ETp)与降水量呈现显著负相关关系。7个子流域平均情况下,随着降水量的增加,I_(ETa)呈现明显的增加趋势,而I_(ETp)呈现明显的下降趋势。3)通过对降水量P与实际蒸散发I_(ETa)及潜在蒸散发I_(ETp)的联合回归方程P-IET回归系数的T检验,判定韩江、柳江和盘江等三个子流域以及七流域面积加权平均I_(ETa)与P和I_(ETp)与P的关系满足理论意义上的严格互补相关;东江、西江、北江等三个流域I_(ETa)与P和I_(ETp)与P的关系满足"非对称"互补相关。4)基于极端干旱和极端湿润的边界条件,推导出非对称条件下的实际蒸散发互补相关理论模型。     

中国大陆降水时空变异规律——Ⅲ. 趋势变化原因

中国大陆现代降水表现出若干长期变化特征,对现代降水趋势性变化的原因,目前还没有很好了解。结合多种资料分析以及前人研究成果,对中国大陆近几十年降水变化趋势的原因进行了探讨,得到以下初步认识:① 现代降水量变化趋势具有明显的地域性差异,全国平均没有表现出显著增加或减少的长期变化,但强降水事件频率和降水量出现明显增多,而小雨事件特别是痕量降水事件显著减少。② 再分析资料表明,最近几十年全国水汽净收支量在一定程度上增加了,实际观测资料显示近地面和对流层中下层空气比湿或大气可降水量出现较明显上升趋势。③ 代用资料序列分析显示,全国大部地区近几十年降水变化仍处于晚近历史时期正常自然波动范围内;近百年观测的降水量序列也表明,黄淮海地区降水具有多重时间尺度相互叠加作用特点,低频自然气候变异的影响信号有清晰表现。④ 人类活动引起的大气中温室气体浓度增加对全国或东部季风区现代降水变化影响的信号,目前仍难以识别;区域性近地面风速减弱导致的雨量观测系统偏差以及大范围气溶胶浓度增加,可能是东部季风区大多数台站观测到的强降水事件频率增加和小雨频率显著减少的两个重要原因。⑤ 主要与城市化影响相关的地面观测资料系统偏差,可以部分解释现有分析表明的短历时强降水事件频率和累计降水量增加现象,同时也很可能是城市台站小雨和痕量降水事件频率明显下降的另一重要原因。     

The Late Triassic I–Type Granites from the Longmu Co–Shuanghu Suture Zone in the interior of Tibetan Plateau, China: Petrogenesis and Implication for Slab Break–Off

The Jiangaidarina granitic mass(JM) is an important part of the magmatic belt in Longmu CoShuanghu Suture Zone(LSSZ) in the central Tibetan Plateau. An integrated research involving wholerock geochemistry, zircon LA-ICP-MS U-Pb ages and Hf isotopic compositions was carried out to define the timing, genesis and tectonic setting of the JM. Zircon LA-ICP-MS U-Pb ages have been obtained ranging from 210 to 215 Ma, rather than the Early Jurassic as previously thought. Fifteen granite samples contain hornblendes and show a negative correlation between P_2 O_5 and SiO_2, indicating that the JM is an I-type granite. All the granites are enriched in LREE relative to HREE, with negative Eu anomalies(Eu/Eu*=0.56-0.81), and have similar trace elements patterns, with depletion of Ba, Nb, Sr and P. These suggest that the JM was fractionated, and this is also proved by the characteristic of negative correlations between oxide elements(TiO_2, MgO, FeOt, MnO, CaO) and SiO_2. Almost all ε_(Hf)(t) values of the granites are between-10.3 and-5.8, implying that the JM has a crustal source intimately related with the South Qiangtang Block(SQB), except for one(+10.2), showing a minor contribution from mantle source.Moreover, relatively low Na_2 O/K_2 O ratios(0.42-0.93) and high A/CNK values(0.91-1.50) reflect that the JM was predominately derived from the medium-high potassium basaltic crust, interacted with greywacke. Our new geochemical data and geochronological results imply that the Late Triassic magmas were generated in a post-collisional tectonic setting, probably caused by slab break-off of the Longmu Co-Shuanghu Tethyan Ocean(LSTO). This mechanism caused the asthenosphere upwelling, formed extension setting, offered an enormous amount of heat, and provided favorable conditions for emplacement of voluminous felsic magmas. Furthermore, the LSTO could be completely closed during the Middle Triassic, succeed by continental collision and later the slab broke off in the Late Triassic.     

中国—吉尔吉斯斯坦天山构造格架与演化

中国—吉尔吉斯斯坦天山地处中亚天山造山带中段,地质构造复杂,矿产资源丰富。在前人资料基础上,基于区域构造-岩石组合的分布发育及时空属性特征,统一将研究区划分为哈萨克斯坦和塔里木两大板块,二者由南天山晚古生代缝合带所焊接。其中,进一步划分为5个二级单元,18个三级单元。研究认为,研究区内北、中、南天山构造格架连续,在800 Ma(相当于南华纪下限)前后都完成了大陆块体的拼合,成为全球新元古代罗迪尼亚超大陆的组成部分。此后经历了大致相同的构造演化史,从中二叠世开始全区转化成陆内盆山构造格局,新生代印度大陆同欧亚大陆碰撞使这一陆内盆山构造格局不断臻于完善。     

柴达木盆地一里坪盐湖富锂卤水特征、储层物性及富水区分析

一里坪盐湖是柴达木盆地中一个典型的富锂卤水矿床,具有重大的经济价值.本文以查明盐湖深部卤水分布为目的,从卤水储层的空间分布特征和储层物性的角度对富水区进行预测,为卤水开发提供依据.研究区位于一里坪成盐盆地沉积中心区域,晚更新世末期以来,以沉积浅湖相的含淤泥和黏土粉砂岩,盐湖相的含粉砂和黏土的石盐岩为特征.在垂向上,由上下两套石盐岩夹中部粉砂岩组成一里坪富锂卤水的储层;平面上,研究区北部主要为浅湖相,往南过渡为盐湖相,石盐岩厚度在东南部最大.对储层厚度、孔隙度和给水度的分析表明,第Ⅱ矿层孔隙型和晶间型卤水优质储层均位于研究区东部,可作为卤水资源勘查开采的重点区域.     

柴达木盆地一里坪盐湖成盐卤水成分变化及其意义——来自LA- ICP- MS分析石盐流体包裹体组成的证据

一里坪盐湖是柴达木盆地一个以富锂卤水为主的干盐湖,蕴藏有丰富的卤水钾锂资源,目前对成矿过程中卤水的成分及其演变规律方面的研究较少.论文选取一里坪盐湖中部钻孔HC2105岩芯的石盐为主要对象,利用激光剥蚀-电感耦合等离子质谱法开展了单个石盐原生流体包裹体成分分析,探讨恢复了一里坪盐湖地区晚更新世以来成盐期的古卤水成分.结果表明,一里坪盐湖下层石盐古卤水Li、B、K等离子浓度均高于上层石盐,这说明晚更新世成矿条件更好.古卤水中Li、B、K和Mg等离子具有正相关性,再结合对Ca离子浓度变化的研究,说明一里坪盐湖的主要物质来源为那棱郭勒河,深部卤水对其物质来源贡献较小;石盐流体包裹体中各离子浓度的演变规律与钻孔沉积韵律以及古气候变化三者基本可以拟合,从而证实盐湖卤水成分变化受到古气候变化的影响,干冷期可能更有利于富锂卤水矿的形成.