川西义敦岛弧中部图姆沟组流纹岩年代学、地球化学特征及其对岩浆成因的限定

【研究目的】 义敦岛弧是三江特提斯复合造山带的重要组成部分。区域现有的研究较多集中在弧花岗质侵入岩及其成矿作用上,而对区内流纹岩的研究则相对匮乏。【研究方法】 本文在详细野外填图的基础上,对图姆沟组流纹岩进行岩石学、地球化学和同位素年代学研究。【研究结果】 流纹岩锆石U-Pb成岩年龄216.5 Ma,为晚三叠世。岩石SiO₂含量为73.24%~74.72%,全碱含量为5.26%~6.27%,为钙碱性系列,富集大离子亲石元素Rb、Th、U、K和轻稀土元素,亏损高场强元素Nb、Ta、Ti、P和重稀土元素,具典型的岛弧火山岩特征。【结论】 图姆沟组流纹岩是印支期甘孜—理塘洋壳向西俯冲环境下地壳部分熔融的产物。     

Compaction in a mantle with a very small melt concentration: Implications for the generation of carbonatitic and carbonate-bearing high alkaline mafic melt impregnations

Xenoliths entrained in alkaline basalts and kimberlites give strong evidence that mantle carbonatitic and carbonated high alkaline mafic silicate melts, which are initially produced at very low degrees of partial melting (?1%), percolate and accumulate to form impregnations with a melt concentration of up to 10%. At present no compaction model has explained such huge local amplification of melt concentration. Recently, Bercovici et al. [1] have shown that the commonly used equations of compaction are not sufficiently general to describe all melt percolation processes in the mantle. In particular, they show that, when the melt concentration in the mantle is very low, the pressure jump ΔP between the solid and liquid fractions of the mantle mush is very important and plays a driving role during compaction. 1-D compaction waves generated with two different systems of equations are computed. Three types of wave-trains are observed, i.e. (1) sinusoidal waves; (2) periodic waves with flat minima and very acute maxima (‘witch hat waves’); (3) periodic solitary waves with flat maxima and extremely narrow minima (‘bowler hat waves’). When the initial melt distribution in the mantle is quite homogeneous, the compaction waves have sinusoidal shapes and can locally amplify the melt concentration by a factor less than two. When there is a drastic obstruction at the top of the wetted domain, the pressure jump ΔP between solid and liquid controls the shape of the waves. If the computation assumes the equality of pressure between the two phases (ΔP=0), the compaction wave has a ‘bowler hat shape’, and locally amplifies the melt concentration by a factor less than 5. Alternatively, simulations taking into account the pressure jump between phases ΔP predict compaction waves with ‘witch hat shape’. These waves collect a large quantity of melt promoting the development of magmons with local melt concentration exceeding 100× the background melt concentration. It is inferred that in a mantle with very low concentrations of carbonatitic or high alkaline mafic silicate melt the magmons are about 1 km thick and reach, in less than 1 Ma, a melt concentration of about 10%. The magmons are likely generated below the lithosphere at some distance away from the center of hot spots. This can explain the development of mantle carbonatitic eruptions in the African rift and the carbonatite and high alkaline mafic silicate volcanic activity in oceanic islands.     

Relative Sea Level Variations Caused by Subduction

By means of a stratified Earth model with viscoelastic rheology, we have studied the long-term global fluctuations of Relative Sea Level (RSL) induced by subducting slabs. We have computed RSL variations for both a single subduction and a realistic distribution of slabs by a numerical simulation based on a simplified model of the subduction process. RSL is determined by the offset between the geoid and the dynamic topography; our analysis demonstrates that the latter provides the prevailing contribution. We have studied, in addition, the effects of rheological stratification upon the amplitude and time-evolution of these two quantities and, consequently, of RSL fluctuations. According to our results, an upper bound for the rate of RSL associated with subduction is of the order of 0.1 mm/yr, in agreement with previous studies. This rate of sea level variation is comparable with that attributed to changes in the tectonic regime on a large scale. This preliminary result corroborates the suggestion by other authors to include subduction in the list of geophysical mechanisms which contribute to long-term RSL fluctuations.     

In situ test of a borehole extensometer

Summary Stresses in the Earth's crust are known to represent a key element of geodynamical processes at various spatial and temporal scales. Static stresses within lithospheric plates can be estimated on the basis of direct in situ measurements in boreholes or near the surface. Earthquake focal mechanisms yield the same type of information by sampling at greater depths. The quantification of geological deformations happens to be the principal tool to determine possible changes in time of the tectonic stress pattern. These changes can however be recorded only qualitatively and on the geological time scale.In seismic regions it is clear that the regional stress field varies on a time scale defined by the recurrence of earthquakes, say several tens of years. Our goal was to design a robust and cheap instrument which could continuously monitor stress changes at depths large enough to reduce meteorological influences.     

Impact of diagenesis on reservoir quality in a sedimentary geothermal play: a case study in the Cooper Basin,South Australia

Geothermal resources hosted within sedimentary basins with high natural permeability have been targeted for the production of energy in Australia. The Hutton Sandstone (Cooper‐Eromanga Basin) – a prolific oil and gas producer known to have good reservoir quality and high reservoir volume – was recently tested for its geothermal potential in the Cooper Region. However, recent exploratory drilling did not produce the anticipated flow rates, raising the question of the impact of diagenesis on the reservoir quality of this sedimentary formation. The combined characterization of the petrology, diagenesis and petrophysical properties of the Hutton Sandstone at Celsius‐1 and other surrounding wells indicates variable reservoir properties in the Cooper Region. This integrated study demonstrates that low formation permeability occurs at geothermal target depth and explains the negligible flow rates obtained at Celsius‐1. These low permeabilities are the results of the preservation of widespread detrital clayey matrix and the extensive occurrence of authigenic kaolinite, illite and silica cements at the top and base of the Hutton Sandstone. This aspect is confirmed by NMR T₂ transversal relaxation time becoming shorter at similar depths. Petrography analysis also reveals that sandstones are affected by diagenetic processes of the eogenetic and mesogenetic phases. However, the Hutton Sandstone at Celsius‐1 is presently at pressure‐temperature conditions that are below the mesogenetic conditions, which suggests a late episode of uplift and cooling from maximum palaeotemperatures.     

Comparative toxic effects of copper-based nanoparticles and their microparticles in Daphnia magna by using natural freshwater media

Copper-based nanoparticles (NPs) are being widely used in different application fields and their health impacts to aquatic environments represent a current concern. Few studies are available about their comparative toxicity with their bulks and ions under natural exposition in aquatic organisms. Thus, the toxicity of Cu and CuO NPs and their microparticle and ionic forms was assayed in the acute immobilisation test of Daphnia magna by using freshwater media. Electronic microscopy, laser doppler velocimetry, and dynamic laser scattering methodologies were used to NPs characterisation. The results indicated that CuNPs and CuONPs were more toxic than their microparticles. Among NPs, CuNPs showed higher toxicity than CuONPs. Copper-based nanoparticles showed similar hydrodynamic particle size and were agglomerated in culture media, suggesting toxic-ionic release relationship and corroborated by the high toxicity induced by CuSO₄. Additionally, water chemistry of natural freshwater used in the experiments also favoured the ion release of these NPs.