Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.     

Estimating coefficients of volume compressibility from compression of strata and piezometric changes in a multiaquifer system in west Taiwan

This paper estimates the coefficients of volume compressibility from variation in compressible layer thickness and changes in piezometric heads by using detail ground surface surveys and a multilayer monitoring well at a selected site (Shigang) within the Choshui River alluvial fan in west Taiwan. The paper integrates various types of in situ monitoring tools, including leveling surveys, continuous global position system (GPS) stations, multilevel layer compression and groundwater pressure head-monitoring wells, to investigate the situation and progress of the subsidence problem in the region. The results from the cross-analyses of the measured data show that surface settlement caused by the compression of strata is between the depths of 60 and 210 m where the clayey stratum within 120-180 m was most pronounced and contributes up to 53% of the total compression. The results indicate that the clayey stratum is under normal consolidation. The results also reflect the fact that 20% of settlement contribution comes from the sandy stratum within 90-120 m; the elasto-plastic behavior of this sandy stratum is clear. The coefficients of volume compressibility of the clayey and sandy stratum analysed from the stratum's compression records; they were 6.38×10⁻⁸ and 5.71×10⁻⁹ m²/N, respectively. Ultimately, this parameter estimation would permit to control and predict land subsidence based on change in pressure head which are related to groundwater extraction.     

On the long-term seismic hazard analysis in the Zhangjiakou–Penglai seismotectonic zone, China

The Zhangjiakou–Penglai seismotectonic zone (ZPSZ) lies in the northern part of North China and extends along the Zhangjiakou–Beijing–Tianjin–Bohai Bay–Penglai–Yellow Sea. It is about 900 km long and some 250 km wide in a northwest direction. The great Sanhe-Pinggu (M_S=8.0) earthquake occurred on September 1679 and the Tangshan (M_S=7.8) earthquake on July 1976 caused serious economic and life losses. According to some differences in crust structure and regional tectonic stress field, the ZPSZ is divided into western and eastern segment by the 117°E line for study on long-term seismic hazard analysis. An analysis of Gutenberg–Richter's empirical relation of earthquake-frequency and time process of historic and recent earthquakes along the eastern and western segments shows that the earthquake activity obeys a Poisson process, and these calculations indicate that the earthquake occurrence probability of M_S=6.0–6.9 is 0.77–0.83 in the eastern segment and the earthquake occurrence probability of M_S=7.0–7.9 is 0.78–0.80 in the western segment of the ZPSZ during a period from 2005 to 2015.     

塔城市一次暴雪天气的分析

2003年2月22日塔城市出现一次暴雪天气过程。文章着重分析了此次天气过程的高空环流形势、地面形势、T—Td等，指出暖湿气流是造成暴雪的主要原因。     

基于二维小波变换的FMI图象分割

为了从FMI资料中定量提取参数，一个重要的步骤是从实际FMI资料中分离出反映溶孔、溶洞、裂缝的子图像。本文给出的方法，考虑图像像元邻域的特征，应用二维小波变换求出目标与背景边缘的点集，按这个边缘点集的坐标点所对应的原图像像素灰度值的平均值作为分割阈值进行图像分割。实际资料处理表明，应用这种方法可以从实际的FMI资料中准确地分割出孔洞、裂缝的子图像并且可以按深度段连续自动处理，为后续定量计算参数奠定了良好基础。     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

Least-squares wave-path migration

We present a new least-squares migration method called least-squares wave-path migration. The proposed method combines an iterative conjugate-gradient solver with a stationary-phase wave-path migration operator. Numerical tests demonstrate that (i) least-squares wave-path migration is computationally more efficient than and almost as accurate as Kirchhoff least-squares migration, and (ii) many of the artefacts seen in wave-path migration images are suppressed after several conjugate-gradient iterations. Previous results have shown that 3D wave-path migration is up to 100 times faster than a standard 3D Kirchhoff migration, but sometimes at the cost of reduced quality. With the proposed least-squares wave-path migration method, the image quality in wave-path migration can be improved at an acceptable increase in computational cost.     

库水位变化对库岸边坡稳定性的影响

在假定坡体孔隙水水位为水平线且不考虑渗透作用影响的基础上,基于极限平衡法考察了水位上升及下降的快慢对边坡安全系数的影响。对比计算表明:在水位缓慢变化即坡体内外水位线等高的条件下,边坡的安全系数随着水位坡高比的增大先略减小后急剧增大,且在水位坡高比为0.3处取得最小值,在边坡完全淹没于水中时取得最大值。当边坡完全淹没于水中后,水位高于坡顶的多少对边坡安全系数没有影响;在水位骤降或陡升条件下,相同库水位对应的边坡安全系数基本上均小于水位缓慢变化情况下的安全系数,故工程实际中无论是排水还是蓄水,都应尽量保持水位缓慢变化,这样才能使边坡处于较安全的状态。