Chemical composition of upper crust in eastern China

In an area of 3.3×10⁶ km² within eastern China, 28 253 rock samples were collected systematically and combined into 2718 composite samples which were analyzed by 15 reliable methods using national preliminary certified reference materials (CRMs) for data quality monitoring. The average chemical compositions of the exposed crust, the sedimentary cover and the exposed basement as well as the upper crust for 76 chemical elements in eastern China are given. A key basic geology projcct supported by Ministry of Geology and Mineral Resources of China.     

Comparison of Cu and Zn cycling in eutrophic lakes with oxic and anoxic hypolimnion

Data on the cycling of Cu and Zn in two eutrophic lakes are presented: Lake Greifen that becomes seasonally anoxic in its hypolimnion and Lake Sempach that is aerated during winter and oxygenated during summer. They suggest that hypolimnetic oxygenation 1) enhances the release of copper from the sediment but 2) also accelerates the entrapment and deposition of Cu and Zn by freshly formed Mn- and Fe-oxides.     

Environmental evolution of Zoigê Basin since 900 kaB.P. and comparison study with Loess Plateau

The Zoige Basin is located in the eastern margin of the Qinghai-Xizang Plateau, in which two cores, RH and RM, have been drilled, with the depths of 120 m and 310 m respectively. The former with the bottom age of 826 kaB. P. has been divided into 21 stages according to the multi-proxy analysis, which could be basically compared with the oxygen isotope record of deep-sea core. The palaeoclimatic and palaeoenvironmental process of the Zoigê Basin over the past 900 kaB. P. is reconstructed, and the comparison of core RH with the Luochuan Loess record is made.     

块状岩体边坡地震滑动位移分析

岩体边坡在强震作用下往往会产生滑动残余位移。这种位移是边坡稳定性评价的重要参量。本文利用块体动力学原理推导出层状和块状岩体边坡地震滑动位移微分方程式, 并编制了相应的计算程序, 给出了实例的计算结果。     

昆仑8.1级地震动力影响下青藏块体北部构造运动特征研究

印度板块对欧亚大陆的强烈推挤作用是中国西部地震活动的根本力源.大尺度的构造动力作用应具有相对稳定性.从受力平衡的观点看,在基本恒定的边界载荷作用下,大陆内部应力场在不断地进行着自我调整,可以是缓慢的构造变形,也可能是强烈地震引起的短期变化.一条断裂上剧烈的突发运动必然破坏原有的平衡,从而引起其他相关构造应力应变的响应性改变和周边块体运动的适应性调整.这种状况有利于潜在震源区域应变能的累积和错动的发生.     

Horizontal crustal movement in Chinese mainland from 1999 to 2001

The paper introduces the horizontal crustal movement obtained from GPS observations in the regional networks (including the basic network and the fiducial network) of the Crustal Movement Observation Network of China (CMONOC) carried out in 1999 and 2001. This paper is characterized by the acquisition of the horizontal displacement velocities during the period from 1999 to 2001 at the observation stations in the regional networks with datum definition of a group of stable stations with small mutual displacements in east China. Based on the most detailed map of horizontal crustal movement in Chinese mainland, the division of blocks, their displacements and deformations are studied. An approach to analysis of the intensity of the horizontal crustal deformation is proposed. The general characteristics of the recent horizontal crustal movement in Chinese mainland and that before the Kunlunshan earthquake of M=8.1 on November 14, 2001 are analyzed. Foundation item: The National Development and Programming Project for Key Basic Research (95-13-03-07).     

基于GPRS的远程气象观测数据实时采集传输系统及其应用

通过对远程自动气象站数据实时采集传输通讯方式的比较，提出基于通用分组无线业务（GPRS）的远程自动气象站数据实时采集和传输系统的技术方案，以小数据流方式，实现野外自动气象站观测数据的实时采集、传输和对观测设备运行的监控，达到节约经费，提高数据传输时效的目的，并将此系统成功地用于苏通长江公路大桥施工期气象环境监测与预警系统中。     

第二松花江流域水电厂综合中长期水文预报的分析研究

基于对第二松花江流域上游小山、松山、两江水电站中长期水文预报研究成果，论述了综合中长期水文预报的研究思路和定性预报、定量预报的分析研究方法。该研究通过2002年实践检验，具有较高的预报精度。     

Dissolution mechanisms of water in depolymerized silicate melts: Constraints from H and Si NMR spectroscopy and ab initio calculations

Dissolution of water in magmas significantly affects phase relations and physical properties. To shed new light on the this issue, we have applied ¹H and ²⁹Si nuclear magnetic resonance (NMR) spectroscopic techniques to hydrous silicate glasses (quenched melts) in the CaO-MgO-SiO₂ (CMS), Na₂O-SiO₂, Na₂O-CaO-SiO₂ and Li₂O-SiO₂ systems. We have also carried out ab initio molecular orbital calculations on representative clusters to gain insight into the experimental results.The most prominent result is the identification of a major peak at ∼1.1 to 1.7 ppm in the ¹H MAS NMR spectra for all the hydrous CMS glasses. On the basis of experimental NMR data for crystalline phases and ab initio calculation results, this peak can be unambiguously attributed to (Ca,Mg)OH groups. Such OH groups, like free oxygens, are only linked to metal cations, but not part of the silicate network, and are thus referred to as free hydroxyls in the paper. This represents the first direct evidence for a substantial proportion (∼13∼29%) of the dissolved water as free hydroxyl groups in quenched hydrous silicate melts. We have found that free hydroxyls are favored by (1) more depolymerized melts and (2) network-modifying cations of higher field strength (Z/R²: Z: charge, R: cation-oxygen bond length) in the order Mg > Ca > Na. Their formation is expected to cause an increase in the melt polymerization, contrary to the effect of SiOH formation. The ²⁹Si MAS NMR results are consistent with such an interpretation. This water dissolution mechanism could be particularly important for ultramafic and mafic magmas.The ¹H MAS NMR spectra for glasses of all the studied compositions contain peaks in the 4 to 17 ppm region, attributable to SiOH of a range of strength of hydrogen bonding and molecular H₂O. The relative population of SiOH with strong hydrogen bonding grows with decreasing field strength of the network-modifying cations. Ab initio calculations confirmed that this trend largely reflects hydrogen bonding with nonbridging oxygens.