Spatio-temporal differentiation of spring phenology in China driven by temperatures and photoperiod from 1979 to 2018

Large amounts of data accumulated in ecology and related environmental sciences arouses urgent need to explore useful patterns and information in it. Here we propose coclustering-based methods and a temperatures-photoperiod driven phenological model to explore spatio-temporal differentiation in long-term spring phenology in China. First, we created the first bloom date(FBD) dataset in China from 1979 to 2018 using the extended spring indices and China Meteorological Forcing Dataset. Then we analyzed the dataset using Bregman block average co-clustering algorithm with I-divergence(BBAC_I) and kmeans algorithm. Such analysis delineated the spatially-continuous phenoregions in China for the first time. Results showed three spatial patterns of FBD in China and their temporal dynamics for 40 years(1979–2018). More specifically, overall late spring onsets occur in 1979–1996, in which areas located in Jiangxi, northern Xinjiang and middle Inner Mongolia experienced constant changing spring onsets. Overall increasingly earlier spring onsets occur in 1997–2012, in which areas located in Fujian,Hunan and eastern Heilongjiang experienced the most variable spring onsets. Stable early spring onsets over China occur after 2012. Results also showed 15 temporal patterns of spring phenology over the study period and their spatial delineation in China.More specifically, most areas in China have the same FBD category for 40 years while northern Guizhou, Hunan and southern Hubei have the same category in 1979–1997 and then fluctuate between different categories. Finally, our results have certain directive significance on the design of existing observational sites in Chinese Phenological Network.     

Crustal velocity structure of the Northwest Sub-basin of the South China Sea based on seismic data reprocessing

Science China Earth Sciences - The deep crustal structure of the Northwest Sub-basin (NWSB) of the South China Sea (SCS) is of great importance for understanding the tectonic nature of the...     

Evaluation of the potential risks of heavy metal contamination in rice paddy soils around an abandoned Hg mine area in Southwest China

To assess the potential ecological and health risks of trace elements(Hg,Cd,As,Mn,Sb,Pb,Cu,Ni,Cr,and Zn),a total of 138 soil samples from rice paddies were collected during the rice harvest season in the Wanshan mining area,Guizhou Province,Southwest China.Factors of the pollution load index(PLI),geo-accumulation index(I-Geo),enrichment factor(EF),and risk index(RI)were determined.High concentrations of Hg,Sb,As,Zn,Cd,Cu,and Mn were observed in the soils.The PLI,I-Geo,and EF results all showed high levels of contamination by Hg and Sb and moderate levels of contamination by As,Pb,Zn,Cu,Cd,and Mn.There was no significant contamination from Ni and Cr.The RI was very high,with Hg as the dominant pollutant,as expected,indicating that the historical large-scale Hg mining,as well as artisanal mining,has had a significant impact on the Wanshan area.Moreover,coal combustion,manganese factories,and the use of agrochemicals by the local population could also have an impact on the soil through the introduction of heavy metal loads.To address the current state of contamination,pollutant remediation and the regulation control of the anthropogenic activities in Wanshan are urgently needed.     

气候系统模式对于北极海冰模拟分析

利用全球耦合模式对比计划第五阶段(CMIP5)模拟试验的结果,并与观测资料对比分析,评估了CMIP5模式对北极海冰的模拟效果。结果表明:多数模式可以较好地模拟出北极海冰的空间分布以及季节变化特征。1979—2005年北极海冰迅速减少,所有模式均模拟出北极海冰减少的趋势,但减少趋势大小与观测差别较大。在全球变化的背景下,全球地表气温升高1℃,北极海冰的面积减少1.02×106km2,而在模式中减少的北极海冰面积在0.62×106—1.68×106km2之间,说明模式对于北极海冰的模拟仍然存在很多不确定性。     

几种大型海藻对赤潮异弯藻生长抑制效应的初步研究

利用共存培养系统研究了大型海藻缘管浒苔、刚毛藻、石花菜、鸭毛藻、扇形拟伊藻、蜈蚣藻、海黍子、脆江蓠对赤潮异弯藻(Heterosigma akashiwo)生长的抑制效应并和孔石莼的作用进行比较。实验指出：孔石莼和缘管浒苔对赤潮异弯藻的抑制效应最强,石花菜次之;扇形拟伊藻、蜈蚣藻、刚毛藻、脆江蓠、海黍子虽表现出抑制作用但较差;鸭毛藻的抑制效应最弱。     

PPH联合补中益气汤加减治疗直肠内脱垂60 例

目的：探讨痔上黏膜环切术（PPH）联合补中益气汤加减治疗直肠内脱垂的临床疗效。方法：将直肠内脱垂患者120 例,随机分为治疗组和对照组,每组各60 例。对照组行PPH术治疗,治疗组在对照组基础上服用补中益气汤加减治疗。比较2组综合疗效、治疗前后肠道菌群参数和主要症状积分。结果：2组总有效率均为100%（60/60）;治疗后2组肠杆菌、肠球菌数量较治疗前减少,乳杆菌、双歧杆菌数量增加,且治疗组改善程度优于对照组,差异均有统计学意义（P＜0.05）;2组治疗后1、3、6个月主要症状积分均较治疗前减少,差异有统计学意义（P＜0.05）,但组间比较,仅治疗后6个月时差异有统计学意义（P＜0.05）。结论：PPH联合补中益气汤加减能明显减轻直肠内脱垂患者的临床症状,纠正肠道菌群失调,巩固术后远期疗效,效果优于单用PPH手术治疗。     

基于环形扫面测量的三维直流电阻率法任意各向异性模型响应特征

高精度地下任意各向异性介质电性分布特征识别是当前的热门研究课题。本文以国内外前人工作为基础,基于非结构化网格,利用基于梯度恢复的后验误差估计指导网格自适应细化过程,实现了直流电阻率法三维有限元数值模拟。通过与一维模型半解析解的对比,验证了本文算法的有效性。考虑到电各向异性介质在观测中存在视电阻率反常现象,本文采用了环形扫面测量方法。通过对几种典型各向异性模型的模拟分析,得到了相应的各向异性影响规律和识别特征,各向异性主轴电阻率之间的比值大小决定了椭圆型视电阻率极性曲线长轴与短轴的比值大小,主轴电阻率的旋转方向会改变视电阻率极性曲线的形状。本文的算法研究及数值模拟技术可为直流电法数据精细处理和解释提供技术支撑。     

夏季大亚湾悬浮颗粒有机物碳、氮同位素组成及其物源指示

2015年夏季开展了大亚湾悬浮颗粒有机物碳（POC）、氮含量（PN）及其同位素组成的研究,结果表明,δ13C_POC和δ15N_PN的变化范围分别为-25.7‰~-17.4‰和-6.3‰~10.4‰,平均值分别为-20.2‰和8.2‰。大亚湾悬浮颗粒有机物含量及其碳氮同位素组成的空间变化反映了不同有机质来源的影响:喜洲岛附近海域表现出高POC、PN、δ13C_POC和δ15N_PN的特征,指征着浮游植物水华的主导贡献;东北部范和港附近海域具有高POC、PN、低δ13C_POC和高δ15N_PN的特征,反映了河流/河口水生有机物的影响;湾顶白寿湾附近海域的δ13C_POC和δ15N_PN出现低值,体现了陆源有机质和人类污水排放的影响。借助δ13C_POC和δ15N_PN的三端元混合模型,定量出海洋自生有机质、陆源有机质、河流/河口水生有机质等3个来源的贡献平均分别为70%、13%和17%,其中海洋自生有机质是夏季大亚湾悬浮颗粒有机物的最主要来源。从这3种来源颗粒有机物含量的空间变化看,海洋自生有机质含量由湾内向湾外减少,与初级生产力的空间变化相对应;河流/河口水生有机质含量在大亚湾东北部出现高值;陆源有机质含量在表、底层出现不同态势,表层陆源有机物含量在湾中部海域最低,而底层则呈现出自湾内向湾口增加的趋势,主要受控于离岸距离和珠江冲淡水、粤东沿岸上升流输送的影响。     

高压密闭消解-电感耦合等离子体光谱和质谱联合测定海洋地质样品中52种元素

An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.