ELECTROCHEMICAL MEASUREMENT OF STEEL CORROSION IN SEABOTTOM SEDIMENT WITH “MD” METHOD

The tbough one year cormsion potential and polarisation resistanoc for 3 kinds of stals in seabottomedment of Liaodong Bay were measured with the “MD” method.The measurements wiIl have some thoretical and pndital talues. The thooretical valoc lies in thatthe reoorded changing process of the practital corrosion case can be basis for indoor discussion andeectrochemical on the corrosion practical value lies in that the obtained datu canbe basis for designing and controlling elatrochemical protation syttems. In fact, it is very difficult tomeasure in situ the cornosion parnders of steeIs in sea sediment.     

人工神经网络在白云岩类型识别中的应用

利用地球化学数据,运用人工神经网络方法对美国密苏里州东南Ｂｏｎｎｅｔｅｒｒｅ组（寒武纪）滨海相的白云岩进行了分类、识别,判别率达１００％,结果表明,该方法性能良好,可望成为岩石分类、判别的有效手段。     

含矿预测的人工神经网络方法

运用神经网络模型的一典型模型——“反向传播”模型的改进形式,处理矿产资源统计预测问题,得出与数量化理论Ⅱ处理极为相似的结果.     

上海城市发展的环境问题及其对策研究

上海市的发展战略;空间布局模式和环境管理是文章讨论的三个主要问题。作者认为:(1)战略设想要立足于上海的发展,“开发浦东、振兴上海、服务全国、面向世界;”(2)新的空间布局模式应为“逐步形成新的CBD,强化和完善金融和服务功能”;(3)城市发展和环境建设要协调。文章着重讨论了上海城市发展中出现的环境问题及其治理的对策和措施。     

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

Strength and stability of frictional sliding of gabbro gouge at elevated temperatures

To investigate the strength of frictional sliding and stability of mafic lower crust, we conducted experiments on oven-dried gabbro gouge of 1 mm thick sandwiched between country rock pieces (with gouge inclined 35° to the sample axis) at slip rates of 1.22 × 10^− 3 mm/s and 1.22 × 10^− 4 mm/s and elevated temperatures up to 615 °C. Special attention has been paid to whether transition from velocity weakening to velocity strengthening occurs due to the elevation of temperature.Two series of experiments were conducted with normal stresses of 200 MPa and 300 MPa, respectively. For both normal stresses, the friction strengths are comparable at least up to 510 °C, with no significant weakening effect of increasing temperature. Comparison of our results with Byerlee's rule on a strike slip fault with a specific temperature profile in the Zhangbei region of North China shows that the strength given by experiments are around that given by Byerlee's rule and a little greater in the high temperature range.At 200 MPa normal stress, the steady-state rate dependence a − b shows only positive values, probably still in the “run-in” process where velocity strengthening is a common feature. With a normal stress of 300 MPa, the values of steady-state rate dependence decreases systematically with increasing temperature, and stick-slip occurred at 615 °C. Considering the limited displacement, limited normal stress applied and the effect of normal stress for the temperatures above 420 °C, it is inferred here that velocity weakening may be the typical behaviour at higher normal stress for temperature above 420 °C and at least up to 615 °C, which covers most of the temperature range in the lower crust of geologically stable continental interior. For a dry mafic lower crust in cool continental interiors where frictional sliding prevails over plastic flow, unstable slip nucleation may occur to generate earthquakes.     

Modeling the seismic response of basin-edge structure by a sequential waveform method

A sequential waveform method is developed to simulate the seismic response of basin-edge structure excited by a plane incident P-wave. The full procedure involves: (a) a previous parameterization of the investigated model using the seismic wave velocities and depths of the sedimentary stratifications; (b) an input motion determined from the records at stations installed on hard rock; (c) forward computation of the P-SV elastic wave field by means of a two-dimensional finite difference (FD) method; (d) the optimization of the model vector using simulated annealing technique and comparing the simulated seismic response of the tested structure with the observed wave field; (e) the correction of the initial model by trial-and-error by testing the differences between synthetics and observed data, and (f) the final solution obtained by iteration using the conjugate gradient algorithm. The search of an optimal basin-edge model has been parallel processed by varying the shapes and velocities of strata on the basis of the fitting of relative timing, amplitude and phase between the output and the observed data. The input motion and sensitivity have been checked and the validity of the method has been demonstrated by numeric analysis. Using the teleseismic records generated by 7 earthquakes recorded at 26 broadband seismic stations, we have studied the seismic velocity structure of the southern edge of the Jiyang depression located in the Bohai Bay basin, northern China. Two cross sections show an agreement between the velocity results and the geological sections available in the region. In addition, we obtain evidence of three hidden faults under the sections and features that suggest major extensions at the Paleogene.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

侵蚀红壤植被恢复后土壤呼吸日动态及日呼吸速率测定方法比较

采用密闭室红外气体分析仪法(IRGA法)观测了中亚热带红壤侵蚀裸地植被恢复后不同季节土壤呼吸速率的日动态变化,并比较了IRGA法与碱吸收法(AA法)测定的土壤呼吸速率.结果表明:侵蚀裸地植被恢复后土壤呼吸速率日动态呈单峰曲线,与土壤温度的昼夜变化基本一致,最高值一般出现在午后13∶00~17∶00,最低值出现在凌晨3∶00~7∶00;植被恢复显著提高了土壤日呼吸速率,但明显降低了土壤呼吸速率日变化幅度;马尾松林对土壤呼吸速率日变化幅度降低程度高于板栗园和百喜草地,且对夏季的降低程度影响最大.而IRGA法和AA法测定的土壤呼吸速率具有显著的幂函数关系,AA法测定的土壤呼吸速率为IRGA法的27.5%~218%,平均为76.2%.当土壤呼吸速率较低时,AA法比IRGA法高估了土壤呼吸速率;反之,AA法则低估了土壤呼吸速率.     

大气CO2浓度升高对土壤中不同粒级碳的影响

不同粒级土壤中的碳有着不同的周转规律，在高CO2浓度条件下，它们含量的变化将在一定程度上反映土壤碳是累积还是减少，对明确土壤碳的变化趋势有重要意义．采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布．结果表明，加入秸秆培养1年，由于CO2浓度升高的原因导致在低氮（LN）、常规氮（NN）和高氮（HN）水平下土壤中碳分别增加0．01、1．10、1．22g／kg，表现为粒级〈53μm土壤颗粒中碳分别增加1．53、2．19、2．70g／kg．粒级〈53μmm土壤颗粒碳量的增加，主要是由于其重量分配百分数显著增加36．2％，碳浓度增加5．4％；粒级〉250μm和250～53μm土壤颗粒部分虽然其碳浓度分别增加20．8％和17．3％（P〈0．05），怛由于重量分配百分数分别显著降低22．8％和36．1％，结果碳量降低．试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化；高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势．